112 research outputs found
Characterization and Evaluation of Methane Oxidation Catalysts for Dual-Fuel Diesel and Natural Gas Engines
The UK has incentivized the use of natural gas in heavy goods vehicles (HGVs) by converting to dual-fuel (DF) diesel-natural gas systems to reduce noxious and greenhouse gas emissions. Laboratory and on-road measurements of DF vehicles have demonstrated a decrease in CO emissions relative to diesel, but there is an increase in greenhouse gas (COe) emissions because of unburned methane. Decreasing tailpipe emissions of methane via after-treatment devices in lean-burn compression ignition engines is a challenge because of low exhaust temperatures (~400 °C) and the presence of water vapor. In this study, six commercially available methane oxidation catalysts (MOCs) were tested for their application in DF HGV vehicles. Each MOC was characterized in terms of the catalyst platinum group metal (PGM) loading (both Pd and Pt), particle size, catalytic surface area, and Pd:Pt ratio. In addition, the washcoat surface area, pore volume, and pore size were evaluated. The MOC conversion efficiency was evaluated in controlled methane-oxidation experiments with varying temperatures, flow rates, and gas compositions. Characteristic-conversion efficiency correlations demonstrate that the influential MOC characteristics were PGM loading (both Pd and Pt), Pd:Pt ratio, washcoat surface area, and washcoat pore volume. With 90 % methane oxidation at less than 400 °C in DF HGV exhaust conditions, sample 1 had the highest conversion efficiency because of a high PGM loading (330 g/ft, 12,000 g/m), a 5.9 Pd:Pt ratio, a high alumina washcoat surface area of 20 m/cm, and 74-mm/cm pore volume. Additional studies showed increased MOC conversion efficiency with decreasing gas hourly space velocities (GHSVs) and increasing methane concentrations.We acknowledge support from the UK Engineering and Physical Sciences Research Council (EP/K00915X/1), the UK Department for Transport, the Office for Low Emission Vehicles and Innovate UK (project reference 400266), and the industrial partners of the Centre for Sustainable Road Freight. GreenUrban Technologies Ltd. (3) and Prins Autogas UK Ltd. (1) provided the samples for testing in this study
One particle interchain hopping in coupled Hubbard chains
Interchain hopping in systems of coupled chains of correlated electrons is
investigated by exact diagonalizations and Quantum-Monte-Carlo methods. For two
weakly coupled Hubbard chains at commensurate densities (e.g. n=1/3) the
splitting at the Fermi level between bonding and antibonding bands is strongly
reduced (but not suppressed) by repulsive interactions extending to a few
lattice spacings. The magnitude of this reduction is directly connected to the
exponent of the 1D Luttinger liquid. However, we show that the
incoherent part of the single particle spectral function is much less affected
by the interchain coupling. This suggests that incoherent interchain hopping
could occur for intermediate values.Comment: 4 pages, LaTeX 3.0, 7 PostScript figures in uuencoded for
Spin-Density-Wave Phase Transitions in Quasi-One-Dimensional Dimerized Quarter-Filled Organic Conductors
We have studied spin density wave (SDW) phase transitions in dimerized
quarter-filled Hubbard chains weakly coupled via interchain one-particle
hopping, . It is shown that there exists a critical value of ,
, between the incoherent metal regime () and the
Fermi liquid regime () in the metallic phase above the SDW
transition temperature. By using the 2-loop perturbative renormalization-group
approach together with the random-phase-approximation, we propose a SDW phase
diagram covering both of the regimes. The SDW phase transition from the
incoherent metal phase for is caused by growth of the
intrachain electron-electron umklapp scattering toward low temperatures, which
is regarded as preformation of the Mott gap. We discuss relevance of the
present result to the SDW phase transitions in the quasi-one-dimensional
dimerized quarter-filled organic conductors, (TMTTF)X and (TMTSF)X.Comment: 19 pages, 13 eps figures, uses jpsj.sty, corrected typo in the text
and figures, no changes to the paper, to appear in J. Phys. Soc. Jpn. 68,
No.8 (1999
Impurity-induced stabilization of Luttinger liquid in quasi-one-dimensional conductors
It is shown theoretically that the Luttinger liquid phase in
quasi-one-dimensional conductors can exist in the presence of impurities in a
form of a collection of bounded Luttinger liquids. The conclusion is based upon
the observation by Kane and Fisher that a local impurity potential in Luttinger
liquid acts, at low energies, as an infinite barrier. This leads to a discrete
spectrum of collective charge and spin density fluctuations, so that interchain
hopping can be considered as a small parameter at temperatures below the
minimum excitation energy of the collective modes. The results are compared
with recent experimental observation of a Luttinger-liquid-like behavior in
thin NbSe and TaS wires.Comment: 11 pages, revtex, final version published in JETP Lett
Superconductivuty versus Tunneling in a Doped Antiferromagnetic Ladder
The low-energy charge excitations of a doped antiferromagnetic ladder are
modeled by a system of interacting spinless fermions that live on the same
ladder. A relatively large spin gap is assumed to ``freeze out'' all spin
fluctuations. We find that the formation of rung hole pairs coincides with the
opening of a single-particle gap for charge excitations along chains and with
the absence of coherent tunneling in between chains. We also find that such
hole pairs condense into either a crystalline or superconducting state as a
function of the binding energy.Comment: 15 pgs. in PLAIN TeX, 2 figs. in postscript, to appear in Phys. Rev.
