Ages of 24 widespread tephras erupted since 30,000 years ago in New Zealand, with re-evaluation of the timing and palaeoclimatic implications of the Lateglacial cool episode recorded at Kaipo bog

Tephras are important for the NZ-INTIMATE project because they link all three records comprising the composite inter-regional stratotype developed for the New Zealand climate event stratigraphy (NZ-CES). Here we firstly report new calendar ages for 24 widespread marker tephras erupted since 30,000 calendar (cal.) years ago in New Zealand to help facilitate their use as chronostratigraphic dating tools for the NZ-CES and for other palaeoenvironmental and geological applications. The selected tephras comprise 12 rhyolitic tephras from Taupo, nine rhyolitic tephras from Okataina, one peralkaline rhyolitic tephra from Tuhua, and one andesitic tephra each from Tongariro and Egmont/Taranaki volcanic centres. Age models for the tephras were obtained using three methods: (i) 14C-based wiggle-match dating of wood from trees killed by volcanic eruptions (these dates published previously); (ii) flexible depositional modelling of a high-resolution 14C-dated age-depth sequence at Kaipo bog using two Bayesian-based modelling programs, Bacon and OxCal's P_Sequence function, and the IntCal09 data set (with SH offset correction -44 ± 17 yr); and (iii) calibration of 14C ages using OxCal's Tau_Boundary function and the SHCal04 and IntCal09 data sets. Our preferred dates or calibrated ages for the 24 tephras are as follows (youngest to oldest, all mid-point or mean ages of 95% probability ranges): Kaharoa AD 1314 ± 12; Taupo (Unit Y) AD 232 ± 10; Mapara (Unit X) 2059 ± 118 cal. yr BP; Whakaipo (Unit V) 2800 ± 60 cal. yr BP; Waimihia (Unit S) 3401 ± 108 cal. yr BP; Stent (Unit Q) 4322 ± 112 cal. yr BP; Unit K 5111 ± 210 cal. yr BP; Whakatane 5526 ± 145 cal. yr BP; Tuhua 6577 ± 547 cal. yr BP; Mamaku 7940 ± 257 cal. yr BP; Rotoma 9423 ± 120 cal. yr BP; Opepe (Unit E) 9991 ± 160 cal. yr BP; Poronui (Unit C) 11,170 ± 115 cal. yr BP; Karapiti (Unit B) 11,460 ± 172 cal. yr BP; Okupata 11,767 ± 192 cal. yr BP; Konini (bed b) 11,880 ± 183 cal. yr BP; Waiohau 14,009 ± 155 cal. yr BP; Rotorua 15,635 ± 412 cal. yr BP; Rerewhakaaitu 17,496 ± 462 cal. yr BP; Okareka 21,858 ± 290 cal. yr BP; Te Rere 25,171 ± 964 cal. yr BP; Kawakawa/Oruanui 25,358 ± 162 cal. yr BP; Poihipi 28,446 ± 670 cal. yr BP; and Okaia 28,621 ± 1428 cal. yr BP. Secondly, we have re-dated the start and end of the Lateglacial cool episode (climate event NZce-3 in the NZ-CES), previously referred to as the Lateglacial climate reversal, as defined at Kaipo bog in eastern North Island, New Zealand, using both Bacon and OxCal P_Sequence modelling with the IntCal09 data set. The ca 1200-yr-long cool episode, indicated by a lithostratigraphic change in the Kaipo peat sequence to grey mud with lowered carbon content, and a high-resolution pollen-derived cooling signal, began 13,739 ± 125 cal. yr BP and ended 12,550 ± 140 cal. yr BP (mid-point ages of the 95% highest posterior density regions, Bacon modelling). The OxCal modelling, generating almost identical ages, confirmed these ages. The Lateglacial cool episode (ca 13.8-12.6 cal. ka BP) thus overlaps a large part of the entire Antarctic Cold Reversal chronozone (ca 14.1-12.4 cal. ka BP or ca 14.6-12.8 cal. ka BP), and an early part of the Greenland Stadial-1 (Younger Dryas) chronozone (ca 12.9-11.7 cal. ka BP). The timing of the Lateglacial cool episode at Kaipo is broadly consistent with the latitudinal patterns in the Antarctic Cold Reversal signal suggested for the New Zealand archipelago from marine and terrestrial records, and with records from southern South America

Microcomputer-controlled polarographic instrumentation and its use in the determination of stability constants of crown ether complexes

A computer-controlled polarographic system is described, based on a commercially available polarograph interfaced to a microcomputer. Experiments are controlled and monitored entirely from software, including automatic evaluation of the Tast polarograms and addition of solutions to the polarographic cell from a motor burette. The program was written in FORTH, a computer language especially apt for laboratory automation. The system is used in the determination of stability constants of crown ether complexes

Polarographic determination of malononitrile

A procedure is proposed for the determination of malononitrile by differential pulse polarography in methanolic 0.1M tetraethylammonium iodide/0.001M tetramethylammonium hydroxide as the supporting electrolyte. In this medium malononitrile is chemically converted into an electroactive species. With close control of timing of the steps in the procedure the error of the method is ±1.5% in the concentration range 0.0001–0.001M. Acrylonitrile, benzonitrile and succinic acid dinitrile do not interfere

