Spin-phonon coupling in multiferroic RCrO3_3 (R-Y, Lu, Gd, Eu, Sm): A Raman study

Raman study on a select few orthochromites, RCrO$_3$ (R = Y, Lu, Gd, Eu and Sm) shows that the phonon behavior at TN in compounds with magnetic R-ion (Gd and Sm) is remarkably different from that of non-magnetic R-ion (Y, Lu and Eu). While anomalies in most of the observed phonon frequencies in all these compounds may result from the distortion of CrO$_6$ octahedra due to size effect and magnetostriction arising from Cr-ordering, the anomalous behavior of their linewidths observed at TN for the compounds with only magnetic R-ion suggests spin-phonon coupling. The presence of spin-phonon coupling and the anomalies in the low frequency modes related to R-ion motion in orthochromites (R = Gd and Sm) support the suggestion that the coupling between 4f-3d moments play important role in inducing switchable electric polarization.Comment: 6 pages (two column format), 7 figures; The updated version of the manuscript can be found at Euro. Phys. Lett. 101, 17008 (2013

Influence of lattice distortion on the Curie temperature and spin-phonon coupling in LaMn0.5_{0.5}Co0.5_{0.5}O3_{3}

Two distinct ferromagnetic phases of LaMn$_{0.5}$Co$_{0.5}$O$_{3}$ having monoclinic structure with distinct physical properties have been studied. The ferromagnetic ordering temperature $\textit{T}_{c}$ is found to be different for both the phases. The origin of such contrasting characteristics is assigned to the changes in the distance(s) and angle(s) between Mn - O - Co resulting from distortions observed from neutron diffraction studies. Investigations on the temperature dependent Raman spectroscopy provide evidence for such structural characteristics, which affects the exchange interaction. The difference in B-site ordering which is evident from the neutron diffraction is also responsible for the difference in $\textit{T}_{c}$. Raman scattering suggests the presence of spin-phonon coupling for both the phases around the $\textit{T}_{c}$. Electrical transport properties of both the phases have been investigated based on the lattice distortion.Comment: 9 figure

Neutrino mixing matrices with relatively large θ13\theta_{13} and with texture one-zero

The recent T2K, MINOS and Double Chooz oscillation data hint a relatively large $\theta_{13}$, which can be accommodated by some general modification of the Tribimaximal/Bimaximal/Democratic mixing matrices. Using such matrices we analyze several Majorana mass matrices with texture one-zero and show whether they satisfy normal or inverted mass hierarchy and phenomenologically viable or not.Comment: 16 pages, 3 figures, minor modification in the text, version to appear in EPJ

Computer-augmented modeling studies of Pb(II) and Cd(II) complexes with maleic acid in ethylene glycol–water mixture

Chemical speciation of binary complexes of Pb(II) and Cd(II) ions with maleic acid have been studied pH metrically in the concentration range of 0–50% v/v ethylene glycol (EG)–water mixtures maintaining an ionic strength of 0.16 molL−1 at 303 K. Alkalimetric titrations were carried out in different relative concentrations of metal and maleic acid. Stability constants of various models of binary complexes were refined with MINIQUAD75. The best-fit chemical models were selected based on statistical parameters and residual analysis. The species detected are ML2, ML3, and ML2H for Pb(II) and Cd(II). The chemical speciation, metal bioavailability, and transportation are explained based on the distribution diagrams

Evaluation of different lactic acid bacterial strains for probiotic characteristics

Objective: The objective of the present study was to collect different Lactic acid bacterial strains from culture collection centers and screen their functional probiotic characteristics such as acid tolerance, bile tolerance, antibacterial activity and antibiotic sensitivity for their commercial use. Materials and Methods: Acid and bile tolerence of selected LAB(Lactic acid bacteria) was determined. The antibiotic resistance of Lactobacillus species was assessed using different antibiotic discs on de Mann Rogosa Sharpe broth (MRS) agar plates seeded with the test probiotic organism. The antibacterial activity of LAB was assessed by using well diffusion method.Results: Among the six probiotic strains tested, all showed good survivability at high bile salt concentration (0.3 to 2.0 % oxgall) and good growth at a low pH of 1.5 to 3.5. These probiotic species showed good survival abilities in acidic pH of 2.0 to 3.5 except Lactobacillus delbrueckii subspp. bulgaricus 281 which did not grown at pH of 2.0. Lactobacillus fermentum 141 was able to grow even at pH of 1.5 also. Among the six lactic acid species, Lactobacillus fermentum 141 (except Tetracycline), Lactobacillus delbrueckii subspp. Bulgaricus 281 except (Cefpodoxime) and all other LAB were resistant to all the antibiotics tested (Ampicillin, Nalidixic acid , Ciprofloxacin ,Co-Trimoxazole, Gentamicin and Cefpodoxime). All these probiotic organisms were screened for their in vitro inhibition ability against pathogenic microorganisms namely, E.coli ATCC (American type culture collection centre), Pseudomonas aeruginosa, Salmonella paratyphi, Staphylococcus aureus. Lactobacillus delbrueckii subspp. bulgaricus 281, Lactobacillus casei 297 and Lactobacillus fermentum 141 inhibited the growth of all the pathogenic bacteria used in the study. Conclusion: The study indicated Lactobacillus fermentum 141 and Lactobacillus casei 297 as potential functional probiotics for future in vivo studies for commercialization in the food industry

