Solidification Versus Adsorption for Immobilization of Pollutants in Geopolymeric Materials: A Review

Geopolymer (GP) is a class of three-dimensional aluminosilicate binder, which is superior to Portland cement materials in acid, heat and fire resistance. GP is produced by reacting an aluminosilicate source (metakaolin, fly ash or waste) with an alkali metal hydroxide or silicate. The aim of the present work is to review the latest developments in three lines of research that deal with application of GP in treatment of pollutants. The first “intra-solidification” that involves mixing real waste (containing heavy metal pollutants) with the GP precursors to obtain a high mechanical strength material. The second type of solidification is “inter-solidification” that involves incorporation of heavy metals solutions (as simulation of polluted water) during geopolymerization reaction. The third line of research “adsorption” involves agitating GP with heavy metals solutions and studying the ability of GP to remove heavy metals from water. These techniques will be investigated regarding efficiency and mechanism of immobilization, cost and environmental impact. GPs are strong low-cost adsorbents for heavy metals. In intra-solidification, despite the high mechanical strength of the produced GP-containing waste, geopolymerization reduces effectively the leaching of heavy metals. The reverse was observed in the case of inter-solidification which presents a greater challenge than intra-solidification

Blending Plastics Waste with Highly Available Jordanian Kaolin for Preparation of Alkali-Activated Mortars

Due to their lower energy demand, alkali-activated materials or geopolymers (GPs) are strong candidates to replace ordinary Portland cement binders in some applications. The present article attempts to investigate the possibility of incorporating plastics waste in place of silica sand filler in the GP mortars. The compressive strength, density, FTIR, XRD, BET and SEM of the prepared mortars were evaluated. Satisfactory compressive strength was achieved for metakaolin (MK)-based GP mortars containing plastic fillers (polyvinylchloride (PV), polystyrene (PS), polypropylene (PP) and polyethylene (PE)) which was dependent on the nature of plastic incorporated in the GP matrix: MKPV (30.3 MPa) > MKPS (15.8 MPa)~MKPP (15.9 MPa) > MKPE (9.1 MPa). The 28-day compressive strength of GP containing polyvinyl chloride was almost equivalent to that containing silica sand. Much lower values were obtained for the corresponding kaolin-based GPs (2.5, 2.8, 1.8 and 2.2 MPa, respectively). As reflected by FTIR absorption bands at 1447 and 1400 cm−1, the addition of plastic filler reduces absorption of CO2 from the atmosphere which enhanced dissolution of Al species from metakaolin. The morphology of GPs containing plastic fillers exhibited amorphous tissue-like structure compared to crystalline structure in the case of GP containing silica sand. However, both types of GPs exhibited lower porosity than previously prepared metakaolin-based GPs. Remarkably, poor adhesion of plastic filler to the GP binder was observed due to the inertness of plastic fillers toward alkali activators

Blending Plastics Waste with Highly Available Jordanian Kaolin for Preparation of Alkali-Activated Mortars

Due to their lower energy demand, alkali-activated materials or geopolymers (GPs) are strong candidates to replace ordinary Portland cement binders in some applications. The present article attempts to investigate the possibility of incorporating plastics waste in place of silica sand filler in the GP mortars. The compressive strength, density, FTIR, XRD, BET and SEM of the prepared mortars were evaluated. Satisfactory compressive strength was achieved for metakaolin (MK)-based GP mortars containing plastic fillers (polyvinylchloride (PV), polystyrene (PS), polypropylene (PP) and polyethylene (PE)) which was dependent on the nature of plastic incorporated in the GP matrix: MKPV (30.3 MPa) > MKPS (15.8 MPa)~MKPP (15.9 MPa) > MKPE (9.1 MPa). The 28-day compressive strength of GP containing polyvinyl chloride was almost equivalent to that containing silica sand. Much lower values were obtained for the corresponding kaolin-based GPs (2.5, 2.8, 1.8 and 2.2 MPa, respectively). As reflected by FTIR absorption bands at 1447 and 1400 cm−1, the addition of plastic filler reduces absorption of CO2 from the atmosphere which enhanced dissolution of Al species from metakaolin. The morphology of GPs containing plastic fillers exhibited amorphous tissue-like structure compared to crystalline structure in the case of GP containing silica sand. However, both types of GPs exhibited lower porosity than previously prepared metakaolin-based GPs. Remarkably, poor adhesion of plastic filler to the GP binder was observed due to the inertness of plastic fillers toward alkali activators

Transition Metal Complexes of Schiff Base Ligands Prepared from Reaction of Aminobenzothiazole with Benzaldehydes

