First results on Martian carbon monoxide from Herschel/HIFI observations

We report on the initial analysis of Herschel/HIFI carbon monoxide (CO) observations of the Martian atmosphere performed between 11 and 16 April 2010. We selected the (7–6) rotational transitions of the isotopes ^(13)CO at 771 GHz and C^(18)O and 768 GHz in order to retrieve the mean vertical profile of temperature and the mean volume mixing ratio of carbon monoxide. The derived temperature profile agrees within less than 5 K with general circulation model (GCM) predictions up to an altitude of 45 km, however, show about 12–15 K lower values at 60 km. The CO mixing ratio was determined as 980 ± 150 ppm, in agreement with the 900 ppm derived from Herschel/SPIRE observations in November 2009

High-Resolution 4.7 Micron Keck/NIRSPEC Spectra of Protostars. II. Detection of the ^(13)CO Isotope in Icy Grain Mantles

The high-resolution (R = 25,000) infrared M-band spectrum of the massive protostar NGC 7538 IRS 9 shows a narrow absorption feature at 4.779 μm (2092.3 cm^(-1)) that we attribute to the vibrational stretching mode of the ^(13)CO isotope in pure CO icy grain mantles. This is the first detection of ^(13)CO in icy grain mantles in the interstellar medium. The ^(13)CO band is a factor of 2.3 narrower than the apolar component of the ^(12)CO band. With this in mind, we discuss the mechanisms that broaden solid-state absorption bands. It is shown that ellipsoidally shaped pure CO grains fit the bands of both isotopes at the same time. Slightly worse but still reasonable fits are also obtained by CO embedded in N_2-rich ices and thermally processed O_2-rich ices. In addition, we report new insights into the nature and evolution of interstellar CO ices by comparing the very high resolution multicomponent solid ^(12)CO spectrum of NGC 7538 IRS 9 with that of the previously studied low-mass source L1489 IRS. The narrow absorption of apolar CO ices is present in both spectra but much stronger in NGC 7538 IRS 9. It is superposed on a smooth broad absorption feature well fitted by a combination of CO_2 and H_2O-rich laboratory CO ices. The abundances of the latter two ices, scaled to the total H_2O ice column, are the same in both sources. We thus suggest that thermal processing manifests itself as evaporation of apolar ices only and not the formation of CO_2 or polar ices. Finally, the decomposition of the ^(12)CO band is used to derive the ^(12)CO/^(13)CO abundance ratio in apolar ices. A ratio of ^(12)CO/^(13)CO = 71 ± 15 (3 σ) is deduced, in good agreement with gas-phase CO studies (~77) and the solid ^(12)CO_2/^(13)CO_2 ratio of 80 ± 11 found in the same line of sight. The implications for the chemical path along which CO_2 is formed are discussed

Methane Abundance Variations toward the Massive Protostar NGC 7538 : IRS9

Absorption and emission lines originating from the nu3 C-H stretching manifold of gas phase CH4 were discovered in the high resolution (R=25,000) infrared L band spectrum along the line of sight toward NGC 7538 : IRS9. These observations provide a diagnostic of the complex dynamics and chemistry in a massive star forming region. The line shapes resemble P Cygni profiles with the absorption and emission components shifted by ~7 km/s with respect to the systemic velocity. Similar velocity components were observed in CO at 4.7 um, but in contrast to CH4, the CO shows deep absorption due to a high velocity outflow as well as absorption at the systemic velocity due to the cold outer envelope. It is concluded that the gas phase CH4 abundance varies by an order of magnitude in this line of sight: it is low in the envelope and the outflow (X[CH4]<0.4e-6), and at least a factor of 10 larger in the central core. The discovery of solid CH4 in independent ground and space based data sets shows that methane is nearly entirely frozen onto grains in the envelope. It thus appears that CH4 is formed by grain surface reactions, evaporates into the gas phase in the warm inner regions of protostellar cores and is efficiently destroyed in shocks related to outflows.Comment: Scheduled for publication in ApJ 615, 01 Nov. 2004. 11 page

On the Interpretation of the broad-band millimeter-wave flux from Orion

Spectral observations of the core of Orion A at wavelengths around 1.3 mm show a high density of strong, broad emission lines. The combined flux in lines with peak antenna temperatures stronger than 0.2 K accounts for approximately 40 percent of the broad-band millimeter-wave flux from the region. Thus the broad-band flux from Orion A is in large part due to sources other than dust emission

Molecular abundances in OMC-1: The chemical composition of interstellar molecular clouds and the influence of massive star formation

