Aggregation kinetics in a model colloidal suspension

We present molecular dynamics simulations of aggregation kinetics in a colloidal suspension modeled as a highly asymmetric binary mixture. Starting from a configuration with largely uncorrelated colloidal particles the system relaxes by coagulation-fragmentation dynamics to a structured state of low-dimensionality clusters with an exponential size distribution. The results show that short-range repulsive interactions alone can give rise to so-called cluster phases. For the present model and probably other, more common colloids, the observed clusters appear to be equilibrium phase fluctuations induced by the entropic inter-colloidal attractions

Comment on "Metallization of Fluid Nitrogen and the Mott Transition in Highly Compressed Low-Z Fluids"

A comment on ``Metallization of Fluid Nitrogen and the Mott Transition in Highly Compressed Low-Z Fluids'' by Chau et al, Phys. Rev. Lett. 90, 245501 (2003).Comment: Submitted to PR

Comment on "Model for Heat Conduction in Nanofluids"

A Comment on the Letter by D. Hemanth Kumar et al., Phys. Rev. Lett. 93, 144301 (2004)Comment: 2 page

Entropy scaling laws for diffusion

Comment to the letter of Samanta et al., Phys. Rev. Lett. 92, 145901 (2004).Comment: 2 pages, 1 figur

Surface-Directed Spinodal Decomposition in Binary Fluid Mixtures

We consider the phase separation of binary fluids in contact with a surface which is preferentially wetted by one of the components of the mixture. We review the results available for this problem and present new numerical results obtained using a mesoscopic-level simulation technique for the 3-dimensional problem.Comment: RevTeX, 7 figure

Binary Fluids with Long Range Segregating Interaction I: Derivation of Kinetic and Hydrodynamic Equations

We study the evolution of a two component fluid consisting of ``blue'' and ``red'' particles which interact via strong short range (hard core) and weak long range pair potentials. At low temperatures the equilibrium state of the system is one in which there are two coexisting phases. Under suitable choices of space-time scalings and system parameters we first obtain (formally) a mesoscopic kinetic Vlasov-Boltzmann equation for the one particle position and velocity distribution functions, appropriate for a description of the phase segregation kinetics in this system. Further scalings then yield Vlasov-Euler and incompressible Vlasov-Navier-Stokes equations. We also obtain, via the usual truncation of the Chapman-Enskog expansion, compressible Vlasov-Navier-Stokes equations.Comment: TeX, 50 page

Freezing Kinetics in Overcompressed Water

We report high pressure dynamic compression experiments of liquid water along a quasi-adiabatic path leading to the formation of ice VII. We observe dynamic features resembling Van der Waals loops and find that liquid water is compacted to a metastable state close to the ice density before the onset of crystallization. By analyzing the characteristic kinetic time scale involved we estimate the nucleation barrier and conclude that liquid water has been compressed to a high pressure state close to its thermodynamic stability limit