Non-Markovian Persistence and Nonequilibrium Critical Dynamics

The persistence exponent \theta for the global order parameter, M(t), of a system quenched from the disordered phase to its critical point describes the probability, p(t) \sim t^{-\theta}, that M(t) does not change sign in the time interval t following the quench. We calculate \theta to O(\epsilon^2) for model A of critical dynamics (and to order \epsilon for model C) and show that at this order M(t) is a non-Markov process. Consequently, \theta is a new exponent. The calculation is performed by expanding around a Markov process, using a simplified version of the perturbation theory recently introduced by Majumdar and Sire [Phys. Rev. Lett. _77_, 1420 (1996); cond-mat/9604151].Comment: 4 pages, Revtex, no figures, requires multicol.st

First order phase transition with a logarithmic singularity in a model with absorbing states

Recently, Lipowski [cond-mat/0002378] investigated a stochastic lattice model which exhibits a discontinuous transition from an active phase into infinitely many absorbing states. Since the transition is accompanied by an apparent power-law singularity, it was conjectured that the model may combine features of first- and second-order phase transitions. In the present work it is shown that this singularity emerges as an artifact of the definition of the model in terms of products. Instead of a power law, we find a logarithmic singularity at the transition. Moreover, we generalize the model in such a way that the second-order phase transition becomes accessible. As expected, this transition belongs to the universality class of directed percolation.Comment: revtex, 4 pages, 5 eps figure

Precision timing of PSR J1012+5307 and strong-field GR tests

We report on the high precision timing analysis of the pulsar-white dwarf binary PSR J1012+5307. Using 15 years of multi-telescope data from the European Pulsar Timing Array (EPTA) network, a significant measurement of the variation of the orbital period is obtained. Using this ideal strong-field gravity laboratory we derive theory independent limits for both the dipole radiation and the variation of the gravitational constant.Comment: 3 pages, Proceedings of the 12th Marcel Grossmann Meeting on General Relativity (MG 12

Improving membrane based multiplex immunoassays for semi-quantitative detection of multiple cytokines in a single sample

BACKGROUND: Inflammatory mediators can serve as biomarkers for the monitoring of the disease progression or prognosis in many conditions. In the present study we introduce an adaptation of a membrane-based technique in which the level of up to 40 cytokines and chemokines can be determined in both human and rodent blood in a semi-quantitative way. The planar assay was modified using the LI-COR (R) detection system (fluorescence based) rather than chemiluminescence and semi-quantitative outcomes were achieved by normalizing the outcomes using the automated exposure settings of the Odyssey readout device. The results were compared to the gold standard assay, namely ELISA. RESULTS: The improved planar assay allowed the detection of a considerably higher number of analytes (n = 30 and n = 5 for fluorescent and chemiluminescent detection, respectively). The improved planar method showed high sensitivity up to 17 pg/ml and a linear correlation of the normalized fluorescence intensity with the results from the ELISA (r = 0.91). CONCLUSIONS: The results show that the membrane-based technique is a semi-quantitative assay that correlates satisfactorily to the gold standard when enhanced by the use of fluorescence and subsequent semi-quantitative analysis. This promising technique can be used to investigate inflammatory profiles in multiple conditions, particularly in studies with constraints in sample sizes and/or budget

Towards Classification of Phase Transitions in Reaction--Diffusion Models

Equilibrium phase transitions are associated with rearrangements of minima of a (Lagrangian) potential. Treatment of non-equilibrium systems requires doubling of degrees of freedom, which may be often interpreted as a transition from the ``coordinate'' to the ``phase'' space representation. As a result, one has to deal with the Hamiltonian formulation of the field theory instead of the Lagrangian one. We suggest a classification scheme of phase transitions in reaction-diffusion models based on the topology of the phase portraits of corresponding Hamiltonians. In models with an absorbing state such a topology is fully determined by intersecting curves of zero ``energy''. We identify four families of topologically distinct classes of phase portraits stable upon RG transformations.Comment: 14 pages, 9 figure

Reentrant phase diagram of branching annihilating random walks with one and two offsprings