Schiff bases have played significant roles in the development of inorganic or coordination chemistry. Three Schiff base (NB, CB and HB) ligands, prepared for the reaction of 2-amino-6-methoxy-benzothiazole with 2-Nitrobenzaldehyde, 2-chlorobenzaldehyde and 2,4-Dihydroxybenzaldehyed, respectively, were investigated for their transition metal complexes, which were prepared by reacting the ligand (2:1 molar ratio) with Co(II), Ni(II), Cu(II), Cd(II), Cr(III) and Fe(III) chlorides. The nature of the interaction between the metal ions and ligands (L) was studied with the aid of magnetic susceptibility, elemental analysis, FTIR and 1H-NMR spectroscopy. Based on the magnetic superstability and elemental analysis results, octahedral structures of the complexes, such as [ML2Cl2] or [ML2Cl(OH)], were proposed for Cu(II), Cd(II), Co(II) and Ni(II) in which the ligand (L:NB, CB or HB) is bidentate through the azomethine and benzothiazole nitrogen. For Cr(III) and Fe(III) complexes, octahedral ML2Cl(OH)2 or ML2(OH)3 structures were proposed, where one ligand is monodentate and the other is bidentate. The azomethine ν(-HC=N-) and 1H-NMR peaks of NB and CB were shifted to a higher frequency and downfield, respectively, upon complexation with metal ions. The bonding of OH groups of HB to Co(II), Cu(II) and Ni(II) enables π-backdonation from these metals to the azomethine of Schiff bases and the consequent shift of ν(-HC=N-) to a lower frequency and changes in the intensity of the 1H-NMR peak of OH. On the other hand, this backdonation was not evidenced in the FTIR of HB complexes with high-charge Cr(III) and Fe(III) ions

Inhibition of <i>Acinetobacter baumannii</i> Biofilm Formation Using Different Treatments of Silica Nanoparticles

There exists a multitude of pathogens that pose a threat to human and public healthcare, collectively referred to as ESKAPE pathogens. These pathogens are capable of producing biofilm, which proves to be quite resistant to elimination. Strains of A. baumannii, identified by the “A” in the acronym ESKAPE, exhibit significant resistance to amoxicillin in vivo due to their ability to form biofilm. This study aims to inhibit bacterial biofilm formation, evaluate novel silica nanoparticles’ effectiveness in inhibiting biofilm, and compare their effectiveness. Amoxicillin was utilized as a positive control, with a concentration exceeding twice that when combined with silica NPs. Treatments included pure silica NPs, silica NPs modified with copper oxide (CuO.SiO2), sodium hydroxide (NaOH.SiO2), and phosphoric acid (H3PO4.SiO2). The characterization of NPs was conducted using scanning electron microscopy (SEM), while safety testing against normal fibroblast cells was employed by MTT assay. The microtiter plate biofilm formation assay was utilized to construct biofilm, with evaluations conducted using three broth media types: brain heart infusion (BHI) with 2% glucose and 2% sucrose, Loria broth (LB) with and without glucose and sucrose, and Dulbecco’s modified eagle medium/nutrient (DMEN/M). Concentrations ranging from 1.0 mg/mL to 0.06 µg/mL were tested using a microdilution assay. Results from SEM showed that pure silica NPs were mesoporous, but in the amorphous shape of the CuO and NaOH treatments, these pores were disrupted, while H3PO4 was composed of sheets. Silica NPs were able to target Acinetobacter biofilms without harming normal cells, with viability rates ranging from 61–73%. The best biofilm formation was achieved using a BHI medium with sugar supplementation, with an absorbance value of 0.35. Biofilms treated with 5.0 mg/mL of amoxicillin as a positive control alongside 1.0 mg/mL of each of the four silica treatments in isolation, resulting in the inhibition of absorbance values of 0.04, 0.13, 0.07, 0.09, and 0.08, for SiO2, CuO.SiO2, NaOH.SiO2 and H3PO4.SiO2, respectively. When amoxicillin was combined, inhibition increased from 0.3 to 0.04; NaOH with amoxicillin resulted in the lowest minimum biofilm inhibitory concentration (MBIC), 0.25 µg/mL, compared to all treatments and amoxicillin, whereas pure silica and composite had the highest MBIC, even when combined with amoxicillin, compared to all treatments, but performed better than that of the amoxicillin alone which gave the MBIC at 625 µg/mL. The absorbance values of MBIC of each treatment showed no significant differences in relation to amoxicillin absorbance value and relation to each other. Our study showed that smaller amoxicillin doses combined with the novel silica nanoparticles may reduce toxic side effects and inhibit biofilm formation, making them viable alternatives to high-concentration dosages. Further investigation is needed to evaluate in vivo activity

Preparation of Chito-Oligomers by Hydrolysis of Chitosan in the Presence of Zeolite as Adsorbent

An increasing interest has recently been shown to use chitin/chitosan oligomers (chito-oligomers) in medicine and food fields because they are not only water-soluble, nontoxic, and biocompatible materials, but they also exhibit numerous biological properties, including antibacterial, antifungal, and antitumor activities, as well as immuno-enhancing effects on animals. Conventional depolymerization methods of chitosan to chito-oligomers are either chemical by acid-hydrolysis under harsh conditions or by enzymatic degradation. In this work, hydrolysis of chitosan to chito-oligomers has been achieved by applying adsorption-separation technique using diluted HCl in the presence of different types of zeolite as adsorbents. The chito-oligomers were retrieved from adsorbents and characterized by differential scanning calorimetry (DSC), liquid chromatography/mass spectroscopy (LC/MS), and ninhydrin test