Effect of argon ion energy on the performance of silicon nitridemultilayer permeation barriers grown by hot-wire CVD on polymers

One of the authors (S.M.) acknowledges Direction des Relations Extérieures of Ecole Polytechnique for financial support.Permeation barriers for organic electronic devices on polymer flexible substrates were realized by combining stacked silicon nitride (SiNx) single layers (50 nm thick) deposited by hot-wire chemical vapor deposition process at low-temperature (~100°C) with a specific argon plasma treatment between two successive layers. Several plasma parameters (RF power density, pressure, treatment duration) as well as the number of single layers have been explored in order to improve the quality of permeation barriers deposited on polyethylene terephthalate. In this work, maximumion energy was highlighted as the crucial parameter making it possible to minimize water vapor transmission rate (WVTR), as determined by the electrical calcium test method, all the other parameters being kept fixed. Thus fixing the plasma treatment duration at 8 min for a stack of two SiNx single layers, a minimum WVTR of 5 × 10−4 g/(m2 day), measured at room temperature, was found for a maximum ion energy of ~30 eV. This minimum WVTR value was reduced to 7 × 10−5 g/(m2 day) for a stack of five SiNx single layers. The reduction in the permeability is interpreted as due to the rearrangement of atoms at the interfaces when average transferred ion energy to target atoms exceeds threshold displacement energy.The authors are grateful to Dr. R. Cortes (PMC, Ecole Polytechnique) for XRR analysis, to Dr. P. Chapon (HORIBA Jobin Yvon) for GD-OES analysis and Dr. J. Leroy (CEA Saclay) for XPS analysis. This work was partly supported by the PICS (FrenchPortuguese) project No. 5336. One of the authors (S.M.) acknowledges Direction des Relations Extérieures of Ecole Polytechnique for financial support

The effect of argon plasma treatment on the permeation barrier properties of silicon nitride layers

In this work we produce and study silicon nitride (SiNx) thin films deposited by Hot Wire Chemical Vapor Depo- sition (HW-CVD) to be used as encapsulation barriers for flexible organic photovoltaic cells fabricated on poly- ethylene terephthalate (PET) substrates in order to increase their shelf lifetime. We report on the results of SiNx double-layers and on the equivalent double-layer stack where an Ar-plasma surface treatment was performed on the first SiNx layer. The Ar-plasma treatment may under certain conditions influences the structure of the interface between the two subsequent layers and thus the barrier properties of the whole system. We focus our attention on the effect of plasma treatment time on the final barrier properties. We assess the encapsulation barrier properties of these layers, using the calcium degradation test where changes in the electrical conductance of encapsulated Ca sensors are monitored with time. The water vapor transmission rate (WVTR) is found to be ~3 × 10−3 g/m2·day for stacked SiNx double-layer with 8 min Ar plasma surface treatment.FCT - CNRS PICS (French–Portuguese no: 5336) projectDirection des Relations Extérieures, Ecole Polytechniqu

Faceting for direction-dependent spectral deconvolution

Reproduced with permission from Astronomy & Astrophysics, © 2018 ESO. Content in the UH Research Archive is made available for personal research, educational, and non-commercial purposes only. Unless otherwise stated, all content is protected by copyright, and in the absence of an open license, permissions for further re-use should be sought from the publisher, the author, or other copyright holder.The new generation of radio interferometers is characterized by high sensitivity, wide fields of view and large fractional bandwidth. To synthesize the deepest images enabled by the high dynamic range of these instruments requires us to take into account the direction-dependent Jones matrices, while estimating the spectral properties of the sky in the imaging and deconvolution algorithms. In this paper we discuss and implement a wideband wide-field spectral deconvolution framework (ddfacet) based on image plane faceting, that takes into account generic direction-dependent effects. Specifically, we present a wide-field co-planar faceting scheme, and discuss the various effects that need to be taken into account to solve for the deconvolution problem (image plane normalization, position-dependent Point Spread Function, etc). We discuss two wideband spectral deconvolution algorithms based on hybrid matching pursuit and sub-space optimisation respectively. A few interesting technical features incorporated in our imager are discussed, including baseline dependent averaging, which has the effect of improving computing efficiency. The version of ddfacet presented here can account for any externally defined Jones matrices and/or beam patterns.Peer reviewe

A MeerKAT-meets-LOFAR study of Abell 1413: a moderately disturbed non-cool-core cluster hosting a ∼500\sim 500 kpc 'mini'-halo

