Transmission Electron Study of Heteroepitaxial Growth in the BiSrCaCuO System

Films of Bi$\rm _2$Sr$\rm _2$CaCu$\rm _2$O$\rm _8$ and Bi$\rm _2$Sr$\rm _2$CuO$\rm _6$ have been grown using Atomic-Layer-by-Layer Molecular Beam Epitaxy (ALL-MBE) on lattice-matched substrates. These materials have been combined with layers of closely-related metastable compounds like Bi$\rm _2$Sr$\rm _2$Ca$\rm _7$Cu$\rm _8$O$\rm _{20}$ (2278) and rare-earth-doped compounds like Bi$\rm _2$Sr$\rm _2$Dy$\rm _x$Ca$\rm _{1-x}$Cu$\rm _2$O$\rm _8$ (Dy:2212) to form heterostructures with unique superconducting properties, including superconductor/insulator multilayers and tunnel junctions. Transmission electron microscopy (TEM) has been used to study the morphology and microstructure of these heterostructures. These TEM studies shed light on the physical properties of the films, and give insight into the growth mode of highly anisotropic solids like Bi$\rm _2$Sr$\rm _2$CaCu$\rm _2$O$\rm _8$.Comment: 17 pages, submitted to J. Materials Research. Email to [email protected] if you want to receive copies of the figure

Josephson coupling through ferromagnetic heterojunctions with noncollinear magnetizations

We study the Josephson effect in clean heterojunctions that consist of superconductors connected through two metallic ferromagnets with insulating interfaces. We solve the scattering problem based on the Bogoliubov--de Gennes equation for any relative orientation of in-plane magnetizations, arbitrary transparency of interfaces, and mismatch of Fermi wave vectors. Both spin singlet and triplet superconducting correlations are taken into account, and the Josephson current is calculated as a function of the ferromagnetic layers thicknesses and of the angle $\alpha$ between their magnetizations. We find that the critical Josephson current $I_c$ is a monotonic function of $\alpha$ when the junction is far enough from $0-\pi$ transitions. This holds when ferromagnets are relatively weak. For stronger ferromagnets, variation of $\alpha$ induces switching between 0 and $\pi$ states and $I_c(\alpha)$ is non-monotonic function, displaying characteristic dips at the transitions. However, the non-monotonicity is the effect of a weaker influence of the exchange potential in the case of non-parallel magnetizations. No substantial impact of spin-triplet superconducting correlations on the Josephson current has been found in the clean limit. Experimental control of the critical current and $0-\pi$ transitions by varying the angle between magnetizations is suggested.Comment: 7 pages, 8 figure

Genotoxicity assessment of piperitenone oxide: an in vitro and in silico evaluation

Piperitenone oxide, a natural flavouring agent also known as rotundifolone, has been studied for the genotoxicity assessment by an integrated in vitro and in silico experimental approach, including the bacterial reverse mutation assay, the micronucleus test, the comet assay and the computational prediction by Toxtree and VEGA tools. Under our experimental conditions, the monoterpene showed to induce both point mutations (i.e. frameshift, base-substitution and/or oxidative damage) and DNA damage (i.e. clastogenic or aneuploidic damage, or single-strand breaks). Computational prediction for piperitenone oxide agreed with the toxicological data, and highlighted the presence of the epoxide function and the α,β-unsaturated carbonyl as possible structural alerts for DNA damage. However, improving the toxicological libraries for natural occurring compounds is required in order to favour the applicability of in silico models to the toxicological predictions. Further in vivo evaluations are strictly needed in order to evaluate the role of the bioavailability of the substance and the metabolic fate on its genotoxicity profile. To the best of our knowledge, these data represent the first evaluation of the genotoxicity for this flavour compound and suggest the need of further studies to assess the safety of piperitenone oxide as either flavour or fragrance chemicals

Interface superconductivity: History, developments and prospects

The concept of interface superconductivity was introduced over 50 years ago. Some of the greatest physicists of that time wondered whether a quasi-two-dimensional (2D) superconductor can actually exist, what are the peculiarities of 2D superconductivity, and how does the reduced dimensionality affect the critical temperature (Tc). The discovery of high-temperature superconductors, which are composed of coupled 2D superconducting layers, further increased the interest in reduced dimensionality structures. In parallel, the advances in experimental techniques made it possible to grow epitaxial 2D structures with atomically flat surfaces and interfaces, enabling some of the experiments that were proposed decades ago to be performed finally. Now we know that interface superconductivity can occur at the junction of two different materials (metals, insulators, semiconductors). This phenomenon is being explored intensely; it is also exploited as a means to increase Tc or to study quantum critical phenomena. This research may or may not produce a superconductor with a higher Tc or a useful superconducting electronic device but it will likely bring in new insights into the physics underlying high-temperature superconductivity

Photoemission Evidence for a Remnant Fermi Surface and d-Wave-Like Dispersion in Insulating Ca2CuO2Cl2

An angle resolved photoemission study on Ca2CuO2Cl2, a parent compound of high Tc superconductors is reported. Analysis of the electron occupation probability, n(k) from the spectra shows a steep drop in spectral intensity across a contour that is close to the Fermi surface predicted by the band calculation. This analysis reveals a Fermi surface remnant even though Ca2CuO2Cl2 is a Mott insulator. The lowest energy peak exhibits a dispersion with approximately the |cos(kxa)-cos(kya)| form along this remnant Fermi surface. Together with the data from Dy doped Bi2Sr2CaCu2O(8 + delta) these results suggest that this d-wave like dispersion of the insulator is the underlying reason for the pseudo gap in the underdoped regime.Comment: 9 pages, including 7 figures. Published in Science, one figure correcte

Epitaxial growth of high quality WO3 thin films

We have grown epitaxial WO3 films on various single-crystal substrates using radio frequency magnetron sputtering. While pronounced surface roughness is observed in films grown on LaSrAlO4 substrates, films grown on Y AlO3 substrates show atomically flat surfaces, as demonstrated by atomic force microscopy and X-ray diffraction (XRD) measurements. The crystalline structure has been confirmed to be monoclinic by symmetric and skew-symmetric XRD. The dependence of the growth modes and the surface morphology on the lattice mismatch are discussed

Pairing interactions and pairing mechanism in high temperature copper oxide superconductors

The polaron binding energy E_{p} in undoped parent cuprates has been determined to be about 1.0 eV from the unconventional oxygen-isotope effect on the antiferromagnetic ordering temperature. The deduced value of E_{p} is in quantitative agreement with that estimated from independent optical data and that estimated theoretically from the measured dielectric constants. The substantial oxygen-isotope effect on the in-plane supercarrier mass observed in optimally doped cuprates suggests that polarons are bound into the Cooper pairs. We also identify the phonon modes that are strongly coupled to conduction electrons from the angle-resolved photoemission spectroscopy, tunneling spectra, and optical data. We consistently show that there is a very strong electron-phonon coupling feature at a phonon energy of about 20 meV along the antinodal direction and that this coupling becomes weaker towards the diagonal direction. We further show that high-temperature superconductivity in cuprates is caused by strong electron-phonon coupling, polaronic effect, and significant coupling with 2 eV Cu-O charge transfer fluctuation.Comment: 11 pages, 7 figure