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Not AvailableMobile phone is most pervasive form of bidirectional communication in the hands of a small holding farmer and cell phones are recently being used for sending text / voice SMS, visual-based information in various sectors. Oil palm is an introduced crop in the country and Indian Council of Agriculture Research is reaching out to the oil palm farmers in the country on the technical know-how of the crop through Oil Palm Kisan Mobile Message Services (OPKiMMS). Content is being developed on different aspects of oil palm is disseminated to the registered oil palm farmers. This service aims at content delivery using text and voice SMS and vernacular interactive access for dissemination of information on oil palm. Initially, the mobile numbers of the oil palm growers of Andhra Pradesh are collected and messages are being sent. Further the programme is envisaged to be implemented in phase wise manner in all the potential states of oil palm in the country. This initiative forms a Mobile Information Platform that helps in intra and inter connectivity among and between the farmers and organizations involved in the Oil Palm Development Programme (OPDP) in the country.Not Availabl

Comparative Study of the Impact of Saline Water Irrigation on Tomato Yield, Quality and Growth in Andhra Pradesh, India

Tomato (Lycopersicon esculentum Mill.) belonging to the family Solanaceae, is one of the most important, popular, nutritious, and palatable vegetables grown in Andhra Pradesh. It plays a vital role in providing a remarkable quantity of vitamin-A and vitamin-C in human diet. Tomato is cultivated all over Andhra Pradesh due to its adaptability to wide range of soil and climate. Saline water resources are abundant in the most areas of India. Most of these resources still have not been effectively utilized. The present investigation was conducted on the effects of saline water irrigation on tomato yield, quality and growth at the Research Farm, Department of Agricultural Engineering, Aditya Engineering College, Surampalem, East Godavari district, Andhra Pradesh. Saline water differing in Electrical Conductivity (EC) 6ds/m and 4ds/m was supplied to the plant after the seedlings. The objective of this work is to compare the effect of tomato crop under drip irrigation by three different treatments. First treatment is of fresh water under drip irrigation. Second treatment is of Nacl+water with an EC of 6ds/m under controlled irrigation in the ratio 2.5:7.5. Third treatment is of Nacl+water with an EC of 4ds/m under controlled irrigation in the ratio 1.5:8.5 of the tomato variety Pusa F1 hybrid is used for the experiment. Growth of crop includes plant height, number of fruits, number of leaves, fruit length, fruit diameter and fruit weight. The healthy growth that is 69.4cm plant height, 26 leaves per plant, 34 fruits per plant, 7.8 cm fruit length, 5.4 cm diameter of fruit and 89.4 g of average fruit weight and maximum score (4.86 out of 5) in organoleptic test were obtained in (T-1) i. e. drip irrigation. Although salinized tomato fruits were smaller than non-salinized control fruits, they have increased soluble solids, high sugar content, which all are highly requested qualities by the processing tomato industry. Current research concludes that the fresh water irrigation T-1 recorded the high-water use efficiency and saline water irrigation treatments (T2&T3) having less water use efficiency may be due to the plants suffering with more soil moisture stress due to osmotic pressure build up by the saline water irrigation

RP-HPLC Determination of Raloxifene in Pharmaceuticl Tablets

A reverse phase HPLC method is developed for the determination of Raloxifene in pharmaceutical dosage forms. Chromatography was carried out on an inertsil C18 column using a mixture of acetonitrile and phosphate buffer (30:70 v/v) as the mobile phase at a flow rate of 1 mL/min. Detection was carried out at 290 nm .The retention time of the drug was 10.609 min. The method produced linear responses in the concentration range of 0.5-200 µg/mL of Raloxifene. The method was found to be applicable for determination of the drug in tablets