A porphyrin-based microporous network polymer that acts as an efficient catalyst for cyclooctene and cyclohexane oxidation under mild conditions

The highly efficient dibenzodioxin-forming reaction between the (pentafluorophenyl)porphyrin manganese(III) (MnP) and hexahydroxytriptycene (HHT) provide a new microporous network polymer (P1), which demonstrated a large surface area (1080 m2 g− 1) and proved to be an efficient solid for heterogeneous catalysis for cyclooctene and cyclohexane oxidation under mild conditions and with high capacity of recovery and reuse in many catalytic cycles

Polymer Ultrapermeability from the Inefficient Packing of 2D Chains.

McKeown, Neil; Bezzu, C. Grazia; Comesaña-Gándara, Bibiana; Carta, Mariolino; Lasseuguette, Elsa; Ferrari, M. Chiara; Bernardo, Paola; Clarizia, Gabriela; Fuoco, Johannes; Rose, Ian. (2017). Polymer Ultrapermeability from the Inefficient Packing of 2D Chains, [dataset]. University of Edinburgh. School of Chemistry. http://dx.doi.org/10.7488/ds/2054