Finite size effects on the phase diagram of a binary mixture confined between competing walls

A symmetrical binary mixture AB that exhibits a critical temperature T_{cb} of phase separation into an A-rich and a B-rich phase in the bulk is considered in a geometry confined between two parallel plates a distance D apart. It is assumed that one wall preferentially attracts A while the other wall preferentially attracts B with the same strength (''competing walls''). In the limit $D\to \infty$, one then may have a wetting transition of first order at a temperature T_{w}, from which prewetting lines extend into the one phase region both of the A-rich and the B-rich phase. It is discussed how this phase diagram gets distorted due to the finiteness of D% : the phase transition at T_{cb} immediately disappears for D<\infty due to finite size rounding, and the phase diagram instead exhibit two two-phase coexistence regions in a temperature range T_{trip}<T<T_{c1}=T_{c2}. In the limit D\to \infty T_{c1},T_{c2} become the prewetting critical points and T_{trip}\to T_{w}. For small enough D it may occur that at a tricritical value D_{t} the temperatures T_{c1}=T_{c2} and T_{trip} merge, and then for D<D_{t} there is a single unmixing critical point as in the bulk but with T_{c}(D) near T_{w}. As an example, for the experimentally relevant case of a polymer mixture a phase diagram with two unmixing critical points is calculated explicitly from self-consistent field methods

Wetting and Capillary Condensation in Symmetric Polymer Blends: A comparison between Monte Carlo Simulations and Self-Consistent Field Calculations

We present a quantitative comparison between extensive Monte Carlo simulations and self-consistent field calculations on the phase diagram and wetting behavior of a symmetric, binary (AB) polymer blend confined into a film. The flat walls attract one component via a short range interaction. The critical point of the confined blend is shifted to lower temperatures and higher concentrations of the component with the lower surface free energy. The binodals close the the critical point are flattened compared to the bulk and exhibit a convex curvature at intermediate temperatures -- a signature of the wetting transition in the semi-infinite system. Investigating the spectrum of capillary fluctuation of the interface bound to the wall, we find evidence for a position dependence of the interfacial tension. This goes along with a distortion of the interfacial profile from its bulk shape. Using an extended ensemble in which the monomer-wall interaction is a stochastic variable, we accurately measure the difference between the surface energies of the components, and determine the location of the wetting transition via the Young equation. The Flory-Huggins parameter at which the strong first order wetting transition occurs is independent of chain length and grows quadratically with the integrated wall-monomer interaction strength. We estimate the location of the prewetting line. The prewetting manifests itself in a triple point in the phase diagram of very thick films and causes spinodal dewetting of ultrathin layers slightly above the wetting transition. We investigate the early stage of dewetting via dynamic Monte Carlo simulations.Comment: to appear in Macromolecule

Second-Order Dynamics in the Collective Evolution of Coupled Maps and Automata

We review recent numerical studies and the phenomenology of spatially synchronized collective states in many-body dynamical systems. These states exhibit thermodynamic noise superimposed on the collective, quasiperiodic order parameter evolution with typically one basic irrational frequency. We concentrate on the description of the global temporal properties in terms of second-order difference equations.Comment: 11 pages (plain TeX), 4 figures (PostScript), preprint OUTP-92-51

On computational complexity of Siegel Julia sets

It has been previously shown by two of the authors that some polynomial Julia sets are algorithmically impossible to draw with arbitrary magnification. On the other hand, for a large class of examples the problem of drawing a picture has polynomial complexity. In this paper we demonstrate the existence of computable quadratic Julia sets whose computational complexity is arbitrarily high.Comment: Updated version, to appear in Commun. Math. Phy

A model for a non-minimally coupled scalar field interacting with dark matter

In this work we investigate the evolution of a Universe consisted of a scalar field, a dark matter field and non-interacting baryonic matter and radiation. The scalar field, which plays the role of dark energy, is non-minimally coupled to space-time curvature, and drives the Universe to a present accelerated expansion. The non-relativistic dark matter field interacts directly with the dark energy and has a pressure which follows from a thermodynamic theory. We show that this model can reproduce the expected behavior of the density parameters, deceleration parameter and luminosity distance.Comment: 3 pages, 4 figures. To appear in Brazilian Journal of Physic

Gravitational Clustering: A Simple, Robust and Adaptive Approach for Distributed Networks

