Structural disorder, magnetism, and electrical and thermoelectric properties of pyrochlore Nd2Ru2O7

Polycrystalline Nd2Ru2O7 samples have been prepared and examined using a combination of structural, magnetic, and electrical and thermal transport studies. Analysis of synchrotron X-ray and neutron diffraction patterns suggests some site disorder on the A-site in the pyrochlore sublattice: Ru substitutes on the Nd-site up to 7.0(3)%, regardless of the different preparative conditions explored. Intrinsic magnetic and electrical transport properties have been measured. Ru 4d spins order antiferromagnetically at 143 K as seen both in susceptibility and specific heat, and there is a corresponding change in the electrical resistivity behaviour. A second antiferromagnetic ordering transition seen below 10 K is attributed to ordering of Nd 4f spins. Nd2Ru2O7 is an electrical insulator, and this behaviour is believed to be independent of the Ru-antisite disorder on the Nd site. The electrical properties of Nd2Ru2O7 are presented in the light of data published on all A2Ru2O7 pyrochlores, and we emphasize the special structural role that Bi3+ ions on the A-site play in driving metallic behaviour. High-temperature thermoelectric properties have also been measured. When considered in the context of known thermoelectric materials with useful figures-of-merit, it is clear that Nd2Ru2O7 has excessively high electrical resistivity which prevents it from being an effective thermoelectric. A method for screening candidate thermoelectrics is suggested.Comment: 19 pages, 10 figure

Centennial-scale variability of the Southern Hemisphere westerly wind belt in the eastern Pacific over the past two millennia

We present the first high-resolution (sub-annual) dust particle data set from West Antarctica, developed from the West Antarctic Ice Sheet (WAIS) Divide deep ice core (79.468° S, 112.086° W), and use it to reconstruct changes in atmospheric circulation over the past 2400 years. We find a background dust flux of ~4 mg m−2 year−1 and a mode particle size of 5–8 μm diameter. Through comparing the WAIS Divide record with other Antarctic ice core particle records, we observe that coastal and lower-elevation sites have higher dust fluxes and coarser particle size distributions (PSDs) than sites on the East Antarctic plateau, suggesting input from local dust sources at these lower-elevation sites. In order to explore the use of the WAIS Divide dust PSD as a proxy for past atmospheric circulation, we make quantitative comparisons between both mid-latitude zonal wind speed and West Antarctic meridional wind speed and the dust size record, finding significant positive interannual relationships. We find that the dust PSD is related to mid-latitude zonal wind speed via cyclonic activity in the Amundsen Sea region. Using our PSD record, and through comparison with spatially distributed climate reconstructions from the Southern Hemisphere (SH) middle and high latitudes, we infer that the SH westerlies occupied a more southerly position from circa 1050 to 1400 CE (Common Era), coinciding with the Medieval Climate Anomaly (MCA). Subsequently, at ca. 1430 CE, the wind belt shifted equatorward, where it remained until the mid-to-late twentieth century. We find covariability between reconstructions of El Niño–Southern Oscillation (ENSO) and the mid-latitude westerly winds in the eastern Pacific, suggesting that centennial-scale circulation changes in this region are strongly influenced by the tropical Pacific. Further, we observe increased coarse particle deposition over the past 50 years, consistent with observations that the SH westerlies have been shifting southward and intensifying in recent decades

Rapid Microwave Preparation of Thermoelectric TiNiSn and TiCoSb Half-Heusler Compounds

The 18-electron ternary intermetallic systems TiNiSn and TiCoSb are promising for applications as high-temperature thermoelectrics and comprise earth-abundant, and relatively nontoxic elements. Heusler and half-Heusler compounds are usually prepared by conventional solid state methods involving arc-melting and annealing at high temperatures for an extended period of time. Here, we report an energy-saving preparation route using a domestic microwave oven, reducing the reaction time significantly from more than a week to one minute. A microwave susceptor material rapidly heats the elemental starting materials inside an evacuated quartz tube resulting in near single phase compounds. The initial preparation is followed by a densification step involving hot-pressing, which reduces the amount of secondary phases, as verified by synchrotron X-ray diffraction, leading to the desired half-Heusler compounds, demonstrating that hot-pressing should be treated as part of the preparative process. For TiNiSn, high thermoelectric power factors of 2 mW/mK^2 at temperatures in the 700 to 800 K range, and zT values of around 0.4 are found, with the microwave-prepared sample displaying somewhat superior properties to conventionally prepared half-Heuslers due to lower thermal conductivity. The TiCoSb sample shows a lower thermoelectric figure of merit when prepared using microwave methods because of a metallic second phase

Superheavy dark matter and ultrahigh energy cosmic rays

The phase of inflationary expansion in the early universe produces superheavy relics in a mass window between 10^{12} GeV and 10^{14} GeV. Decay or annihilation of these superheavy relics can explain the observed ultrahigh energy cosmic rays beyond the Greisen-Zatsepin-Kuzmin cutoff. We emphasize that the pattern of cosmic ray arrival directions with energies beyond 20 EeV will decide between the different proposals for the origin of ultrahigh energy cosmic rays.Comment: Based on an invited talk given by RD at Theory Canada 1, Vancouver, June 2-5, 200

