Influence of the initial chemical conditions on the rational design of silica particles

The influence of the water content in the initial composition on the size of silica particles produced using the Stöber process is well known. We have shown that there are three morphological regimes defined by compositional boundaries. At low water levels (below stoichiometric ratio of water:tetraethoxysilane), very high surface area and aggregated structures are formed; at high water content (>40 wt%) similar structures are also seen. Between these two boundary conditions, discrete particles are formed whose size are dictated by the water content. Within the compositional regime that enables the classical Stöber silica, the structural evolution shows a more rapid attainment of final particle size than the rate of formation of silica supporting the monomer addition hypothesis. The clearer understanding of the role of the initial composition on the output of this synthesis method will be of considerable use for the establishment of reliable reproducible silica production for future industrial adoption

Purcell enhancement and focusing effects in plasmonic nanoantenna arrays

This paper presents measured fluorescence results for PMMA dye-coated 5×5 gold plasmonic nanoantenna arrays. We use numerical electromagnetic modeling to show how array size and element spacing can be used to control emitted beam shape and compare this with experimental data. The Friis formula from RF antenna theory is used to calculate the intensity enhancement produced by the array. A figure of merit is then developed, which accounts for the very small mode volume from which the array emission is occurring