16 research outputs found
Static Electric Dipole Polarizabilities of Na Clusters
The static electric dipole polarizability of clusters with
even N has been calculated in a collective, axially averaged and a
three-dimensional, finite-field approach for , including the
ionic structure of the clusters. The validity of a collective model for the
static response of small systems is demonstrated. Our density functional
calculations verify the trends and fine structure seen in a recent experiment.
A pseudopotential that reproduces the experimental bulk bond length and atomic
energy levels leads to a substantial increase in the calculated
polarizabilities, in better agreement with experiment. We relate remaining
differences in the magnitude of the theoretical and experimental
polarizabilities to the finite temperature present in the experiments.Comment: 7 pages, 3 figures, accepted for publication in the European Physical
Journal
Dynamical Effects in the Optical Response of Carbon Chains
We discuss the optical response of small carbon chains from the linear to the non linear domain in the framework of Time Dependent Local Density Approximation. We show that even for moderate ionizations, corresponding to a moderately intense excitation, the optical response exhibits significant alteration with respect to the truly linear domain response. This reflects non trivial dynamical effects at the level of electrons
www.mdpi.org/ijms/ Dynamical Effects in the Optical Response of Carbon Chains
Abstract: We discuss the optical response of small carbon chains from the linear to the non linear domain in the framework of Time Dependent Local Density Approximation. We show that even for moderate ionizations, corresponding to a moderately intense excitation, the optical response exhibits significant alteration with respect to the truly linear domain response. This reflects non trivial dynamical effects at the level of electrons