Strong-Coupling Expansion for the Hubbard Model
A strong-coupling expansion for models of correlated electrons in any
dimension is presented. The method is applied to the Hubbard model in
dimensions and compared with numerical results in . Third order expansion
of the Green function suffices to exhibit both the Mott metal-insulator
transition and a low-temperature regime where antiferromagnetic correlations
are strong. It is predicted that some of the weak photoemission signals
observed in one-dimensional systems such as should become stronger as
temperature increases away from the spin-charge separated state.Comment: 4 pages, RevTex, 3 epsf figures include
Dimensional Crossovers in the Doped Ladder System: Spin Gap, Superconductivity and Interladder Coherent Band Motion
Based on the perturbative renormalization group (PRG) approach, we have
studied dimensional crossovers in Hubbard ladders coupled via weak interladder
one-particle hopping, . We found that the one-particle crossover is
strongly suppressed through growth of the intraladder scattering processes
which lead the isolated Hubbard ladder system toward the spin gap metal (SGM)
phase. Consequently when sets in, there exists, for any finite
intraladder Hubbard repulsion, , the region where the two-particle
crossover dominates the one-particle crossover and consequently the d-wave
superconducting transition, which is regarded as a bipolaron condensation,
occurs. By solving the scaling equations for the interladder one-particle and
two-particle hopping amplitudes, we give phase diagrams of the system with
respect to , (initial value of ) and the
temperature, . We compared the above dimensional crossovers with those in a
weakly coupled chain system, clarifying the difference between them.Comment: 26 pages, 19 eps figures, to appear J. Phys. Soc. Jpn. Vol.67 No.
Interaction-induced Fermi surface deformations in quasi one-dimensional electronic systems
We consider serious conceptual problems with the application of standard
perturbation theory, in its zero temperature version, to the computation of the
dressed Fermi surface for an interacting electronic system. In order to
overcome these difficulties, we set up a variational approach which is shown to
be equivalent to the renormalized perturbation theory where the dressed Fermi
surface is fixed by recursively computed counterterms. The physical picture
that emerges is that couplings that are irrelevant tend to deform the Fermi
surface in order to become more relevant (irrelevant couplings being those that
do not exist at vanishing excitation energy because of kinematical constraints
attached to the Fermi surface). These insights are incorporated in a
renormalization group approach, which allows for a simple approximate
computation of Fermi surface deformation in quasi one-dimensional electronic
conductors. We also analyze flow equations for the effective couplings and
quasiparticle weights. For systems away from half-filling, the flows show three
regimes corresponding to a Luttinger liquid at high energies, a Fermi liquid,
and a low-energy incommensurate spin-density wave. At half-filling Umklapp
processes allow for a Mott insulator regime where the dressed Fermi surface is
flat, implying a confined phase with vanishing effective transverse
single-particle coherence. The boundary between the confined and Fermi liquid
phases is found to occur for a bare transverse hopping amplitude of the order
of the Mott charge gap of a single chain.Comment: 38 pages, 39 figures. Accepted for publication in Phys. Rev.
Dynamical Properties of one dimensional Mott Insulators
At low energies the charge sector of one dimensional Mott insulators can be
described in terms of a quantum Sine-Gordon model. Using exact results derived
from integrability it is possible to determine dynamical properties like the
frequency dependent optical conductivity. We compare the exact results to
perturbation theory and renormalisation group calculations. We also discuss the
application of our results to experiments on quasi-1D organic conductors.Comment: 17 pages, 5 figures, to appear in the proceedings of the NATO ASI/EC
summer school "New Theoretical Approaches to Strongly Correlated Systems"
Newton Institute for Mathematical Sciences, Cambridge UK, April 200
On-chain electrodynamics of metallic (TMTSF)_2 X salts: Observation of Tomonaga-Luttinger liquid response
We have measured the electrodynamic response in the metallic state of three
highly anisotropic conductors, (TMTSF)_2 X, where X=PF_6, AsF_6, or ClO_4, and
TMTSF is the organic molecule tetramethyltetraselenofulvalene. In all three
cases we find dramatic deviations from a simple Drude response. The optical
conductivity has two features: a narrow mode at zero frequency, with a small
spectral weight, and a mode centered around 200 cm^{-1}, with nearly all of the
spectral weight expected for the relevant number of carriers and single
particle bandmass. We argue that these features are characteristic of a nearly
one-dimensional half- or quarter-filled band with Coulomb correlations, and
evaluate the finite energy mode in terms of a one-dimensional Mott insulator.
At high frequencies (\hbar\omega > t_\perp, the transfer integral perpendicular
to the chains), the frequency dependence of the optical conductivity
\sigma_1(\omega) is in agreement with calculations based on an interacting
Tomonaga-Luttinger liquid, and is different from what is expected for an
uncorrelated one-dimensional semiconductor. The zero frequency mode shows
deviations from a simple Drude response, and can be adequately described with a
frequency dependent mass and relaxation rate.Comment: 12 pages, 7 figures, RevTeX; minor corrections to text and
references; To be published in Phys. Rev. B, 15 July 199
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