In Situ Measurement of Orthotropic Thermal Conductivity on Commercial Pouch Lithium-Ion Batteries with Thermoelectric Device

In this paper, the direct measurement of the orthotropic thermal conductivity on a commercial Li-ion pouch battery is presented. The samples under analysis are state-of-the art batteries obtained from a fully electric vehicle commercialized in 2016. The proposed methodology does not require a laboratory equipped to manage hazardous chemical substances as the battery does not need to be disassembled. The principle of the measurement methodology consists of forcing a thermal gradient on the battery along the desired direction and measuring the heat flux and temperature after the steady state condition has been reached. A thermoelectric device has been built in order to force the thermal gradient and keep it stable over a long period of time in order to be able to observe the temperatures in steady state condition. Aligned with other measurement methodologies, the results revealed that the thermal conductivity in the thickness direction (0.77 Wm−1K−1) is lower with respect to the other two directions (25.55 Wm−1K−1 and 25.74 Wm−1K−1) to about a factor ×35