Luminescent ionic liquid crystals based on stilbazolium moieties

Liquid crystals have become pivotally important to a variety of image displaying technologies. They have drawn much attention due to their ability to confer luminescent properties to a wide spectrum of image based devices. The purpose of this research is to describe a new methodology for an efficient synthesis of luminescent ionic liquid crystals including a discussion of their applications in the biological/medicinal sciences

Synthesis and Characterization of PT(II) Complexes for Anticancer Therapy

The first platinum-based drug was discovered and approved by Food and Drug Administration (FDA) in 1978 is cis-diamminedichloroplatinum (II) (cisplatin or CDDP). Cisplatin is used for about 50% of the chemotherapeutic cancer treatments along with its two analogues carboplatin and oxaliplatin. So far these drugs have been used extensively as treatment for ovarian, bladder, head and neck, and lung cancers. Although cisplatin has been used so often, it has toxic side effects and drug resistance.1-4 Due to these limitations other compounds have been synthesized. Specifically, our lab in conjunction with a biochemistry lab has recently published one article in this area. This project is a continuation to the development of anticancer drugs

Synthesis of novel aromatic quinols for colon and renal cancers

Colon Cancer: The third most common cancer in USA. More than 1 million Americans currently living with colon cancer. 148,810 new cases expected in 2010. 50,000 deaths annually. Renal Cancer: Approximately 58,000 people diagnosed in USA annually. Seventh most common cancer and tenth most common cause of cancer related death in men. Aromatic quinols have demonstrated in vitro antitumor activity. Three heteroaromatic quinols show antitumor activity

Isothermal Titration Calorimetry and Transmission Electron Microscopy of Main-Chain Viologen Polymer Containing Bromide as Counerions

Polyelectrolytes are an important class of macromolecules that contain dissociable ionic groups. When introduced into polar solvent, usually the universal solvent water, dissociation takes place so that electrically charged macromolecule is suspended in solution. The electrostatic interaction is operative between ionized groups inside the macromolecule, between the macromolecules, between the counterions, and between the macromolecule and counterion. Since this interaction is characterized by its long-range nature, the solution exhibits various interesting properties including the polyelectrolyte behavior very different from solutions of neutral polymers

A New Method of Synthesizing Black Birnessite Nanoparticles: From Brown to Black Birnessite with Nanostructures

A new method for preparing black birnessite nanoparticles is introduced. The initial synthesis process resembles the classical McKenzie method of preparing brown birnessite except for slower cooling and closing the system from the ambient air. Subsequent process, including wet-aging at 7◦C for 48 hours, overnight freezing, and lyophilization, is shown to convert the brown birnessite into black birnessite with complex nanomorphology with folded sheets and spirals. Characterization of the product is performed by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), thermogravimetric analysis (TGA), and N2 adsorption (BET) techniques. Wet-aging and lyophilization times are shown to affect the architecture of the product. XRD patterns show a single phase corresponding to a semicrystalline birnessite-based manganese oxide. TEM studies suggest its fibrous and petal-like structures. The HRTEM images at 5 and 10 nm length scales reveal the fibrils in folding sheets and also show filamentary breaks. The BET surface area of this nanomaterial was found to be 10.6m2/g. The TGA measurement demonstrated that it possessed an excellent thermal stability up to 400◦C. Layerstructured black birnessite nanomaterial containing sheets, spirals, and filamentary breaks can be produced at low temperature (−49◦C) from brown birnessite without the use of cross-linking reagents

Ionic liquid crystals : synthesis and characterization via NMR, DSC, POM, X-ray diffraction and ionic conductivity of asymmetric viologen bistriflimide salts

Acknowledgments This research is in part supported by the NSF EPSCoR RING-TRUE III grant no. 0447416, NSF-SBIR grant no. OII-0610753, NSF-STTR grant no. IIP-0740289 and NASA GRC contract no. NNX10CD25P (PKB). We thank Ronald C. G. Principe for making the Figures and Tables for this article. Acknowledgment is made to the donors of the American Chemical Society Petroleum Research Fund grant no. 59345-ND7 for partial support of this research by CMR and MRF. AMF would like to thank the Carnegie Trust for the Universities of Scotland, for the Research Incentive Grant RIG008586, the Royal Society and Specac Ltd., for the Research Grant RGS\R1\201397, and the Royal Society of Chemistry for the award of a mobility grant (M19-0000).Peer reviewedPostprin