Observation of Electron Clouds in the ANKA Undulator by Means of the Microwave Transmission Method

A superconducting undulator is installed in the ANKA electron storage ring. Electron clouds could potentially contribute to the heat load of this device. A microwave transmission type electron cloud diagnostic has been installed for the undulator section of the ANKA machine. We present the system layout with particular emphasis on the electron machine aspects. Hardware transfer function results and e-cloud data for different machine settings are discussed. Special care has been taken for front end filter design both on the microwave injection and pick-up side

Twentieth century dust lows and the weakening of the westerly winds over the Tibetan Plateau

Understanding past atmospheric dust variability is necessary to put modern atmospheric dust into historical context and assess the impacts of dust on the climate. In Asia, meteorological data of atmospheric dust is temporally limited, beginning only in the 1950s. High‐resolution ice cores provide the ideal archive for reconstructing preinstrumental atmospheric dust concentrations. Using a ~500 year (1477–1982 A.D.) annually resolved calcium (Ca) dust proxy from a Tibetan Plateau (TP) ice core, we demonstrate the lowest atmospheric dust concentrations in the past ~500 years during the latter twentieth century. Declines in late nineteenth to twentieth century Ca concentrations significantly correspond with regional zonal wind trends from two reanalysis models, suggesting that the Ca record provides a proxy for the westerlies. Twentieth century warming and attendant atmospheric pressure reductions over northern Asia have potentially reduced temperature/pressure gradients resulting in lower zonal wind velocities and associated dust entrainment/transport in the past ~500 years over the TP

High Energy Neutrinos From Superheavy Dark Matter Annihilation

Superheavy ($M>10^{10}$ GeV) particles produced during inflation may be the dark matter, independent of their interaction strength. Strongly interacting superheavy particles will be captured by the sun, and their annihilation in the center of the sun will produce a flux of energetic neutrinos that should be detectable by neutrino telescopes. Depending on the particle mass, event rates in a cubic-kilometer detector range from several per hour to several per year. The signature of the process is a predominance of tau neutrinos, with a relatively flat energy spectrum of events ranging from 50 GeV to many TeV, and with the mean energy of detected tau neutrinos about 3 TeV.Comment: 24 pages, 7 figure

Massless Metric Preheating

Can super-Hubble metric perturbations be amplified exponentially during preheating ? Yes. An analytical existence proof is provided by exploiting the conformal properties of massless inflationary models. The traditional conserved quantity \zeta is non-conserved in many regions of parameter space. We include backreaction through the homogeneous parts of the inflaton and preheating fields and discuss the role of initial conditions on the post-preheating power-spectrum. Maximum field variances are strongly underestimated if metric perturbations are ignored. We illustrate this in the case of strong self-interaction of the decay products. Without metric perturbations, preheating in this case is very inefficient. However, metric perturbations increase the maximum field variances and give alternative channels for the resonance to proceed. This implies that metric perturbations can have a large impact on calculations of relic abundances of particles produced during preheating.Comment: 8 pages, 4 colour figures. Version to appear in Phys. Rev. D. Contains substantial new analysis of the ranges of parameter space for which large changes to the inflation-produced power spectrum are expecte

Neutrino cross sections at high energies and the future observations of ultrahigh-energy cosmic rays

We show that future detectors of ultrahigh-energy cosmic-ray neutrinos will be able to measure neutrino-nucleon cross section at energies as high as 10^{11}GeV or higher. We find that the flux of up-going charged leptons per unit surface area produced by neutrino interactions below the surface is inversely proportional to the cross section. This contrasts with the rate of horizontal air showers (HAS) due to neutrino interactions in the atmosphere, which is proportional to the cross section. Thus, by comparing the HAS and up-going air shower (UAS) rates, the neutrino-nucleon cross section can be inferred. Taken together, up-going and horizontal rates ensure a healthy total event rate, regardless of the value of the cross section.Comment: 4 pages, 2 figures, revtex; final draf

Long-Lived Superheavy Particles in Dynamical Supersymmetry-Breaking Models in Supergravity

Superheavy particles of masses $\simeq 10^{13}-10^{14} GeV$ with lifetimes $\simeq 10^{10}-10^{22} years$ are very interesting, since their decays may account for the ultra-high energy (UHE) cosmic rays discovered beyond the Greisen-Zatsepin-Kuzmin cut-off energy $E \sim 5 \times 10^{10} GeV$. We show that the presence of such long-lived superheavy particles is a generic prediction of QCD-like SU(N_c) gauge theories with N_f flavors of quarks and antiquarks and the large number of colors N_c. We construct explicit models based on supersymmetric SU(N_c) gauge theories and show that if the dynamical scale $\Lambda \simeq 10^{13}-10^{14} GeV$ and N_c = 6-10 the lightest composite baryons have the desired masses and lifetimes to explain the UHE cosmic rays. Interesting is that in these models the gaugino condensation necessarily occurs and hence these models may play a role of so-called hidden sector for supersymmetry breaking in supergravity.Comment: 13 pages, Late