6 research outputs found
Iron-Catalyzed Dioxygen-Driven C–C Bond Formation: Oxidative Dearomatization of 2-Naphthols with Construction of a Chiral Quaternary Stereocenter
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Drastic Enhancement of Activity in Iodane-Based α-Tosyloxylation of Ketones: Iodine(III) Does the Hypervalent Twist
No full textPalladium(0)-Catalyzed Arylative Dearomatization of Phenols
No full textThe palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).National Institutes of Health (U.S.) (Grant GM46059)National Science Foundation (U.S.) (Grant CHE 9808061)National Science Foundation (U.S.) (Grant DBI 9729592
