Controlled Contact to a C60 Molecule

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to 0.25 conductance quanta G0. An abrupt conductance jump to G0 is observed upon further decreasing the distance between the instrument's tip and the surface. Ab-initio calculations within density functional theory and non-equilibrium Green's function techniques explain the experimental data in terms of the conductance of an essentially undeformed C60. From a detailed analysis of the crossover from tunneling to contact we conclude that the conductance in this region is strongly affected by structural fluctuations which modulate the tip-molecule distance.Comment: 4 pages, 3 figure

D'atri spaces of type k and related classes of geometries concerning jacobi operators

In this article we continue the study of the geometry of $k$-D'Atri spaces, $$ $\leq n-1$ ($n$ denotes the dimension of the manifold)$,$ began by the second author. It is known that $k$-D'Atri spaces, $k\geq 1,$ are related to properties of Jacobi operators $R_{v}$ along geodesics, since she has shown that ${\operatorname{tr}}R_{v}$, ${\operatorname{tr}}R_{v}^{2}$ are invariant under the geodesic flow for any unit tangent vector $v$. Here, assuming that the Riemannian manifold is a D'Atri space, we prove in our main result that ${\operatorname{tr}}R_{v}^{3}$ is also invariant under the geodesic flow if $k\geq 3$. In addition, other properties of Jacobi operators related to the Ledger conditions are obtained and they are used to give applications to Iwasawa type spaces. In the class of D'Atri spaces of Iwasawa type, we show two different characterizations of the symmetric spaces of noncompact type: they are exactly the $\frak{C}$-spaces and on the other hand they are $k$ -D'Atri spaces for some $k\geq 3.$ In the last case, they are $k$-D'Atri for all $k=1,...,n-1$ as well. In particular, Damek-Ricci spaces that are $k$-D'Atri for some $k\geq 3$ are symmetric. Finally, we characterize $k$-D'Atri spaces for all $k=1,...,n-1$ as the $\frak{SC}$-spaces (geodesic symmetries preserve the principal curvatures of small geodesic spheres). Moreover, applying this result in the case of 4% -dimensional homogeneous spaces we prove that the properties of being a D'Atri (1-D'Atri) space, or a 3-D'Atri space, are equivalent to the property of being a $k$-D'Atri space for all $k=1,2,3$.Comment: 19 pages. This paper substitute the previous one where one Theorem has been deleted and one section has been adde

Controlling the Kondo Effect in CoCu_n Clusters Atom by Atom

Clusters containing a single magnetic impurity were investigated by scanning tunneling microscopy, spectroscopy, and ab initio electronic structure calculations. The Kondo temperature of a Co atom embedded in Cu clusters on Cu(111) exhibits a non-monotonic variation with the cluster size. Calculations model the experimental observations and demonstrate the importance of the local and anisotropic electronic structure for correlation effects in small clusters.Comment: 4 pages, 4 figure

Palaeotethys-related sediments of the Karaburun Peninsula, western Turkey: constraints on provenance and stratigraphy from detrital zircon geochronology

Detrital zircon U–Pb geochronology of 15 Late Palaeozoic to Early Mesozoic siliciclastic sandstones from the Karaburun Peninsula in western Turkey determines maximum sedimentation ages, identifies possible source areas, and anchors the study area within the Palaeotethyan realm. Siliciclastic sandstones yielded ages from Triassic to Archean with major input from Palaeozoic to Neoproterozoic sources and very few Mesoproterozoic zircons. The youngest age groups set the new limit of the maximum depositional ages to Late Carboniferous–Early Permian for the Küçükbahçe and Dikendağı formations. Detrital zircons from Triassic sandstones are mainly Neoproterozoic and Palaeozoic in age. Zircons from the Scythian–Anisian Gerence Formation are predominantly Devonian and Carboniferous in age, while also Permian and Triassic zircon grains occur in the Carnian–Rhaetian Güvercinlik Formation. According to the zircon age populations and the data available from possible source regions, the Karaburun siliciclastic sediments, with the exception of two samples from the Dikendağı Formation, record sediment supply from units located at the southern margin of Eurasia during Late Palaeozoic and Early Mesozoic times. This interpretation is in agreement with palaeotectonic reconstructions for the closely related Greek islands of Chios and Inousses. The presence of Devonian accompanied by Carboniferous zircons in some of the Karaburun samples reveals similarities with Karakaya Complex sandstones of the Sakarya Zone in NW Turkey