We investigate the phase diagram of branching annihilating random walks with one and two offsprings in one dimension. A walker can hop to a nearest neighbor site or branch with one or two offsprings with relative ratio. Two walkers annihilate immediately when they meet. In general, this model exhibits a continuous phase transition from an active state into the absorbing state (vacuum) at a finite hopping probability. We map out the phase diagram by Monte Carlo simulations which shows a reentrant phase transition from vacuum to an active state and finally into vacuum again as the relative rate of the two-offspring branching process increases. This reentrant property apparently contradicts the conventional wisdom that increasing the number of offsprings will tend to make the system more active. We show that the reentrant property is due to the static reflection symmetry of two-offspring branching processes and the conventional wisdom is recovered when the dynamic reflection symmetry is introduced instead of the static one.Comment: 14 pages, Revtex, 4 figures (one PS figure file upon request) (submitted to Phy. Rev. E

Applications of Field-Theoretic Renormalization Group Methods to Reaction-Diffusion Problems

We review the application of field-theoretic renormalization group (RG) methods to the study of fluctuations in reaction-diffusion problems. We first investigate the physical origin of universality in these systems, before comparing RG methods to other available analytic techniques, including exact solutions and Smoluchowski-type approximations. Starting from the microscopic reaction-diffusion master equation, we then pedagogically detail the mapping to a field theory for the single-species reaction k A -> l A (l < k). We employ this particularly simple but non-trivial system to introduce the field-theoretic RG tools, including the diagrammatic perturbation expansion, renormalization, and Callan-Symanzik RG flow equation. We demonstrate how these techniques permit the calculation of universal quantities such as density decay exponents and amplitudes via perturbative eps = d_c - d expansions with respect to the upper critical dimension d_c. With these basics established, we then provide an overview of more sophisticated applications to multiple species reactions, disorder effects, L'evy flights, persistence problems, and the influence of spatial boundaries. We also analyze field-theoretic approaches to nonequilibrium phase transitions separating active from absorbing states. We focus particularly on the generic directed percolation universality class, as well as on the most prominent exception to this class: even-offspring branching and annihilating random walks. Finally, we summarize the state of the field and present our perspective on outstanding problems for the future.Comment: 10 figures include

The non-equilibrium phase transition of the pair-contact process with diffusion

The pair-contact process 2A->3A, 2A->0 with diffusion of individual particles is a simple branching-annihilation processes which exhibits a phase transition from an active into an absorbing phase with an unusual type of critical behaviour which had not been seen before. Although the model has attracted considerable interest during the past few years it is not yet clear how its critical behaviour can be characterized and to what extent the diffusive pair-contact process represents an independent universality class. Recent research is reviewed and some standing open questions are outlined.Comment: Latexe2e, 53 pp, with IOP macros, some details adde

Surface Critical Behavior in Systems with Non-Equilibrium Phase Transitions

We study the surface critical behavior of branching-annihilating random walks with an even number of offspring (BARW) and directed percolation (DP) using a variety of theoretical techniques. Above the upper critical dimensions d_c, with d_c=4 (DP) and d_c=2 (BARW), we use mean field theory to analyze the surface phase diagrams using the standard classification into ordinary, special, surface, and extraordinary transitions. For the case of BARW, at or below the upper critical dimension, we use field theoretic methods to study the effects of fluctuations. As in the bulk, the field theory suffers from technical difficulties associated with the presence of a second critical dimension. However, we are still able to analyze the phase diagrams for BARW in d=1,2, which turn out to be very different from their mean field analog. Furthermore, for the case of BARW only (and not for DP), we find two independent surface beta_1 exponents in d=1, arising from two distinct definitions of the order parameter. Using an exact duality transformation on a lattice BARW model in d=1, we uncover a relationship between these two surface beta_1 exponents at the ordinary and special transitions. Many of our predictions are supported using Monte-Carlo simulations of two different models belonging to the BARW universality class.Comment: 19 pages, 12 figures, minor additions, 1 reference adde

Ruthenacycles and Iridacycles as Catalysts for Asymmetric Transfer Hydrogenation and Racemisation

Ruthenacycles, which are easily prepared in a single step by reaction between enantiopure aromatic amines and [Ru(arene)Cl2]2 in the presence of NaOH and KPF6, are very good asymmetric transfer hydrogenation catalysts. A range of aromatic ketones were reduced using isopropanol in good yields with ee’s up to 98%. Iridacycles, which are prepared in similar fashion from [IrCp*Cl2]2 are excellent catalysts for the racemisation of secondary alcohols and chlorohydrins at room temperature. This allowed the development of a new dynamic kinetic resolution of chlorohydrins to the enantiopure epoxides in up to 90% yield and 98% enantiomeric excess (ee) using a mutant of the enzyme Haloalcohol dehalogenase C and an iridacycle as racemisation catalyst.