38 research outputs found

    Moir\'e Intralayer Excitons in a MoSe2_2/MoS2_2 Heterostructure

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    Spatially periodic structures with a long range period, referred to as moir\'e pattern, can be obtained in van der Waals bilayers in the presence of a small stacking angle or of lattice mismatch between the monolayers. Theoretical predictions suggest that the resulting spatially periodic variation of the band structure modifies the optical properties of both intra and interlayer excitons of transition metal dichalcogenides heterostructures. Here, we report on the impact of the moir\'e pattern formed in a MoSe2_2/MoS2_2 heterobilayer encapsulated in hexagonal boron nitride. The periodic in-plane potential results in a splitting of the MoSe2_2 exciton and trion in both emission and absorption spectra. The observed energy difference between the split peaks is fully consistent with theoretical predictions.Comment: just accepted in Nano Letters (10.1021/acs.nanolett.8b03266

    Brightening of dark excitons in 2D perovskites

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    Optically inactive dark exciton states play an important role in light emission processes in semiconductors because they provide an efficient nonradiative recombination channel. Understanding the exciton fine structure in materials with potential applications in light-emitting devices is therefore critical. Here, we investigate the exciton fine structure in the family of two-dimensional (2D) perovskites (PEA)(2)SnI(4), (PEA)(2)PbI(4), and (PEA)(2)PbBr(4). In-plane magnetic field mixes the bright and dark exciton states, brightening the otherwise optically inactive dark exciton. The bright-dark splitting increases with increasing exciton binding energy. Hot photoluminescence is observed, indicative of a non-Boltzmann distribution of the bright-dark exciton populations. We attribute this to the phonon bottleneck, which results from the weak exciton–acoustic phonon coupling in soft 2D perovskites. Hot photoluminescence is responsible for the strong emission observed in these materials, despite the substantial bright-dark exciton splitting

    Recommendations of the Polish Society of Gynaecologists and Obstetricians for removal of the uterus by vaginal, laparoscopic and abdominal routes

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    The recommendations represent the current procedure, which may be modified and changed where justified, after a thoroughanalysis of the given clinical situation, which may be the basis for their modification and updating in the future

    Intervalley Scattering of Interlayer Excitons in a MoS2_2/MoSe2_2/MoS2_2 Heterostructure in High Magnetic Field

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    Degenerate extrema in the energy dispersion of charge carriers in solids, also referred to as valleys, can be regarded as a binary quantum degree of freedom, which can potentially be used to implement valleytronic concepts in van der Waals heterostructures based on transition metal dichalcogenides. Using magneto-photoluminescence spectroscopy, we achieve a deeper insight into the valley polarization and depolarization mechanisms of interlayer excitons formed across a MoS2_2/MoSe2_2/MoS2_2 heterostructure. We account for the non-trivial behavior of the valley polarization as a function of the magnetic field by considering the interplay between exchange interaction and phonon mediated intervalley scattering in a system consisting of Zeeman-split energy levels. Our results represent a crucial step towards the understanding of the properties of interlayer excitons, with strong implications for the implementation of atomically thin valleytronic devices.Comment: just accepted in Nano Letters, DOI: 10.1021/acs.nanolett.8b0148

    Peri-operative red blood cell transfusion in neonates and infants: NEonate and Children audiT of Anaesthesia pRactice IN Europe: A prospective European multicentre observational study