Many relaxed cool-core clusters host diffuse radio emission on scales of hundreds of kiloparsecs: mini-haloes. However, the mechanism responsible for generating them, as well as their connection with central active galactic nuclei, is elusive and many questions related to their physical properties and origins remain unanswered. This paper presents new radio observations of the galaxy cluster Abell 1413 performed with MeerKAT (L-band; 872 to 1712 MHz) and LOFAR HBA (120 to 168 MHz) as part of a statistical and homogeneous census of mini-haloes. Abell 1413 is unique among mini-halo clusters as it is a moderately-disturbed non-cool-core cluster. Our study reveals an asymmetric mini-halo up to 584 kpc in size at 1283 MHz, twice as large as first reported at similar frequencies. The spectral index is flatter than previously reported, with an integrated value of $\alpha = -1.01 \pm 0.06$, shows significant spatial variation, and a tentative radial steepening. We studied the point-to-point X-ray/radio surface brightness correlation to investigate the thermal/non-thermal connection: our results show a strong connection between these components, with a super-linear slope of $b = 1.63 \pm 0.10$ at 1283 MHz and $b = 1.20 \pm 0.12$ at 145 MHz. We also explore the X-ray surface brightness/radio spectral index correlation, finding a slope of $b = 0.59 \pm 0.11$. Both investigations support the evidence of spectral steepening. Finally, in the context of understanding the particle acceleration mechanism, we present a simple theoretical model which demonstrates that hybrid scenarios - secondary electrons (re-)accelerated by turbulence - reproduce a super-linear correlation slope.Comment: 19 pages, 11 figures, 4 tables. Accepted for publication in MNRA

Spectral analysis of spatially resolved 3C295 (sub-arcsecond resolution) with the International LOFAR Telescope

3C295 is a bright, compact steep spectrum source with a well-studied integrated radio spectral energy distribution (SED) from 132 MHz to 15 GHz. However, spatially resolved spectral studies have been limited due to a lack of high resolution images at low radio frequencies. These frequencies are crucial for measuring absorption processes, and anchoring the overall spectral modelling of the radio SED. In this paper, we use International LOw-Frequency ARray (LOFAR) Telescope (ILT) observations of 3C295 to study its spatially resolved spectral properties with sub-arcsecond resolution at 132 MHz. Combining our new 132 MHz observation with archival data at 1.6, 4.8, and 15 GHz, we are able to carry out a resolved radio spectral analysis. The spectral properties of the hotspots provides evidence for low frequency flattening. In contrast, the spectral shape across the lobes is consistent with a Jaffe-Perola spectral ageing model. Using the integrated spectral information for each component, we then fitted low-frequency absorption models to the hotspots, finding that both free-free absorption and synchrotron self-absorption models provide a better fit to the data than a standard power law. Although we can say there is low-frequency absorption present in the hotspots of 3C295, future observations with the Low Band Antenna of the ILT at 55 MHz may allow us to distinguish the type of absorption

The resolved jet of 3C 273 at 150 MHz: sub-arcsecond imaging with the LOFAR international baselines

Galaxie

The coma cluster at low frequency array frequencies. I. Insights into particle acceleration mechanisms in the radio bridge

Radio synchrotron emission from the bridges of low-density gas connecting galaxy clusters and groups is a challenge for particle acceleration processes. In this work, we analyze the Coma radio bridge using new LOw Frequency ARray (LOFAR) observations at 144 MHz. LOFAR detects the bridge and its substructures with unprecedented sensitivity and resolution. We found that the radio emission peaks on the NGC 4839 group. Toward the halo, in front of the NGC 4839 group, the radio brightness decreases and streams of radio emission connect the NGC 4839 group to the radio relic. Using X-ray observations, we found that thermal and non-thermal plasma are moderately correlated with a sublinear scaling. We use archival radio data at 326 MHz to constrain the spectral index in the bridge, and quantify the distribution of particles and magnetic field at different frequencies. We found that the spectrum is steeper than −1.4 ± 0.2, and that the emission is clumpier at 326 MHz than at 144 MHz. Using cosmological simulations and a simplified approach to compute particle acceleration, we derive under which conditions turbulent acceleration of mildly relativistic electrons generate the radio emission in the bridge. Assuming that the initial energy ratio of the seed electrons is 3 · 10−4 with respect to the thermal gas, we are able to reproduce the observed luminosity. Our results suggest that the seed electrons released by radio galaxies in the bridge and the turbulence generated by the motion of gas and galaxies are essential to producing the radio emission