Ultrafast light-induced response of photoactive yellow protein chromophore analogues

The fluorescence decays of several analogues of the photoactive yellow protein (PYP) chromophore in aqueous solution have been measured by femtosecond fluorescence up-conversion and the corresponding time-resolved fluorescence spectra have been reconstructed. The native chromophore of PYP is a thioester derivative of p-coumaric acid in its trans deprotonated form. Fluorescence kinetics are reported for a thioester phenyl analogue and for two analogues where the thioester group has been changed to amide and carboxylate groups. The kinetics are compared to those we previously reported for the analogues bearing ketone and ester groups. The fluorescence decays of the full series are found to lie in the 1–10 ps range depending on the electron-acceptor character of the substituent, in good agreement with the excited-state relaxation kinetics extracted from transient absorption measurements. Steady-state photolysis is also examined and found to depend strongly on the nature of the substituent. While it has been shown that the ultrafast light-induced response of the chromophore in PYP is controlled by the properties of the protein nanospace, the present results demonstrate that, in solution, the relaxation dynamics and pathway of the chromophore is controlled by its electron donor–acceptor structure: structures of stronger electron donor–acceptor character lead to faster decays and less photoisomerisation

A model for upper kHz QPO coherence of accreting neutron star

{We investigate the coherence of the twin kilohertz quasi-periodic oscillations (kHz QPOs) in the low-mass X-ray binary (LMXB) theoretically. The profile of upper kHz QPO, interpreted as Keplerian frequency, is ascribed to the radial extent of the kHz QPO emission region, associated with the transitional layer at the magnetosphere-disk boundary, which corresponds to the coherence of upper kHz QPO. The theoretical model for Q-factor of upper kHz QPO is applied to the observational data of five Atoll and five Z sources, and the consistence is implied.Comment: accepted by A&

A reaction-diffusion model for the hydration/setting of cement

We propose a heterogeneous reaction-diffusion model for the hydration and setting of cement. The model is based on diffusional ion transport and on cement specific chemical dissolution/precipitation reactions under spatial heterogeneous solid/liquid conditions. We simulate the spatial and temporal evolution of precipitated micro structures starting from initial random configurations of anhydrous cement particles. Though the simulations have been performed for two dimensional systems, we are able to reproduce qualitatively basic features of the cement hydration problem. The proposed model is also applicable to general water/mineral systems.Comment: REVTeX (12 pages), 4 postscript figures, tarred, gzipped, uuencoded using `uufiles', coming with separate file(s). Figure 1 consists of 6 color plates; if you have no color printer try to send it to a black&white postscript-plotte

Effect of the Equivalence Between Topological and Electric Charge on the Magnetization of the Hall Ferromagnet

The dependence on temperature of the spin magnetization of a two-dimensional electron gas at filling factor unity is studied. Using classical Monte Carlo simulations we analyze the effect that the equivalence between topological and electrical charge has on the the behavior of the magnetization. We find that at intermediate temperatures the spin polarization increases in a thirty per cent due to the Hartree interaction between charge fluctuations.Comment: 4 pages. Submitted to Phys.Rev.

Skyrme Crystal In A Two-Dimensional Electron Gas

The ground state of a two-dimensional electron gas at Landau level filling factors near $\nu =1$ is a Skyrme crystal with long range order in the positions and orientations of the topologically and electrically charged elementary excitations of the $\nu=1$ ferromagnetic ground state. The lowest energy Skyrme crystal is a square lattice with opposing postures for topological excitations on opposite sublattices. The filling factor dependence of the electron spin-polarization, calculated for the square lattice Skyrme crystal, is in excellent agreement with recent experiments.Comment: 3 pages, latex, 3 figures available upon request from [email protected]

Application of wavelets to singular integral scattering equations

The use of orthonormal wavelet basis functions for solving singular integral scattering equations is investigated. It is shown that these basis functions lead to sparse matrix equations which can be solved by iterative techniques. The scaling properties of wavelets are used to derive an efficient method for evaluating the singular integrals. The accuracy and efficiency of the wavelet transforms is demonstrated by solving the two-body T-matrix equation without partial wave projection. The resulting matrix equation which is characteristic of multiparticle integral scattering equations is found to provide an efficient method for obtaining accurate approximate solutions to the integral equation. These results indicate that wavelet transforms may provide a useful tool for studying few-body systems.Comment: 11 pages, 4 figure

Single-Particle Pseudogap in Two-Dimensional Electron Systems

We investigate pseudogap phenomena in the 2D electron system. Based on the mode-mode coupling theory of antiferromagnetic (AFM) and $d_{x^2-y^2}$-wave superconducting ($d$SC) fluctuations, single-particle dynamics is analyzed. For the parameter values of underdoped cuprates, pseudogap structure grows in the single-particle spectral weight $A(k,\omega)$ around the wave vector $(\pi,0)$ and $(0,\pi)$ below the pseudo-spin-gap temperature \TPG signaled by the reduction of dynamical spin correlations in qualitative agreement with the experimental data. The calculated results for the overdoped cuprates also reproduce the absence of the pseudogap in the experiments. We also discuss limitations of our weak-coupling approach.Comment: 6 pages with 4 figures, submitted to J. Phys. Soc. Jp

Evolution of AQL X-1 During the Rising Phase of its 1998 Outburst

We present results from 16 snapshots of Aql X-1 with RXTE during the rising phase of its recent outburst. The observations were carried out at a typical rate of once or twice per day. The source shows interesting spectral evolution during this period. Phenomenologically, it bears remarkable similarities to ``atoll'' sources. Shortly after the onset of the outburst, the source is seen to be in an ``island'' state, but with little X-ray variability. It then appears to have made a rapid spectral transition (on a time scale less than half a day) to another ``island'' state, where it evolves slightly and stays for 4 days. In this state, the observed X-ray flux becomes increasingly variable as the source brightens. Quasi-period oscillation (QPO) in the X-ray intensity is detected in the frequency range 670--870 Hz. The QPO frequency increases with the X-ray flux while its fractional rms decreases. The QPO becomes undetectable following a transition to a ``banana'' state, where the source continues its evolution by moving up and down the ``banana'' branch in the color-color diagram as the flux (presumably, the mass accretion rate) fluctuates around the peak of the outburst. Throughout the entire period, the power density spectrum is dominated by very-low frequency noises. Little power can be seen above ~1 Hz, which is different from typical ``atoll'' sources. In the ``banana'' state, the overall X-ray variability remains low (with fractional rms ~3--4%) but roughly constant. The observed X-ray spectrum is soft with few photons from above $\sim$25 keV, implying the thermal origin of the emission. The evolution of both spectral and temporal X-ray properties is discussed in the context of disk-instability models.Comment: 13 pages, including one table and five figures. To appear in ApJ Letters (July 20