7,152 research outputs found
Building Design and Construction over Organic Soil
A lowrise office building was constructed on a mat foundation over a thick peat deposit that had been preconsolidated beneath surface fill. Environmental restrictions prevented use of deep foundations for fear that penetration through an aquaclude would permit contamination of a deeper water table. This paper describes the laboratory testing and field instrumentation programs, as well as the special geotechnical and structural analysis undertaken for the design and construction of this project. Included in the program were long-term consolidation tests, pressuremeter tests, use of heave markers, inclinometers and pore pressure piezometers. A site history was also developed to define the extent and nature of the surficial fill. To achieve much of the anticipated initial settlement, the basement was temporarily flooded, thus preloading with the full building weight. Water was removed as construction proceeded so that the full building weight was always maintained. Actual settlement was observed to agree fairly well with predicted settlements
Unexpected Caisson Problems, Soil Structure Interaction Predictions and Required Ground Modification
Recent advances in strain measurement using optical fibers provide new opportunities for monitoring the performance of geotechnical structures during and after construction. Brillouin optical time-domain reflectometry (BOTDR) is an innovative technique that allows measurement of full strain profiles using standard optical fibers. In this paper, two case studies illustrating the application of the distributed optical fiber strain sensors are presented. One is monitoring of an old masonry tunnel when a new tunnel was constructed nearby and the other is monitoring the behavior of secant piled walls for basement construction. Both sites are located in London. The advantages and limitations of this new sensor technology for monitoring geotechnical structures are discussed.
The paper describes the caisson construction problems encountered and the required modification necessary for a 55-story residential high-rise in Chicago’s near north side. Belled caissons were planned on a very thin hardpan bearing layer which was underlain by water bearing dense silt that extended to dolomite bedrock. Three filtered dewatering wells extending into the fractured rock surface were planned to reduce the hydrostatic pressure head within the silt to permit the belled construction. A complete collapse of the dense silt layer during the installation of the first dewatering well undermined the planned belled caisson foundation system. An additional subsurface investigation, a compaction grouting program and further in-situ pressuremeter testing was then performed. Subsequent modified performance predictions required the addition of selective micropile underpinning after completion of the planned system of grade beams and belled caisson installation. Settlement monitoring during building construction confirmed settlements within or less than the predicted settlement range
Improved Quantum Hard-Sphere Ground-State Equations of State
The London ground-state energy formula as a function of number density for a
system of identical boson hard spheres, corrected for the reduced mass of a
pair of particles in a sphere-of-influence picture, and generalized to fermion
hard-sphere systems with two and four intrinsic degrees of freedom, has a
double-pole at the ultimate \textit{regular} (or periodic, e.g.,
face-centered-cubic) close-packing density usually associated with a
crystalline branch. Improved fluid branches are contructed based upon exact,
field-theoretic perturbation-theory low-density expansions for many-boson and
many-fermion systems, appropriately extrapolated to intermediate densities, but
whose ultimate density is irregular or \textit{random} closest close-packing as
suggested in studies of a classical system of hard spheres. Results show
substantially improved agreement with the best available Green-function Monte
Carlo and diffusion Monte Carlo simulations for bosons, as well as with ladder,
variational Fermi hypernetted chain, and so-called L-expansion data for
two-component fermions.Comment: 15 pages and 7 figure
Complexity and Inapproximability Results for Parallel Task Scheduling and Strip Packing
We study the Parallel Task Scheduling problem with a
constant number of machines. This problem is known to be strongly NP-complete
for each , while it is solvable in pseudo-polynomial time for each . We give a positive answer to the long-standing open question whether
this problem is strongly -complete for . As a second result, we
improve the lower bound of for approximating pseudo-polynomial
Strip Packing to . Since the best known approximation algorithm
for this problem has a ratio of , this result