The origin of runaway stars

Milli-arcsecond astrometry provided by Hipparcos and by radio observations makes it possible to retrace the orbits of some of the nearest runaway stars and pulsars to determine their site of origin. The orbits of the runaways AE Aurigae and mu Columbae and of the eccentric binary iota Orionis intersect each other about 2.5 Myr ago in the nascent Trapezium cluster, confirming that these runaways were formed in a binary-binary encounter. The path of the runaway star zeta Ophiuchi intersects that of the nearby pulsar PSR J1932+1059, about 1 Myr ago, in the young stellar group Upper Scorpius. We propose that this neutron star is the remnant of a supernova that occurred in a binary system which also contained zeta Oph, and deduce that the pulsar received a kick velocity of about 350 km/s in the explosion. These two cases provide the first specific kinematic evidence that both mechanisms proposed for the production of runaway stars, the dynamical ejection scenario and the binary-supernova scenario, operate in nature.Comment: 5 pages, including 2 eps-figures and 1 table, submitted to the ApJ Letters. The manuscript was typeset using aaste

Bedreigingen, persterijen en suicidaliteit in detentie

achtergrond Onderzoek van Blaauw en Kerkhof onderscheidde 16 indicatoren voor verhoogd suïciderisico in een gedetineerdenpopulatie. Deze indicatoren suggereren dat het hoge suïcidecijfer in penitentiaire inrichtingen het gevolg is van blootstelling van kwetsbare personen aan een stressvolle situatie. Hierdoor is een verband te verwachten tussen pesterijen, bedreigingen en suïcidaliteit. Deze verwachting wordt door onderzoeken indirect ondersteund. doel Nagaan of pesterijen en bedreigingen samenhangen met verhoogd suïciderisico en of de door Blaauw en Kerkhof onderscheiden persoonsgebonden risicofactoren samenhangen met het ervaren van pesterijen of bedreigingen. methode Meldingen van bedreigingen en pesterijen werden nagegaan in dossiers van 95 gedetineerden die suïcide hadden gepleegd, en interviews werden afgenomen van 221 gedetineerden met laag suïciderisico en 53 gedetineerden met hoog suïciderisico. resultaten In 34% van de dossiers stond weergegeven dat de suïcidepleger zich gepest en/of bedreigd had gevoeld. Pesterijen en bedreigingen kwamen vaker voor onder suïcidale gedetineerden dan onder niet-suïcidale gedetineerden. Verbanden werden gevonden tussen pesterijen en bedreigingen enerzijds en indicatoren voor kwetsbaarheid anderzijds. conclusie Pesterijen en bedreigingen hebben een relatie met suïcidaliteit onder gedetineerden

Triggered Star Formation by Massive Stars

We present our diagnosis of the role that massive stars play in the formation of low- and intermediate-mass stars in OB associations (the Lambda Ori region, Ori OB1, and Lac OB1 associations). We find that the classical T Tauri stars and Herbig Ae/Be stars tend to line up between luminous O stars and bright-rimmed or comet-shaped clouds; the closer to a cloud the progressively younger they are. Our positional and chronological study lends support to the validity of the radiation-driven implosion mechanism, where the Lyman continuum photons from a luminous O star create expanding ionization fronts to evaporate and compress nearby clouds into bright-rimmed or comet-shaped clouds. Implosive pressure then causes dense clumps to collapse, prompting the formation of low-mass stars on the cloud surface (i.e., the bright rim) and intermediate-mass stars somewhat deeper in the cloud. These stars are a signpost of current star formation; no young stars are seen leading the ionization fronts further into the cloud. Young stars in bright-rimmed or comet-shaped clouds are likely to have been formed by triggering, which would result in an age spread of several megayears between the member stars or star groups formed in the sequence.Comment: 2007, ApJ, 657, 88

Representations of celestial coordinates in FITS

In Paper I, Greisen & Calabretta (2002) describe a generalized method for assigning physical coordinates to FITS image pixels. This paper implements this method for all spherical map projections likely to be of interest in astronomy. The new methods encompass existing informal FITS spherical coordinate conventions and translations from them are described. Detailed examples of header interpretation and construction are given.Comment: Consequent to Paper I: "Representations of world coordinates in FITS". 45 pages, 38 figures, 13 tables, aa macros v5.2 (2002/Jun). Both papers submitted to Astronomy & Astrophysics (2002/07/19). Replaced to try to get figure and table placement right (no textual changes

Chemical composition of Galactic OB stars II. The fast rotator Z Oph

Z Oph, HD149757, is an O9.5 Vnn star with a very high projected rotational velocity (vsini >= 340 km\s). It is also a classical runaway star due to its high proper motion. We perform a quantitative analysis of its optical spectrum in order to measure important observables of the star such as its mass, effective temperature, luminosity and He, C, N, and O abundances. Comparing these observed values to those predicted by the rotating evolutionary models of the Geneva group we find that none of the two sets of models is capable of reproducing the characteristics of the star. Nevertheless, due to its runaway nature, the reason for this discrepancy may be that the star is not the result of the evolution of a single object, but the product of the evolution of a close binary system.Comment: Accepted for publication in A&