276 research outputs found
Theory and it ab initio calculation of radiative lifetime of excitons in semiconducting carbon nanotubes
We present theoretical analysis and first-principles calculation of the
radiative lifetime of excitons in semiconducting carbon nanotubes. An intrinsic
lifetime of the order of 10 ps is computed for the lowest optically active
bright excitons. The intrinsic lifetime is however a rapid increasing function
of the exciton momentum. Moreover, the electronic structure of the nanotubes
dictates the existence of dark excitons nearby in energy to each bright
exciton. Both effects strongly influence measured lifetime. Assuming a thermal
occupation of bright and dark exciton bands, we find an effective lifetime of
the order of 10 ns at room temperature, in good accord with recent experiments.Comment: 12 pages, 3 figure
Diameter and Chirality Dependence of Exciton Properties in Carbon Nanotubes
We calculate the diameter and chirality dependences of the binding energies,
sizes, and bright-dark splittings of excitons in semiconducting single-wall
carbon nanotubes (SWNTs). Using results and insights from {\it ab initio}
calculations, we employ a symmetry-based, variational method based on the
effective-mass and envelope-function approximations using tight-binding
wavefunctions. Binding energies and spatial extents show a leading dependence
with diameter as and , respectively, with chirality corrections
providing a spread of roughly 20% with a strong family behavior. Bright-dark
exciton splittings show a leading dependence. We provide analytical
expressions for the binding energies, sizes, and splittings that should be
useful to guide future experiments
Hamilton Sundstrand deaerator project
Includes bibliographical references.The deaerator is a mechanical device that is used to separate air from oil. The deaerator is a component of the Integrated Drive Generator (IDG). The Integrated Drive Generator is used in aircrafts as the main power generator. Oil is used in the IDG as a lubricant and coolant. Air is trapped in the oil due to high suction forces of the oil pumps. The entrained air adversely affects the lubricative and thermal properties of oil. Centrifugal forces inside the deaerator are used to remove this entrained air from the oil. Hamilton Sundstrand has several different deaerator models, but has been unable to evaluate the efficiency of oil separation for different designs. Our goal is to evaluate the efficiency of two deaerator models. The evaluation will be based on experimental and theoretical data. The experimental data will be collected using an actual deaerator setup. The theoretical data will be collected using computational fluid dynamic (CFD) software models. ANSYS CFX software will be used for CFD models. The experimental results will then be compared to the theoretical results. An analysis of both results will lead to a better understanding of flow separation.B.S. (Bachelor of Science
Excitonic Effects and Optical Spectra of Single-Walled Carbon Nanotubes
Many-electron effects often dramatically modify the properties of reduced
dimensional systems. We report calculations, based on an many-electron Green's
function approach, of electron-hole interaction effects on the optical spectra
of small-diameter single-walled carbon nanotubes. Excitonic effects
qualitatively alter the optical spectra of both semiconducting and metallic
tubes. Excitons are bound by ~ 1 eV in the semiconducting (8,0) tube and by ~
100 meV in the metallic (3,3) tube. These large many-electron effects explain
the discrepancies between previous theories and experiments.Comment: 6 pages, 3 figures, 2 table
Selection Rules for One- and Two-Photon Absorption by Excitons in Carbon Nanotubes
Recent optical absorption/emission experiments showed that the lower energy
optical transitions in carbon nanotubes are excitonic in nature, as predicted
by theory. These experiments were based on the symmetry aspects of free
electron-hole states and bound excitonic states. The present work shows,
however, that group theory does not predict the selection rules needed to
explain the two photon experiments. We obtain the symmetries and selection
rules for the optical transitions of excitons in single-wall carbon nanotubes
within the approach of the group of the wavevector, thus providing important
information for the interpretation of theoretical and experimental optical
spectra of these materials.Comment: 4 pages, 1 figure, 1 tabl
Data Analytics Techniques for Performance Prediction of Steamflooding in Naturally Fractured Carbonate Reservoirs
Thermal oil recovery techniques, including steam processes, account for more than 80%
of the current global heavy oil, extra heavy oil, and bitumen production. Evaluation of Naturally Fractured Carbonate Reservoirs (NFCRs) for thermal heavy oil recovery using field pilot tests and exhaustive numerical and analytical modeling is expensive, complex, and personnel-intensive. Robust statistical models have not yet been proposed to predict cumulative steam to oil ratio (CSOR) and
recovery factor (RF) during steamflooding in NFCRs as strong process performance indicators. In this paper, new statistical based techniques were developed using multivariable regression analysis for quick estimation of CSOR and RF in NFCRs subjected to steamflooding. The proposed data based models include vital parameters such as in situ fluid and reservoir properties. The data used are taken from experimental studies and rare field trials of vertical well steamflooding pilots in heavy oil NFCRs reported in the literature. The models show an average error of <6% for the worst cases
and contain fewer empirical constants compared with existing correlations developed originally for oil sands. The interactions between the parameters were considered indicating that the initial oil saturation and oil viscosity are the most important predictive factors. The proposed models were successfully predicted CSOR and RF for two heavy oil NFCRs. Results of this study can be used for feasibility assessment of steam flooding in NFCRs..
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