On excess entropy and latent heat in crystallizing white dwarfs

Based on the linear mixing approach, we calculate the latent heat for crystallizing fully-ionized $^{12}$C/$^{16}$O and $^{16}$O/$^{20}$Ne mixtures in white dwarf (WD) cores for two different parametrizations of the corrections to the linear-mixing energies and with account of ion quantum effects. We report noticeable composition-dependent deviations of the excess entropy in both directions from the standard value of 0.77 per ion. Within the same framework, we evaluate the excess entropy and released or absorbed heat accompanying the exsolution process in solidified WD layers. The inclusion of this effect is shown to be important for reliable interpretation of WD cooling data. We also analyze the latent heat of crystallizing eutectic $^{12}$C/$^{22}$Ne mixture, where we find a qualitative dependence of both the phase diagram and the latent heat behaviour on ion quantum effects. This may be important for the model with $^{22}$Ne distillation in cooling C/O/$^{22}$Ne WD proposed as a solution for the ultramassive WD multi-Gyr cooling anomaly. Astrophysical implications of our findings for crystallizing WD are discussed.Comment: 5 pages, 2 figures. Letter to MNRAS, in pres

Phase diagrams of binary ionic mixtures and white dwarf cooling

Phase diagrams of fully ionized binary ionic mixtures are considered within the framework of the linear mixing formalism taking into account recent advances in understanding quantum one-component plasma thermodynamics. We have followed a transformation of azeotropic phase diagrams into peritectic and eutectic types with increase of the charge ratio. For solid $^{12}$C/$^{16}$O and $^{16}$O/$^{20}$Ne mixtures, we have found extensive miscibility gaps. Their appearance seems to be a robust feature of the theory. The gaps evolve naturally into two-solid regions of eutectic phase diagrams at higher $Z_2/Z_1$. They do not depend on thermodynamic fit extensions beyond their applicability limits. The gaps are sensitive to binary mixture composition and physics, being strongly different for C/O and O/Ne mixtures and for the three variants of corrections to linear-mixing solid-state energies available in the literature. When matter cools to its miscibility gap temperature, the exsolution process takes place. It results in a separation of heavier and lighter solid solutions. This may represent a significant reservoir of gravitational energy and should be included in future white dwarf (WD) cooling simulations. Ion quantum effects mostly resulted in moderate modifications, however, for certain $Z_2/Z_1$, these effects can produce qualitative restructuring of the phase diagram. This may be important for the model with $^{22}$Ne distillation in cooling C/O/Ne WD proposed as a solution for the ultramassive WD cooling anomaly.Comment: 13 pages, 8 figures, accepted in MNRA