We present here an investigation of the chemical composition of the various regions in the core of the Orion molecular cloud (OMC-1) based on results from the Caltech Owens Valley Radio Observatory (OVRO) millimeter-wave spectral line survey (Sutton et al.; Blake et al.). This survey covered a 55 GHz interval in the 1.3 mm (230 GHz) atmospheric window and contained emission from over 800 resolved spectral features. Of the 29 identified species 14 have a sufficient number of detected transitions to be investigated with an LTE "rotation diagram" technique, in which large numbers of lines are used to estimate both the rotational excitation and the overall abundance. The rotational temperatures and column densities resulting from these fits have then been used to model the emission from those remaining species which either have too few lines or which are too weak to be so analyzed. When different kinematic sources of emission are blended to produce a single feature, Gaussian fits have been used to derive the individual contributions to the total line profile. The uniformly calibrated data in the unique and extensive Caltech spectral line survey lead to accurate estimates of the chemical and physical parameters of the Orion molecular cloud, and place significant constraints on models of interstellar chemistry. A global analysis of the observed abundances shows that the markedly different chemical compositions of the kinematically and spatially distinct Orion subsources may be interpreted in the framework of an evolving, initially quiescent, gas-phase chemistry influenced by the process of massive star formation. The chemical composition of the extended Orion cloud complex is similar to that found in a number of other objects, but the central regions of OMC-1 have had their chemistry selectively altered by the radiation and high-velocity outflow from the young stars embedded deep within the interior of the molecular cloud. Specifically, the extended ridge clouds are inferred to have a low (subsolar) gas-phase oxygen content from the prevalence of reactive carbon-rich species like CN, CCH, and C_3H_2 also found in more truly quiescent objects such as TMC-1. The similar abundances of these and other simple species in clouds like OMC-1, Sgr B2, and TMC-1 lend support to gas-phase ion-molecule models of interstellar chemistry, but grain processes may also play a significant role in maintaining the overall chemical balance in such regions through selective depletion mechanisms and grain mantle processing. In contrast, the chemical compositions of the more turbulent plateau and hot core components of OMC-1 are dominated by high-temperature, shock-induced gas and grain surface neutral-neutral reaction processes. The high silicon/sulfur oxide and water content of the plateau gas is best modeled by fast shock disruption of smaller grain cores to release the more refractory elements followed by a predominantly neutral chemistry in the cooling postshock regions, while a more passive release of grain mantle products driven toward kinetic equilibrium most naturally explains the prominence of fully hydrogenated N-containing species like HCN, NH_3 , CH_3CN, and C_2H_5CN in the hot core. The clumpy nature of the outflow is illustrated by the high-velocity emission observed from easily decomposed molecules such as H_2CO. Areas immediately adjacent to the shocked core in which the cooler, ion-rich gas of the surrounding molecular cloud is mixed with water/oxygen rich gas from the plateau source are proposed to give rise to the enhanced abundances of complex internal rotors such as CH_30H, HCOOCH_3 , and CH_30CH_3 whose line widths are similar to carbon-rich species such as CN and CCH found in the extended ridge, but whose rotational temperatures are somewhat higher and whose spatial extents are much more compact

CO Rovibrational Emission as a Probe of Inner Disk Structure

We present an analysis of CO emission lines from a sample of T Tauri, Herbig Ae/Be, and transitional disks with known inclinations in order to study the structure of inner disk molecular gas. We calculate CO inner radii by fitting line profiles with a simple parameterized model. We find that, for optically thick disks, CO inner radii are strongly correlated with the total system luminosity (stellar plus accretion) and consistent with the dust sublimation radius. Transitional disk inner radii show the same trend with luminosity, but are systematically larger. Using rotation diagram fits, we derive, for classical T Tauri disks, emitting areas consistent with a ring of width ~0.15 AU located at the CO inner radius; emitting areas for transitional disks are systematically smaller. We also measure lower rotational temperatures for transitional disks, and disks around Herbig Ae/Be stars, than for those around T Tauri stars. Finally, we find that rotational temperatures are similar to, or slightly lower than, the expected temperature of blackbody grains located at the CO inner radius, in contrast to expectations of thermal decoupling between gas and dust

HIFI observations of water in the atmosphere of comet C/2008 Q3 (Garradd)

High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres.We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 2_(12)−1_(01) (1669 GHz) ortho and 1_(11)−0_(00) (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 1_(10)−1_(01) at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7−2.8 × 10^(28) s^(−1) over the range r_h = 1.83−1.85 AU

The rotational emission-line spectrum of Orion A between 247 and 263 GHz

Results are presented from a molecular line survey of the core of the Orion molecular cloud between 247 and 263 GHz. The spectrum contains a total of 243 resolvable lines from 23 different chemical species. When combined with the earlier survey of Orion from 215 to 247 GHz by Sutton et al. (1985), the complete data set includes over 780 emission features from 29 distinct molecules. Of the 23 molecules detected in this survey, only NO, CCH, and HCO^+ were not identified in the lower frequency data. As a result of the supporting laboratory spectroscopy performed to supplement existing millimeter-wave spectral line catalogs, only 33 of the more than 780 lines remain unidentified, of which 16 occur in the upper frequency band. A significant chance remains that a number of these unidentified lines are due to transitions between states of either isotopically substituted or highly excited abundant and complex molecules such as CH_3OH, CH_3OCH_3, and HCOOCH_3, whose rotational spectra are poorly known at present. The very small percentage and weak strength of the unidentified lines implies that the dominant chemical constituents visible at millimeter wavelengths have been identified in the Orion molecular cloud

Observations of pre-stellar cores

Our understanding of the physical and chemical structure of pre-stellar cores, the simplest star-forming sites, has significantly improved since the last IAU Symposium on Astrochemistry (South Korea, 1999). Research done over these years has revealed that major molecular species like CO and CS systematically deplete onto dust grains at the interior of pre-stellar cores, while species like N2H+ and NH3 survive in the gas phase and can usually be detected towards the core centers. Such a selective behaviour of molecular species gives rise to a differentiated (onion-like) chemical composition, and manifests itself in molecular maps as a dichotomy between centrally peaked and ring-shaped distributions. From the point of view of star-formation studies, the identification of molecular inhomogeneities in cores helps to resolve past discrepancies between observations made using different tracers, and brings the possibility of self-consistent modelling of the core internal structure. Here I present recent work on determining the physical and chemical structure of two pre-stellar cores, L1498 and L1517B, using observations in a large number of molecules and Monte Carlo radiative transfer analysis. These two cores are typical examples of the pre-stellar core population, and their chemical composition is characterized by the presence of large freeze out holes in most molecular species. In contrast with these chemically processed objects, a new population of chemically young cores has started to emerge. The characteristics of its most extreme representative, L1521E, are briefly reviewed.Comment: 10 pages, 5 figures. To appear in IAU 231 conf. proc. "Astrochemistry: Recent Successes and Current Challenges," eds. D.C. Lis, G.A. Blake, and E. Herbs