Continental crust in the Davis Strait::new evidence from seabed sampling

Although the structural framework of the subsurface offshore West Greenland has been well documented based on comprehensive seismic analysis (cf. Dalhoff et al. 2003), the stratigraphy of the region is less well known. The oldest documented sedimentary rocks drilled offshore West Greenland are Santonian sandstones reached at TD in the 6354/4-1 well (Fig. 1) although reworked palynomorphs of Carboniferous, Triassic and Jurassic (Kimmeridgian) age have been reported from a number of wells in the region. In order to obtain better constraints on the pre-Upper Cretaceous stratigraphy, a preliminary screening was undertaken to identify inversion structures and erosional canyons where such deeper stratigraphic levels crop out at the seabed (Nielsen et al. 2001). Sea-floor sampling at selected sites between 62° and 67°N (Fig. 1) was undertaken during the summers of 2003 and 2004. Other objectives of these cruises were to seek direct evidence of active petroleum systems, to establish further constraints on tectonic and stratigraphic models, and to obtain a better understanding of the Neogene and Pleistocene history of the region (Dalhoff et al. 2005). The most promising seabed features identified by Nielsen et al. (2001) were investigated in more detail using a wide range of techniques in order to optimise sampling positions. In 2003, these techniques included echo sounder, side-scan sonar, single-channel seismic and video inspection before sampling either by dredge, gravity corer, or by video-controlled grab. In 2004, comprehensive data acquisition with a deep-water sparker system was undertaken before sampling by dredge or gravity corer, supplemented by grab samples at selected stations

Redox element record shows that environmental perturbations associated with the T-OAE were of longer duration than the carbon isotope record suggests – the Aubach section, SW Germany

The Early Jurassic Toarcian Oceanic Anoxic Event (T-OAE) with its associated carbon-isotope excursion (CIE) was possibly one of the most pronounced periods of widespread oxygen deficiency in the Mesozoic ocean. The event has been extensively studied in order to understand the processes triggering the environmental perturbations and the extreme oxygen depletion in many marine basins. However, comparatively little focus has been placed on the end of the positive CIE and the stratigraphic coherent end of anoxiceuxinic conditions. In the present study, we constrain the stratigraphic extent of anoxic-euxinic conditions and define the termination of the positive CIE in the Swabo-Franconian Basin covering the Lower Toarcian strata using carbon-isotope ratios, organic matter pyrolysis and redox-sensitive element concentrations of outcrop samples from the Aubach section. Bulk organic carbon-isotope values, corrected for changes in type of organic matter using the Hydrogen Index (HI), suggest that the amplitude of the negative CIE in organic matter is as little as 3.3–3.5 ‰, in contrast to 4.5 ‰ change in δ13 Ccarb in the same section. Enrichment in redox-sensitive proxies (V/Al and DOP-T) and %TOC suggest that environmental perturbations associated with the T-OAE continued until the upper falciferum Zone in the Aubach section. This indicates that anoxic–euxinic conditions terminated in the same stratigraphic interval in which δ13 C values return to steady, light values at ~–28 ‰ (termination of positive CIE). This synchronism in the return to normal marine conditions is also observed in the southern Paris Basin, but not in the Cleveland Basin

Redox element record shows that environmental perturbations associated with the T-OAE were of longer duration than the carbon isotope record suggests – the Aubach section, SW Germany

The Early Jurassic Toarcian Oceanic Anoxic Event (T-OAE) with its associated carbon-isotope excursion (CIE) was possibly one of the most pronounced periods of widespread oxygen deficiency in the Mesozoic ocean. The event has been extensively studied in order to understand the processes triggering the environmental perturbations and the extreme oxygen depletion in many marine basins. However, comparatively little focus has been placed on the end of the positive CIE and the stratigraphic coherent end of anoxiceuxinic conditions. In the present study, we constrain the stratigraphic extent of anoxic-euxinic conditions and define the termination of the positive CIE in the Swabo-Franconian Basin covering the Lower Toarcian strata using carbon-isotope ratios, organic matter pyrolysis and redox-sensitive element concentrations of outcrop samples from the Aubach section. Bulk organic carbon-isotope values, corrected for changes in type of organic matter using the Hydrogen Index (HI), suggest that the amplitude of the negative CIE in organic matter is as little as 3.3–3.5 ‰, in contrast to 4.5 ‰ change in δ13 Ccarb in the same section. Enrichment in redox-sensitive proxies (V/Al and DOP-T) and %TOC suggest that environmental perturbations associated with the T-OAE continued until the upper falciferum Zone in the Aubach section. This indicates that anoxic–euxinic conditions terminated in the same stratigraphic interval in which δ13 C values return to steady, light values at ~–28 ‰ (termination of positive CIE). This synchronism in the return to normal marine conditions is also observed in the southern Paris Basin, but not in the Cleveland Basin