Thermotropic Liquid-Crystalline and Light-Emitting Properties of Poly(pyridinium) Salts Containing Various Diamine Connectors and Hydrophilic Macrocounterions

A set of poly(pyridinium) salts containing various diamine moieties, as molecular connectors, and poly(ethyleneglycol)-4-nonylphenyl-3-sulfopropyl ether, thereafter referred to as “Macroion”, as the hydrophilic counterion, were prepared by metathesis reaction from the respective precursory tosylated poly(pyridinium)s in methanol. The structure of these ionic polymers was established by spectroscopy and chromatography techniques. The shape-persistent ionic poly(pyridinium) materials, inserting rigid or semi-rigid diamine spacers, display thermotropic liquid-crystalline properties from room-temperature up to their isotropization (in the temperature range around 160–200 °C). The nature of the LC phases is lamellar in both cases as identified by the combination of various complementary experimental techniques including DSC, POM and variable-temperature SAXS. The other polymers, inserting bulky or flexible spacers, only form room temperature viscous liquids. These new macromolecular systems can then be referred to as polymeric ionic liquid crystals (PILCs) and or polymeric ionic liquids (PILs). All the ionic polymers show excellent thermal stability, in the 260–330 °C temperature range as determined by TGA measurements, and a good solubility in common organic solvents as well as in water. Their optical properties were characterized in both solution and solid states by UV−Vis and photoluminescent spectroscopies. They emit blue or green light in both the states and exhibit a positive solvatochromic effect

Dicationic stilbazolium salts : structural, thermal, optical, and ionic conduction properties

Acknowledgments This research is in part supported by the NSF EPSCoR RING-TRUE III grant no. 0447416, NSF-SBIR grant no. OII-0610753, NSF-STTR grant no. IIP-0740289 and NASA GRC contract no. NNX10CD25P (PKB). BD and BH thank the CNRS and University of Strasbourg. AMF would like to acknowledge the Carnegie Trust for the Universities of Scotland, for the Research Incentive Grant RIG008586, the Royal Society and Specac Ltd., for the Research Grant RGS\R1\201397, the Royal Society of Chemistry for the award of a mobility grant (M19-0000), and the Royal Society of Edinburgh and the Scottish Government, for the award of a SAPHIRE project.Peer reviewedPostprin

High Ionic Conductivities of Ionic Materials as Potential Electrolytes

Acknowledgments We sincerely acknowledge Dr. Kousaalya Bakthavatchalam for critically reading and making insightful suggestions for the improvement of the article. TSV acknowledges the Ministry of Higher Education under the Fundamental Research Grant Scheme [FRGS/1/2018/STG07/UM/02/6] for the financial support. AMF would like to thank the Carnegie Trust for the Universities of Scotland, for the Research Incentive Grant RIG008586, the Royal Society and Specac Ltd. for the Research Grant RGS\R1\201397, the Royal Society of Edinburgh and the Scottish Government for one Sapphire project, and the Royal Society of Chemistry for the award of a mobility grant (M19-0000). UB thanks the School of Engineering (University of Aberdeen) for the award of one Summer Scholarship.Publisher PD

Thermotropic Liquid-Crystalline Properties of Viologens Containing 4-n-alkylbenzenesulfonates†

A series of viologens containing 4-n-alkylbenzenesulfonates were synthesized by the metathesis reaction of 4-n-alkylbenzenesulfonic acids or sodium 4-n-alkylbezenesulfonates with the respective viologen dibromide in alcohols. Their chemical structures were characterized by Fourier Transform Infrared, 1H and 13C Nuclear Magnetic Resonance spectra and elemental analysis. Their thermotropic liquid-crystalline (LC) properties were examined by differential scanning calorimetry and polarizing optical microscopy. They formed LC phases above their melting transitions and showed isotropic transitions. As expected, all the viologen salts had excellent stabilities in the temperature range of 278–295 °C as determined by thermogravimetric analysis