18 research outputs found
The mercury photosensitized reaction of dimethyl ether
The mercury photosensitized reaction of dimethyl ether has been investigated at pressures between 28 and 500 mm and at temperatures between 25°C and 292°C. At 25°C the products consist almost entirely of hydrogen and 1,2-dimethoxyethane, and the initial step has been shown to be the abstraction of a hydrogen atom.At higher temperatures CH2O, CH4, C2H6 and probably CH3OC2H5 become important products. They are derived from the decomposition of the methoxy methyl radical followed by subsequent radical recombination reactions. Carbon monoxide is produced in the later stages from the decomposition of formaldehyde.By varying the light intensity and pressure it has been shown that ethane and dimethoxyethane are produced by second order recombination of methyl and methoxy methyl radicals respectively. The activation energies of the following reactions have been estimated: CH3+CH3OCH3→CH4+CH3OCH2 E=9.0 kcal. CH3OCH2→CH3+CH2O E=19 kcal., the only assumption being that methyl and methoxy methyl radicals recombine with zero activation energy
Constraints on Hidden Photon Models from Electron g-2 and Hydrogen Spectroscopy
The hidden photon model is one of the simplest models which can explain the
anomaly of the muon anomalous magnetic moment (g-2). The experimental
constraints are studied in detail, which come from the electron g-2 and the
hydrogen transition frequencies. The input parameters are set carefully in
order to take dark photon contributions into account and to prevent the
analysis from being self-inconsistent. It is shown that the new analysis
provides a constraint severer by more than one order of magnitude than the
previous result.Comment: 18 pages, 2 figures, 1 table. v2: minor correction