Distributed signal processing for wireless sensor networks enables that different devices cooperate to solve different signal processing tasks. A crucial first step is to answer the question: who observes what? Recently, several distributed algorithms have been proposed, which frame the signal/object labelling problem in terms of cluster analysis after extracting source-specific features, however, the number of clusters is assumed to be known. We propose a new method called Gravitational Clustering (GC) to adaptively estimate the time-varying number of clusters based on a set of feature vectors. The key idea is to exploit the physical principle of gravitational force between mass units: streaming-in feature vectors are considered as mass units of fixed position in the feature space, around which mobile mass units are injected at each time instant. The cluster enumeration exploits the fact that the highest attraction on the mobile mass units is exerted by regions with a high density of feature vectors, i.e., gravitational clusters. By sharing estimates among neighboring nodes via a diffusion-adaptation scheme, cooperative and distributed cluster enumeration is achieved. Numerical experiments concerning robustness against outliers, convergence and computational complexity are conducted. The application in a distributed cooperative multi-view camera network illustrates the applicability to real-world problems.Comment: 12 pages, 9 figure

Life-Cycle Models and Cross-Country Analysis of Saving

This paper develops a rational expectations life-cycle model designed as a framework for the cross-country analysis of (private) saving decisions. It is shown that a broad range of life-cycle models that have been used in the literature to study aggregate time series on consumption and saving fail to deliver plausible predictions for the purpose of analyzing saving decisions across countries as they imply that the level of saving has a constant mean and that the long-run saving rate may tend to zero. Introducing a utility specification that ties the long-run evolution of consumers' aspired consumption paths to that of aggregate labor income, an analytically tractable life-cycle model is proposed that has plausible long-run properties, including the implication that the net asset-labor income ratio, the saving rate, and the consumption-labor income ratio have meaningful long-run distributions. The moments of the long-run saving rate are shown to depend in a precise way on various characteristics of consumers' preferences, the real rate of interest, the growth rate and volatility of labor income, the government consumption-labor income ratio, and the government debt-labor income ratio. Employing a data set on saving rates and asset holdings across OECD economies and using techniques for the estimation of dynamic heterogeneous panels, the paper will also adduce empirical evidence assessing the model's ability to explain differences in the saving patterns across these economies.

Phase diagram of polymer blends in confined geometry

Within self-consistent field theory we study the phase behavior of a symmetrical binary AB polymer blend confined into a thin film. The film surfaces interact with the monomers via short range potentials. One surface attracts the A component and the corresponding semi-infinite system exhibits a first order wetting transition. The surface interaction of the opposite surface is varied as to study the crossover from capillary condensation for symmetric surface fields to the interface localization/delocalization transition for antisymmetric surface fields. In the former case the phase diagram has a single critical point close to the bulk critical point. In the latter case the phase diagram exhibits two critical points which correspond to the prewetting critical points of the semi-infinite system. Only below a triple point there is a single two phase coexistence region. The crossover between these qualitatively different limiting behaviors occurs gradually, however, the critical temperature and the critical composition exhibit a non-monotonic dependence on the surface field. The dependence of the phase behavior for antisymmetric boundaries is studied as a function of the film thickness and the strength of the surface interactions. Upon reducing the film thickness or decreasing the strength of the surface interactions we can change the order of the interface localization/delocalization transition from first to second. The role of fluctuations is explored via Monte Carlo simulations of a coarse grained lattice model. Close to the (prewetting) critical points we observe 2D Ising critical behavior. At lower temperatures capillary waves of the AB interface lead to a pronounced dependence of the effective interface potential on the lateral system size.Comment: submitted to the Journal of Molecular Liquids and Condensed Matter Physic

Estimation and Inference in Short Panel Vector Autoregressions with Unit Roots and Cointegration

This paper considers estimation and inference in panel vector autoregressions (PVARs) with fixed effects when the time dimension of the panel is finite, and the cross-sectional dimension is large. A Maximum Likelihood (ML) estimator based on a transformed likelihood function is proposed and shown to be consistent and asymptotically normally distributed irrespective of the unit root and cointegrating properties of the underlying PVAR model. The transformed likelihood framework is also used to derive unit root and cointegration tests in panels with short time dimension; these tests have the attractive feature that they are based on standard chi-squared and normal distributed statistics. Examining Generalised Method of Moments (GMM) estimation as an alternative to our proposed ML estimator, it is shown that conventional GMM estimators based on standard orthogonality conditions break down if the underlying time series contain unit roots.Panel vector autoregressions, Fixed effects, Unit roots, Cointegration