The Mechanism and Application of Deep-Hole Precracking Blasting on Rockburst Prevention

The mechanism of preventing rockburst through deep-hole precracking blasting was studied based on experimental test, numerical simulation, and field testing. The study results indicate that the deep-hole precracking could change the bursting proneness and stress state of coal-rock mass, thereby preventing the occurrence of rockburst. The bursting proneness of the whole composite structure could be weakened by the deep-hole precracking blasting. The change of stress state in the process of precracking blasting is achieved in two ways: (1) artificially break the roof apart, thus weakening the continuity of the roof strata, effectively inducing the roof caving while reducing its impact strength; and (2) the dynamic shattering and air pressure generated by the blasting can structurally change the properties of the coal-rock mass by mitigating the high stress generation and high elastic energy accumulation, thus breaking the conditions of energy transfer and rock burst occurrence

Strength Damage and Acoustic Emission Characteristics of Water-Bearing Coal Pillar Dam Samples from Shangwan Mine, China

Long-term erosion and repeated scouring of water significantly affect the technical properties of coals, which are the essential elements that must be considered in evaluating an underground reservoir coal column dam’s standing sustainability. In the paper, the coal pillar dam body of the 22 layers of coal in the Shangwan Coal Mine is studied (22 represents No. 2 coal seam), and the water content of this coal pillar dam body is simplified into two types of different water content and dry–wet cycle. Through acoustic emission detection technology and energy dissipation analysis method, the internal failure mechanism of coal water action is analyzed. This study revealed three findings. (1) The crest pressure, strain, and resilient modulus in the coal sample were inversely related to the water content along with the dry–wet cycle number, while the drying–wetting cycle process had a certain time effect on the failure to the sample. (2) As the moisture content and the dry–wet cycle times incremented, three features were shown: first, the breakage pattern is the mainly stretching fracture for the coal specimen; second, the number and absolute value of acoustic emission count peaks decrease; third, the RA-AF probability density plot (RA is the ratio of AE Risetime and Amplitude, and AF is the ratio of AE Count and Duration) corresponds more closely to the large-scale destruction characteristics for the coal samples. (3) A higher quantity of wet and dry cycles results in a smoother energy dissipation curve in the compacted and flexible phases of the crack, indicating that this energy is released earlier. The research results can be applied to the long-term sustainability assessment of the dams of coal columns for underground reservoirs and can also serve as valuable content to the excogitation of water-bearing coal column dams under similar engineering conditions

Direct fabrication of flexible strain sensor with adjustable gauge factor on medical catheters

The preparation of flexible sensors on medical catheters is primarily an indirect process using certain materials as substrates. Using medical catheters as flexible substrates is beneficial for directly detecting the strain and contact force of the catheters. In this study, a strain sensor is prepared by rubbing graphite on a silicone medical catheter with a minimum inner diameter of 1 mm × 2 mm. The gauge factor (GF) of the strain sensor is adjusted by changing the resistance during preparation. By precisely controlling the composite material seepage zone, the maximum achievable GF is 121 at a low strain of 1%, which can be used to detect low forces with a resolution of 0.0013 N. Liquid glue is used to encapsulate the sensor, which barely changes the conductive network of the sensor. The response time of the strain sensor is 50 ms, and the performance of the sensor remains unchanged after 1000 cycles, which renders it suitable for intestinal shape detection. Additionally, we demonstrate the feasibility of integrating four strain sensors on the medical catheter to detect its bending direction via vector synthesis, which allows the spatial shape to be examined. The results obtained indicate the potential of the friction method for preparing strain sensors with different GFs on medical catheters to be used in different medical applications

Construction of Novel Thermostable Chimeric Vaccine Candidates for Genotype VII Newcastle Disease Virus

Genotype VII Newcastle Disease Virus (NDV) has caused a pandemic in many countries and usually causes fatal consequences in infected chickens. Although current commercial attenuated NDV vaccines can provide an ideal protection against genotype VII NDV, they cannot completely prevent the infection and viral shedding, and the genotype of some vaccine strains cannot match with the prevalent strain. In this study, in order to construct a thermostable and genotype VII-matched live attenuated vaccine, we used a thermostable genotype VIII virulent HR09 strain as the backbone and replaced its F gene with that of the genotype VII DT-2014 strain. Meanwhile, the cleavage site of F gene of DT-2014 was mutated to that of class I F protein and avirulent class II F protein, respectively. The results showed that the two chimeric viruses, designated rcHR09-CI and rcHR09-CII, shared a similar growth kinetics and thermostability with their parental HR09 strain. Mean death time (MDT) and intracerebral pathogenicity index (ICPI) tests showed that the two chimeric viruses were highly attenuated. Though both chimeric NDVs and La Sota vaccine strain could provide complete protection to immunized chickens against the challenge of virulent genotype VII ZJ1 strain, the two chimeric NDVs could induce a higher level of antibody response against ZJ1 strain and could significantly reduce the viral shedding compared with La Sota vaccine strain. In conclusion, our study constructed two chimeric thermostable genotype VII-matched NDV vaccine candidates, which provided complete protection against the challenge of virulent genotype VII NDV

Toward High-Performance Electrochromic Conjugated Polymers: Influence of Local Chemical Environment and Side-Chain Engineering

Three homologous electrochromic conjugated polymers, each containing an asymmetric building block but decorated with distinct alkyl chains, were designed and synthesized using electrochemical polymerization in this study. The corresponding monomers, namely T610FBTT810, DT6FBT, and DT48FBT, comprise the same backbone structure, i.e., an asymmetric 5-fluorobenzo[c][1,2,5]thiadiazole unit substituted by two thiophene terminals, but were decorated with different types of alkyl chain (hexyl, 2-butyloctyl, 2-hexyldecyl, or 2-octyldecyl). The effects of the side-chain structure and asymmetric repeating unit on the optical absorption, electrochemistry, morphology, and electrochromic properties were investigated comparatively. It was found that the electrochromism conjugated polymer, originating from DT6FBT with the shortest and linear alkyl chain, exhibits the best electrochromic performance with a 25% optical contrast ratio and a 0.3 s response time. The flexible electrochromic device of PDT6FBT achieved reversible colors of navy and cyan between the neutral and oxidized states, consistent with the non-device phenomenon. These results demonstrate that subtle modification of the side chain is able to change the electrochromic properties of conjugated polymers