Light emission from a scanning tunneling microscope: Fully retarded calculation

The light emission rate from a scanning tunneling microscope (STM) scanning a noble metal surface is calculated taking retardation effects into account. As in our previous, non-retarded theory [Johansson, Monreal, and Apell, Phys. Rev. B 42, 9210 (1990)], the STM tip is modeled by a sphere, and the dielectric properties of tip and sample are described by experimentally measured dielectric functions. The calculations are based on exact diffraction theory through the vector equivalent of the Kirchoff integral. The present results are qualitatively similar to those of the non-retarded calculations. The light emission spectra have pronounced resonance peaks due to the formation of a tip-induced plasmon mode localized to the cavity between the tip and the sample. At a quantitative level, the effects of retardation are rather small as long as the sample material is Au or Cu, and the tip consists of W or Ir. However, for Ag samples, in which the resistive losses are smaller, the inclusion of retardation effects in the calculation leads to larger changes: the resonance energy decreases by 0.2-0.3 eV, and the resonance broadens. These changes improve the agreement with experiment. For a Ag sample and an Ir tip, the quantum efficiency is $\approx$ 10$^{-4}$ emitted photons in the visible frequency range per tunneling electron. A study of the energy dissipation into the tip and sample shows that in total about 1 % of the electrons undergo inelastic processes while tunneling.Comment: 16 pages, 10 figures (1 ps, 9 tex, automatically included); To appear in Phys. Rev. B (15 October 1998

Evolution of the Palaeotethys in the Eastern Mediterranean: A multi-method approach to unravel the age, provenance and tectonic setting of the Upper Palaeozoic Konya Complex and its Mesozoic cover sequence (south-central Turkey)

Thirteen siliciclastic sediments from the Upper Palaeozoic Konya Complex and its Mesozoic cover were studied by a multi-method approach combining thin-section petrography, bulk-rock geochemistry, mineral chemistry of rutile, and U–Pb geochronology of detrital zircons. Provenance sensitive data of samples from the Upper Palaeozoic Halıcı Formation indicate sediment supply from mainly low- to medium-grade metamorphosed sedimentary rocks of felsic character, while contribution from volcanic rocks was rare. The detrital zircon record of sediments from the Halıcı Formation documents sediment supply from different sources and excludes a similar provenance. Some samples show great similarities with Palaeozoic sandstones from the cover sequence of the Saharan Metacraton and the Arabian–Nubian Shield, while the other samples indicate a provenance that must be sought in units with a southern Eurasian affinity. The upper limit for sediment deposition in the Halıcı Formation is mostly constrained by Early Palaeozoic zircon populations, however, sediment accumulation in Pennsylvanian–Cisuralian time is more likely, contemporaneously with the Upper Palaeozoic succession on the Karaburun Peninsula (western Turkey). The provenance of sediments from the Upper Triassic Ardıçlı Formation remains enigmatic, but the source should be sought nonetheless in units close to the depositional site. In any case, detrital zircon age spectra and compositional data exclude recycling of underlying rock units (i.e. Halıcı Formation). Overall, our new provenance data reveal great similarities between the Konya Complex and comparable units (Chios, Karaburun) but also highlight distinct differences in terms of sediment composition and provenance

Factors associated with the success of rabies vaccination of dogs in Sweden

<p>Abstract</p> <p>Background</p> <p>United Kingdom, Ireland, Malta and Sweden maintain their national provisions for a transitional period regarding rules concerning rabies vaccination and individual serological test for rabies neutralizing antibodies. The purpose of vaccinating dogs against rabies is to establish pre-exposure immunity and protect individual animals from contracting rabies.</p> <p>The aim of the study was to investigate factors associated with reaching the internationally accepted threshold antibody titre of 0.5 IU/mL after rabies vaccination of dogs.</p> <p>Methods</p> <p>The study was a prospective single cohort study including 6,789 samples from Swedish dogs vaccinated with commercially available vaccines in Sweden, and the dog's antibody responses were determined by the OIE approved FAVN test. Information on potential risk factors; breed, age, gender, date of vaccination, vaccine label and the number of vaccinations, was collected for each dog. Associations between the dependent variable, serological response ≥ 0.5 IU/mL or < 0.5 IU/mL and each of the potential risk factors were investigated using logistic regression analysis.</p> <p>Results</p> <p>Of 6,789 vaccinated dogs, 6,241 (91.9%) had an approved test result of ≥ 0.5 IU/mL. The results of the multivariable logistic regression analysis showed that vaccinating with vaccine B reduced the risk of having antibody titres of < 0.5 IU/mL by 0.2 times compared with vaccination using vaccine A. Breed size was found significant as an interaction with number of vaccinations and age at vaccination as an interaction with day of antibody testing after last vaccination. In summary, larger breeds were at higher risk of having antibody titres of < 0.5 IU/mL but if vaccinated twice this risk was reduced. Moreover, there were a increased risk for dogs < 6 months of age and > 5 years of age to have antibody titres of < 0.5 IU/mL, but this was affected by number of days from vaccination till testing.</p> <p>Conclusions</p> <p>The probability of success of rabies vaccinations of dogs depends on type of vaccine used, number of rabies vaccinations, the breed size of the dog, age at vaccination, and number of days after vaccination when the antibody titres are tested. The need for a booster vaccination regimen is recommended for larger breeds of dog.</p