Ab initio Evidence for Giant Magnetoelectric Responses Driven by Structural Softness

We show that inducing structural softness in regular magnetoelectric (ME) multiferroics -- i.e., tuning the materials to make their structure strongly reactive to applied fields -- makes it possible to obtain very large ME effects. We present illustrative first-principles results for BiFeO3 thin films.Comment: 4 pages with 3 figures embedded. More information at http://www.icmab.es/dmmis/leem/jorg

Magnetoelectric response of multiferroic BiFeO3 and related materials

We present a first-principles scheme for computing the magnetoelectric response of multiferroics. We apply our method to BiFeO3 (BFO) and related compounds in which Fe is substituted by other magnetic species. We show that under certain relevant conditions -- i.e., in absence of incommensurate spin modulation, as in BFO thin films and some BFO-based solid solutions -- these materials display a large linear magnetoelectric response. Our calculations reveal the atomistic origin of the coupling and allow us to identify the most promising strategies to enhance it.Comment: 4 pages with 1 figure embedded. More information at http://www.icmab.es/dmmis/leem/jorg

Prediction for new magnetoelectric fluorides

We use symmetry considerations in order to predict new magnetoelectric fluorides. In addition to these magnetoelectric properties, we discuss among these fluorides the ones susceptible to present multiferroic properties. We emphasize that several materials present ferromagnetic properties. This ferromagnetism should enhance the interplay between magnetic and dielectric properties in these materials.Comment: 12 pages, 4 figures, To appear in Journal of Physics: Condensed Matte

Magneto-electric effect in NdCrTiO5

We have measured the dielectric constant and the pyroelectric current of orthorhombic (space group $Pbam$) NdCrTiO$_5$ polycrystalline samples. The dielectric constant and the pyroelectric current show features associated with ferroelectric transitions at the antiferromagnetic transition temperature ($T_{\text{N}}$ = 21 K). The effect of magnetic fields is to enhance the features almost linearly up to the maximum measured field (7 T) with a spontaneous polarization value of $\sim 3.5 \mu$C/m$^2$. Two possible scenarios, the linear magnetoelectric effect and multiferroicity (antiferromagnetism + ferroelectricity), are discussed as possible explanations for the observations.Comment: 7 pages, 6 figure

Multiferroic properties of an \aa kermanite Sr2_2CoSi2_2O7_7 single crystal in high magnetic fields

The magnetic and dielectric properties of \aa kermanite Sr$_2$CoSi$_2$O$_7$ single crystals in high magnetic fields were investigated. We have observed finite induced electric polarization along the c axis in high fields, wherein all Co spins were forcibly aligned to the magnetic field direction. Existence of the induced polarization in the spin-polarized state accompanied with the finite slope in the magnetization curve suggests the possible role of the orbital angular momenta in the excited states as its microscopic origin. The emergence of the field-induced polarization without particular magnetic order can be regarded as the magnetoelectric effects of the second order from the symmetry point of view. A low magnetic field-driven electric polarization flip induced by a rotating field, even at room temperature, has been successfully demonstrated.Comment: 12 pages, 4 figure

U(1)-Symmetry breaking and violation of axial symmetry in TlCuCl3 and other insulating spin systems

We describe the Bose-Einstein condensate of magnetic bosonic quasiparticles in insulating spin systems using a phenomenological standard functional method for T = 0. We show that results that are already known from advanced computational techniques immediately follow. The inclusion of a perturbative anisotropy term that violates the axial symmetry allows us to remarkably well explain a number of experimental features of the dimerized spin-1/2 system TlCuCl3. Based on an energetic argument we predict a general intrinsic instability of an axially symmetric magnetic condensate towards a violation of this symmetry, which leads to the spontaneous formation of an anisotropy gap in the energy spectrum above the critical field. We, therefore, expect that a true Goldstone mode in insulating spin systems, i.e., a strictly linear energy-dispersion relation down to arbitrarily small excitations energies, cannot be observed in any real material.Comment: 6 pages, 3 figure

Near--K-edge double and triple detachment of the F- negative ion: observation of direct two-electron ejection by a single photon

Double and triple detachment of the F-(1s2 2s2 2p6) negative ion by a single photon have been investigated in the photon energy range 660 to 1000 eV. The experimental data provide unambiguous evidence for the dominant role of direct photo-double-detachment with a subsequent single-Auger process in the reaction channel leading to F2+ product ions. Absolute cross sections were determined for the direct removal of a (1s+2p) pair of electrons from F- by the absorption of a single photon