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    BACKGROUND: Little is known about current clinical practice concerning peri-operative red blood cell transfusion in neonates and small infants. Guidelines suggest transfusions based on haemoglobin thresholds ranging from 8.5 to 12 g dl-1, distinguishing between children from birth to day 7 (week 1), from day 8 to day 14 (week 2) or from day 15 (≄week 3) onwards. OBJECTIVE: To observe peri-operative red blood cell transfusion practice according to guidelines in relation to patient outcome. DESIGN: A multicentre observational study. SETTING: The NEonate-Children sTudy of Anaesthesia pRactice IN Europe (NECTARINE) trial recruited patients up to 60 weeks' postmenstrual age undergoing anaesthesia for surgical or diagnostic procedures from 165 centres in 31 European countries between March 2016 and January 2017. PATIENTS: The data included 5609 patients undergoing 6542 procedures. Inclusion criteria was a peri-operative red blood cell transfusion. MAIN OUTCOME MEASURES: The primary endpoint was the haemoglobin level triggering a transfusion for neonates in week 1, week 2 and week 3. Secondary endpoints were transfusion volumes, 'delta haemoglobin' (preprocedure - transfusion-triggering) and 30-day and 90-day morbidity and mortality. RESULTS: Peri-operative red blood cell transfusions were recorded during 447 procedures (6.9%). The median haemoglobin levels triggering a transfusion were 9.6 [IQR 8.7 to 10.9] g dl-1 for neonates in week 1, 9.6 [7.7 to 10.4] g dl-1 in week 2 and 8.0 [7.3 to 9.0] g dl-1 in week 3. The median transfusion volume was 17.1 [11.1 to 26.4] ml kg-1 with a median delta haemoglobin of 1.8 [0.0 to 3.6] g dl-1. Thirty-day morbidity was 47.8% with an overall mortality of 11.3%. CONCLUSIONS: Results indicate lower transfusion-triggering haemoglobin thresholds in clinical practice than suggested by current guidelines. The high morbidity and mortality of this NECTARINE sub-cohort calls for investigative action and evidence-based guidelines addressing peri-operative red blood cell transfusions strategies. TRIAL REGISTRATION: ClinicalTrials.gov, identifier: NCT02350348

    Bayesian optimization for solving high-frequency passive component design problems

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    In this paper, the performance of the Bayesian Optimization (BO) technique applied to various problems of microwave engineering is studied. Bayesian optimization is a novel, non-deterministic, global optimization scheme that uses machine learning to solve complex optimization problems. However, each new optimization scheme needs to be evaluated to find its best application niche, as there is no universal technique that suits all problems. Here, BO was applied to different types of microwave and antenna engineering problems, including matching circuit design, multiband antenna and antenna array design, or microwave filter design. Since each of the presented problems has a different nature and characteristics such as different scales (i.e. number of design variables), we try to address the question about the generality of BO and identify the problem areas for which the technique is or is not recommended

    Comparison of the Usability of Apple M2 and M1 Processors for Various Machine Learning Tasks

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    Thispaper compares the usability of various Apple MacBook Pro laptops were tested for basic machine learning research applications, including text-based, vision-based, and tabular data. Four tests/benchmarks were conducted using four different MacBook Pro models—M1, M1 Pro, M2, and M2 Pro. A script written in Swift was used to train and evaluate four machine learning models using the Create ML framework, and the process was repeated three times. The script also measured performance metrics, including time results. The results were presented in tables, allowing for a comparison of the performance of each device and the impact of their hardware architectures

    Innovative approach in analysis of EEG and EMG signals — Comparision of the two novel methods

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    In this paper comparison of the two innovative signal processing methods for analysis of both EEG and EMG biomedical signals is in short presented. The reason for that is caused by the fact, that nowadays the broad analysis of various biomedical signals is extremely popular. The first method presented in this paper relies on kernel density estimators application. Implementation of such method enables construction of densitograms for the examined bio-signals. One of the biggest advantages of this method is that it allows to obtain statistically filtered signals, which results in making the whole signal processing task significantly quicker. The second method described in this paper is based on basic mathematical operations only. Despite its simplicity the whole process can be implemented on almost any hardware platform, including those with very limited computational capabilities. Also it makes the task quick. In accordance with the conducted experiments - the method is also efficient and as it can also be implemented on embedded platform and the algorithm can be rewritten in any programming language, the potential application of this method is wide
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