9 research outputs found
Probabilistic design of a molybdenum-base alloy using a neural network
An artificial intelligence tool is exploited to discover and characterize a new molybdenum-base alloy that is the most likely to simultaneously satisfy targets of cost, phase stability, precipitate content, yield stress, and hardness. Experimental testing demonstrates that the proposed alloy fulfills the computational predictions, and furthermore the physical properties exceed those of other commercially available Mo-base alloys for forging-die applications.The authors acknowledge the financial support of Rolls-Royce plc, EPSRC under EP/H022309/1 and EP/H500375/1, the Royal Society, and Gonville & Caius College
Design of a nickel-base superalloy using a neural network
A new computational tool has been developed to model, discover, and optimize
new alloys that simultaneously satisfy up to eleven physical criteria. An
artificial neural network is trained from pre-existing materials data that
enables the prediction of individual material properties both as a function of
composition and heat treatment routine, which allows it to optimize the
material properties to search for the material with properties most likely to
exceed a target criteria. We design a new polycrystalline nickel-base
superalloy with the optimal combination of cost, density, gamma' phase content
and solvus, phase stability, fatigue life, yield stress, ultimate tensile
strength, stress rupture, oxidation resistance, and tensile elongation.
Experimental data demonstrates that the proposed alloy fulfills the
computational predictions, possessing multiple physical properties,
particularly oxidation resistance and yield stress, that exceed existing
commercially available alloys
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On the entropic stabilisation of an Al<inf>0.5</inf>CrFeCoNiCu high entropy alloy
The extent to which configurational entropy can stabilise a single solid solution in an Al0.5CrFeCoNiCu high entropy alloy has been assessed through characteristion of samples following casting and heat treatment at 1000 C. At temperatures between 1000 C and the onset of melting, the alloy was shown to be within a two phase field and these phases were stable following prolonged exposure at elevated temperature. X-ray and transmission electron diffraction indicated that both constituent phases had an fcc structure. Therefore, these phases share a Gibbs energy curve that must contain two local minima at the solidus temperature, rather than the single minimum required for a continuous solid solution. These
observations indicate that there is no temperature at which this material is in a stable, solid state single phase field and that therefore, the configurational complexity is insufficient to stabilise a solid solution phase against enthalpic effects.EPSRC/Rolls-Royce Strategic partnership for funding (NGJ, AB and HJS under EP/H500375/1, JWA and BDC under EP/H022309/1).This is the final published manuscript distributed under a Creative Commons Attribution License 2.0 UK. This article can also be viewed on the publisher's website at: http://www.sciencedirect.com/science/article/pii/S0966979514001848
On the entropic stabilisation of an Al0.5CrFeCoNiCu high entropy alloy
This is the final published manuscript distributed under a Creative Commons Attribution License 2.0 UK. This article can also be viewed on the publisher's website at: http://www.sciencedirect.com/science/article/pii/S0966979514001848#The extent to which configurational entropy can stabilise a single solid solution in an Al0.5CrFeCoNiCu high entropy alloy has been assessed through characteristion of samples following casting and heat treatment at 1000 C. At temperatures between 1000 C and the onset of melting, the alloy was shown to be within a two phase field and these phases were stable following prolonged exposure at elevated temperature. X-ray and transmission electron diffraction indicated that both constituent phases had an fcc structure. Therefore, these phases share a Gibbs energy curve that must contain two local minima at the solidus temperature, rather than the single minimum required for a continuous solid solution. These
observations indicate that there is no temperature at which this material is in a stable, solid state single phase field and that therefore, the configurational complexity is insufficient to stabilise a solid solution phase against enthalpic effects.EPSRC/Rolls-Royce Strategic partnership for funding (NGJ, AB and HJS under EP/H500375/1, JWA and BDC under EP/H022309/1)
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Probabilistic neural network identification of an alloy for direct laser deposition
A neural network tool was used to discover a new nickel-base alloy for direct laser deposition most likely to satisfy targets of processability, cost, density, phase stability, creep resistance, oxidation, fatigue life, and resistance to thermal stresses. The neural network tool can learn property-property relationships, which allows it to use a large database of thermal resistance measurements to guide the extrapolation of just ten data entries of alloy processability. The tool was used to propose a new alloy, and experimental testing confirms that the physical properties of the proposed alloy are better tailored to the target application than other available commercial alloys
Parthenogenesis in insects: the centriole renaissance
Building a new organism usually requires the contribution of two differently shaped haploid cells, the male and female gametes, each providing its genetic material to restore diploidy of the new born zygote. The successful execution of this process requires defined sequential steps that must be completed in space and time. Otherwise, development fails. Relevant among the earlier steps are pronuclear migration and formation of the first mitotic spindle that promote the mixing of parental chromosomes and the formation of the zygotic nucleus. A complex microtubule network ensures the proper execution of these processes. Instrumental to microtubule organization and bipolar spindle assembly is a distinct non-membranous organelle, the centrosome. Centrosome inheritance during fertilization is biparental, since both gametes provide essential components to build a functional centrosome. This model does not explain, however, centrosome formation during parthenogenetic development, a special mode of sexual reproduction in which the unfertilized egg develops without the contribution of the male gamete. Moreover, whereas fertilization is a relevant example in which the cells actively check the presence of only one centrosome, to avoid multipolar spindle formation, the development of parthenogenetic eggs is ensured, at least in insects, by the de novo assembly of multiple centrosomes. Here, we will focus our attention on the assembly of functional centrosomes following fertilization and during parthenogenetic development in insects. Parthenogenetic development in which unfertilized eggs are naturally depleted of centrosomes would provide a useful experimental system to investigate centriole assembly and duplication together with centrosome formation and maturation