25 research outputs found
Increase of the mean inner Coulomb potential in Au clusters induced by surface tension and its implication for electron scattering
Electron holography in a transmission electron microscope was applied to
measure the phase shift induced by Au clusters as a function of the cluster
size. Large phase shifts Df observed for small Au clusters cannot be described
by the well-known equation Df=C_E V_0 t (C_E: interaction constant, V_0: mean
inner Coulomb potential (MIP) of bulk gold, t: cluster thickness). The rapid
increase of the Au MIP with decreasing cluster size derived from Df, can be
explained by the compressive strain of surface atoms in the cluster