Utilization of recycled polypropylene, cellulose and newsprint fibres for production of green composites

This work investigates the feasibility of using the recycled polypropylene (rPP), cellulose (CF) and newsprint (NP) fibres in polyolefin reinforced composites. Recycled PP filled with 40 wt.% of cellulose (rPP/CF) or newsprint (rPP/NP), with the addition of impact modifier (IM) and compatibilizing agent (CA), have been prepared with ex-trusion melting and injection moulding. Melting and crystallization behaviour of plain matrix and composites were measured by differential scanning calorimetry (DSC). Morphological and mechanical properties were also studied using scanning electron microscope (SEM) and tensile testing, respectively. Thermal stability of composites was similar to neat rPP for both types of the filler used. Though, the crystallinity was progressively decreased with the addition of CF or NP. The DSC further revealed an occurrence of the two distinct melting transitions, meaning that the examined materials were not based on pure polypropylene (PP), but are rather blends of high-density polyethylene (HDPE) and PP, what has been confirmed also by the Fourier transform infrared spectroscopy (FTIR). The largest single source of contaminations in recycled PP comes from HDPE since both polymers are identified by a similar density and can be accidentally mixed during the conventional physical separation process. Composites reinforced with CF have shown better mechanical performances than those based on reclaimed NP fibres, what can be attributed to the initial fibre quality. Tensile strength of the composites filled with CF and NP fibres was 36 MPa and 29 MPa, respectively, in disparity to 23 MPa measured for neat rPP. The fibre addition further resulted in substantial increase in Young modulus of the composites. The addition of CF and NP fibres lead to an improved modulus of elasticity by 16 and 47%, respectively. Waste paper in the form of recovered cellulose or reclaimed newsprint fibre can thus meet all the technical requirements to become an alternative to inor-ganic fillers in thermoplastic composites

Governance of interdependent ecosystem services and common-pool resources

Environmental governance is recognized as a key issue in many natural and social sciences. It is highly relevant for ecosystem services and common-pool resources as well. Both fields overlap yet have typically been studied separately. Therefore, this study aimed a) to examine the emerging body of literature that incorporates concepts from both fields of research and considers governance challenges, and b) to identify policy tools and recommendations presented for addressing those challenges. The analysis of thirty-nine selected peer-review papers revealed the multiplicity of interacting governance challenges with three major categories: environmental, socioeconomic, and problems of governance itself. Governance is impeded by institutional mismatches, exclusion of local actors, corruption, and perverse policies. The proposed policy recommendations most often suggest changes in institutional arrangements and increasing scientific understanding. Meeting human needs, and increasing social equity and justice were recognized broadly as integral for improving governance, yet correlations among governance problems and solutions appear elusive. These findings extend theoretical reasoning, while carrying practical implications for policy, governance and environmental stewardship. The analysis implies that policies to improve human conditions will be key for improved environmental governance, but more research is needed to learn which types of policy recommendations prove successful given diverse local contexts

SLOCLIM: a high-resolution daily gridded precipitation and temperature dataset for Slovenia

We present a new publicly available daily gridded dataset of maximum and minimum temperature and precipitation data covering the whole territory of Slovenia from 1950 to 2018. It represents the great variability of climate at the crossroads between the Mediterranean, Alpine and continental climatic regimes with altitudes between 0-2864ma.s.l. We completely reconstructed (quality control and gap filling) the data for the three variables from 174 observatories (climatological, precipitation and automatic stations) with the original records all over the country. A comprehensive quality control process based on the spatial coherence of the data was applied to the original dataset, and the missing values were estimated for each day and location independently. Using the filled data series, a grid of 1 x 1 km spatial resolution with 20 998 points was created by estimating daily temperatures (minimum and maximum) and precipitation, as well as their corresponding uncertainties at each grid point. In order to show the potential applications, four daily temperature indices and two on precipitation were calculated to describe the spatial distribution of (1) the absolute maximum and minimum temperature, (2) the number of frost days, (3) the number of summer days, (4) the intensity of precipitation and (5) the maximum number of consecutive dry days. The use of all the available information, the complete quality control and the high spatial resolution of the grid allowed for an accurate estimate of precipitation and temperature that represents a precise spatial and temporal distribution of daily temperatures and precipitation in Slovenia. The SLOCLIM dataset is publicly available at https://doi.org/10.5281/zenodo.4108543 and http://www.sloclim.eu (last access: 10 June 2021) and can be cited as Skrk et al. (2020)

New Insights in ATP Synthesis as Therapeutic Target in Cancer and Angiogenic Ocular Diseases.

Lactate and ATP formation by aerobic glycolysis, the Warburg effect, is considered a hallmark of cancer. During angiogenesis in non-cancerous tissue, proliferating stalk endothelial cells (ECs) also produce lactate and ATP by aerobic glycolysis. In fact, all proliferating cells, both non-cancer and cancer cells, need lactate for the biosynthesis of building blocks for cell growth and tissue expansion. Moreover, both non-proliferating cancer stem cells in tumors and leader tip ECs during angiogenesis rely on glycolysis for pyruvate production, which is used for ATP synthesis in mitochondria through oxidative phosphorylation (OXPHOS). Therefore, aerobic glycolysis is not a specific hallmark of cancer but rather a hallmark of proliferating cells and limits its utility in cancer therapy. However, local treatment of angiogenic eye conditions with inhibitors of glycolysis may be a safe therapeutic option that warrants experimental investigation. Most types of cells in the eye such as photoreceptors and pericytes use OXPHOS for ATP production, whereas proliferating angiogenic stalk ECs rely on glycolysis for lactate and ATP production. (J Histochem Cytochem XX.XXX-XXX, XXXX)