1,329 research outputs found
Transmission Electron Study of Heteroepitaxial Growth in the BiSrCaCuO System
Films of BiSrCaCuO and BiSrCuO have been grown using Atomic-Layer-by-Layer Molecular Beam
Epitaxy (ALL-MBE) on lattice-matched substrates. These materials have been
combined with layers of closely-related metastable compounds like BiSrCaCuO (2278) and rare-earth-doped
compounds like BiSrDyCaCuO
(Dy:2212) to form heterostructures with unique superconducting properties,
including superconductor/insulator multilayers and tunnel junctions.
Transmission electron microscopy (TEM) has been used to study the morphology
and microstructure of these heterostructures. These TEM studies shed light on
the physical properties of the films, and give insight into the growth mode of
highly anisotropic solids like BiSrCaCuO.Comment: 17 pages, submitted to J. Materials Research. Email to
[email protected] if you want to receive copies of the figure
Photoemission Evidence for a Remnant Fermi Surface and d-Wave-Like Dispersion in Insulating Ca2CuO2Cl2
An angle resolved photoemission study on Ca2CuO2Cl2, a parent compound of
high Tc superconductors is reported. Analysis of the electron occupation
probability, n(k) from the spectra shows a steep drop in spectral intensity
across a contour that is close to the Fermi surface predicted by the band
calculation. This analysis reveals a Fermi surface remnant even though
Ca2CuO2Cl2 is a Mott insulator. The lowest energy peak exhibits a dispersion
with approximately the |cos(kxa)-cos(kya)| form along this remnant Fermi
surface. Together with the data from Dy doped Bi2Sr2CaCu2O(8 + delta) these
results suggest that this d-wave like dispersion of the insulator is the
underlying reason for the pseudo gap in the underdoped regime.Comment: 9 pages, including 7 figures. Published in Science, one figure
correcte
Vanishing of phase coherence in underdoped Bi_2Sr_2CaCu_2O_8+d
Coherent time-domain spectroscopy is used to measure the screening and
dissipation of high-frequency electromagnetic fields in a set of underdoped
Bi_2Sr_2CaCu_2O_8+d thin films. The measurements provide direct evidence for a
phase-fluctuation driven transition from the superconductor to normal state,
with dynamics described well by the Berezinskii-Kosterlitz-Thouless theory of
vortex-pair unbinding.Comment: Nature, Vol. 398, 18 March 1999, pg. 221 4 pages with 4 included
figure
Zeolite-based photocatalysts immobilized on aluminum support by plasma electrolytic oxidation
The preparation and properties of zeolite-containing oxide coatings obtained
by plasma electrolytic oxidation are investigated and discussed. Pure and
Ce-exchanged natural (clinoptilolite) and synthetic (13X) zeolites are
immobilized on aluminum support from silicate-based electrolyte. Obtained
coatings are characterized with respect to their morphology, phase and chemical
composition, photocatalytic activity and anti-corrosion properties. It is
observed that all mentioned properties of obtained coatings are dependent on
processing time and type of immobilized zeolite. Coatings with Ce-exchanged
zeolite show higher photocatalytic activity and more effective corrosion
protection than those with pure zeolite. The highest photocatalytic activity is
observed for coatings processed in pulsed a DC regime for 30 minutes containing
Ce-exchanged 13X zeolite, followed by those containing Ce-exchanged
clinoptilolite. Pronounced anti-corrosion properties feature almost all samples
containing Ce-exchanged 13X zeolite
Insulator to metal transition in WO3 induced by electrolyte gating
Tungsten oxide and its associated bronzes (compounds of tungsten oxide and an alkali metal) are well known for their interesting optical and electrical characteristics. We have modified the transport properties of thin WO3 films by electrolyte gating using both ionic liquids and polymer electrolytes. We are able to tune the resistivity of the gated film by more than five orders of magnitude, and a clear insulator-to-metal transition is observed. To clarify the doping mechanism, we have performed a series of incisive operando experiments, ruling out both a purely electronic effect (charge accumulation near the interface) and oxygen-related mechanisms. We propose instead that hydrogen intercalation is responsible for doping WO3 into a highly conductive ground state and provide evidence that it can be described as a dense polaronic gas
Atomic-Layer Engineering of Oxide Superconductors
Molecular beam epitaxy technique has enabled synthesis of atomically smooth thin films, multilayers, and superlattices of cuprates and other complex oxides. Such heterostructures show high temperature superconductivity and enable novel experiments that probe the basic physics of this phenomenon. For example, it was established that high temperature superconductivity and anti-ferromagnetic phases separate on Ångström scale, while the pseudo-gap state apparently mixes with high temperature superconductivity over an anomalously large length scale (the “Giant Proximity Effect”). We review some recent experiments on such films and superlattices, including X-ray diffraction, atomic force microscopy, angle-resolved time of flight ion scattering and recoil spectroscopy, transport measurements, high- resolution transmission electron microscopy, resonant X-ray scattering, low-energy muon spin resonance, and ultrafast photo-induced reflection high energy electron diffraction. The results include an unambiguous demonstration of strong coupling of in-plane charge excitations to out-of-plane lattice vibrations, a discovery of interface high temperature superconductivity that occurs in a single CuO2 plane, evidence for local pairs, and establishing tight limits on the temperature range of superconducting fluctuations
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