18 research outputs found
Second Harmonic Generation Imaging of a Magnetic Topological Insulator
A topological insulator (TI) is a type of quantum material that is insulating in the bulk but metallic on the surface. Due to the unique spin properties of the surface electrons, TIs have attracted much interest for their potential applications in spin-based electronics and quantum computers. Even more exotic effects occur when TIs are brought in contact with magnetic materials. This thesis represents a study of two-layer thin films consisting of the TI Bi2Se3 and the magnetic insulator EuS using a nonlinear optical technique called second harmonic generation (SHG) imaging. SHG imaging can probe the crystal and magnetic structure at the surfaces and interfaces of inversion symmetric materials. At the interface between the EuS and Bi2Se3 layers, magnetic domains are expected to form. The domain boundaries are predicted to host chiral edge states, which are dissipationless currents that flow in one direction around a domain. Using SHG imaging, our goal was to visualize the magnetic domains in this magnetic topological insulator system. Even though we have yet to observe any evidence of magnetic domains in this material, we also performed SHG imaging on monolayer MoS2 and were able to visualize distinct crystal grains. Our SHG imaging setup that was improved upon during this thesis has the potential to reveal information about other interesting quantum materials
Rapid and Precise Determination of Zero-Field Splittings by Terahertz Time-Domain Electron Paramagnetic Resonance Spectroscopy
Zero-field splitting (ZFS) parameters are fundamentally tied to the
geometries of metal ion complexes. Despite their critical importance for
understanding the magnetism and spectroscopy of metal complexes, they are not
routinely available through general laboratory-based techniques, and are often
inferred from magnetism data. Here we demonstrate a simple tabletop
experimental approach that enables direct and reliable determination of ZFS
parameters in the terahertz (THz) regime. We report time-domain measurements of
electron paramagnetic resonance (EPR) signals associated with THz-frequency
ZFSs in molecular complexes containing high-spin transition-metal ions. We
measure the temporal profiles of the free-induction decays of spin resonances
in the complexes at zero and nonzero external magnetic fields, and we derive
the EPR spectra via numerical Fourier transformation of the time-domain
signals. In most cases, absolute values of the ZFS parameters are extracted
from the measured zero-field EPR frequencies, and the signs can be determined
by zero-field measurements at two different temperatures. Field-dependent EPR
measurements further allow refined determination of the ZFS parameters and
access to the g-factor. The results show good agreement with those obtained by
other methods. The simplicity of the method portends wide applicability in
chemistry, biology and material science.Comment: 36 pages, 30 figures, 1 tabl
Structural investigation of the bilayer iridate Sr_3Ir_2O_7
A complete structural solution of the bilayer iridate compound Sr_3Ir_2O_7 presently remains outstanding. Previously reported structures for this compound vary and all fail to explain weak structural violations observed in neutron scattering measurements as well as the presence of a net ferromagnetic moment in the basal plane. In this paper, we present single crystal neutron diffraction and rotational anisotropy second harmonic generation measurements unveiling a lower, monoclinic symmetry inherent to Sr_3Ir_2O_7. Combined with density functional theory, our measurements identify the correct structural space group as No. 15 (C2/c) and provide clarity regarding the local symmetry of Ir^(4+) cations within this spin-orbit Mott material
Z topology and superconductivity from symmetry lowering of a 3D Dirac Metal AuPb
3D Dirac semi-metals (DSMs) are materials that have massless Dirac electrons
and exhibit exotic physical properties It has been suggested that structurally
distorting a DSM can create a Topological Insulator (TI), but this has not yet
been experimentally verified. Furthermore, quasiparticle excitations known as
Majorana Fermions have been theoretically proposed to exist in materials that
exhibit superconductivity and topological surface states. Here we show that the
cubic Laves phase AuPb has a bulk Dirac cone above 100 K that gaps out upon
cooling at a structural phase transition to create a topologically non trivial
phase that superconducts below 1.2 K. The nontrivial Z = -1 invariant in
the low temperature phase indicates that AuPb in its superconducting state
must have topological surface states. These characteristics make AuPb a
unique platform for studying the transition between bulk Dirac electrons and
topological surface states as well as studying the interaction of
superconductivity with topological surface states
Structural investigation of the bilayer iridate Sr_3Ir_2O_7
A complete structural solution of the bilayer iridate compound Sr_3Ir_2O_7 presently remains outstanding. Previously reported structures for this compound vary and all fail to explain weak structural violations observed in neutron scattering measurements as well as the presence of a net ferromagnetic moment in the basal plane. In this paper, we present single crystal neutron diffraction and rotational anisotropy second harmonic generation measurements unveiling a lower, monoclinic symmetry inherent to Sr_3Ir_2O_7. Combined with density functional theory, our measurements identify the correct structural space group as No. 15 (C2/c) and provide clarity regarding the local symmetry of Ir^(4+) cations within this spin-orbit Mott material