narrows the gap between approximation ratio and inapproximability result by a
significant step. Both results are proven by a reduction from the strongly
-complete problem 3-Partition
A novel thiol-labile cysteine protecting group for peptide synthesis based on a pyridazinedione (PD) scaffold
Herein we report a thiol-labile cysteine protecting group based on an unsaturated pyridazinedione (PD) scaffold. We establish compatibility of the PD in conventional solid phase peptide synthesis (SPPS), showcasing this in the on-resin synthesis of biologically relevant oxytocin. Furthermore, we establish the applicability of the PD protecting group towards both microwave-assisted SPPS and native chemical ligation (NCL) in a model system
Thermodynamics of low dimensional spin-1/2 Heisenberg ferromagnets in an external magnetic field within Green function formalism
The thermodynamics of low dimensional spin-1/2 Heisenberg ferromagnets (HFM)
in an external magnetic field is investigated within a second-order two-time
Green function formalism in the wide temperature and field range. A crucial
point of the proposed scheme is a proper account of the analytical properties
for the approximate transverse commutator Green function obtained as a result
of the decoupling procedure. A good quantitative description of the correlation
functions, magnetization, susceptibility, and heat capacity of the HFM on a
chain, square and triangular lattices is found for both infinite and
finite-sized systems. The dependences of the thermodynamic functions of 2D HFM
on the cluster size are studied. The obtained results agree well with the
corresponding data found by Bethe ansatz, exact diagonalization, high
temperature series expansions, and quantum Monte Carlo simulations.Comment: 11 pages, 14 figure
One-pot thiol–amine bioconjugation to maleimides: simultaneous stabilisation and dual functionalisation
Maleimide chemistry is widely used in the site-selective modification of proteins. However, hydrolysis of the resultant thiosuccinimides is required to provide robust stability to the bioconjugates. Herein, we present an alternative approach that affords simultaneous stabilisation and dual functionalisation in a one pot fashion. By consecutive conjugation of a thiol and an amine to dibromomaleimides, we show that aminothiomaleimides can be generated extremely efficiently. Furthermore, the amine serves to deactivate the electrophilicity of the maleimide, precluding further reactivity and hence generating stable conjugates. We have applied this conjugation strategy to peptides and proteins to generate stabilised trifunctional conjugates. We propose that this stabilisation-dual modification strategy could have widespread use in the generation of diverse conjugates
Families of Graphs with W_r({G},q) Functions That Are Nonanalytic at 1/q=0
Denoting as the chromatic polynomial for coloring an -vertex
graph with colors, and considering the limiting function , a fundamental question in graph theory is the
following: is analytic or not at the origin
of the plane? (where the complex generalization of is assumed). This
question is also relevant in statistical mechanics because
, where is the ground state entropy of the
-state Potts antiferromagnet on the lattice graph , and the
analyticity of at is necessary for the large- series
expansions of . Although is analytic at for many
, there are some for which it is not; for these, has no
large- series expansion. It is important to understand the reason for this
nonanalyticity. Here we give a general condition that determines whether or not
a particular is analytic at and explains the
nonanalyticity where it occurs. We also construct infinite families of graphs
with functions that are non-analytic at and investigate the
properties of these functions. Our results are consistent with the conjecture
that a sufficient condition for to be analytic at is
that is a regular lattice graph . (This is known not to be a
necessary condition).Comment: 22 pages, Revtex, 4 encapsulated postscript figures, to appear in
Phys. Rev.
Corrections to scaling in 2--dimensional polymer statistics
Writing for the mean
square end--to--end length of a self--avoiding polymer chain of
links, we have calculated for the two--dimensional {\em continuum}
case from a new {\em finite} perturbation method based on the ground state of
Edwards self consistent solution which predicts the (exact) exponent.
This calculation yields . A finite size scaling analysis of data
generated for the continuum using a biased sampling Monte Carlo algorithm
supports this value, as does a re--analysis of exact data for two--dimensional
lattices.Comment: 10 pages of RevTex, 5 Postscript figures. Accepted for publication in
Phys. Rev. B. Brief Reports. Also submitted to J. Phys.
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