Photocatalytic degradation of metoprolol tartrate in suspensions of two TiO2-based photocatalysts with different surface area. Identification of intermediates and proposal of degradation pathways.

This study investigates the efficiency of the photocatalytic degradation of metoprolol tartrate (MET), a widely used β 1-blocker, in TiO 2 suspensions of Wackherr's " Oxyde de titane standard" and Degussa P25. The study encompasses transformation kinetics and efficiency, identification of intermediates and reaction pathways. In the investigated range of initial concentrations (0.01-0.1mM), the photocatalytic degradation of MET in the first stage of the reaction followed approximately a pseudo-first order kinetics. The TiO 2 Wackherr induced a significantly faster MET degradation compared to TiO 2 Degussa P25 when relatively high substrate concentrations were used. By examining the effect of ethanol as a scavenger of hydroxyl radicals (OH), it was shown that the reaction with OH played the main role in the photocatalytic degradation of MET. After 240min of irradiation the reaction intermediates were almost completely mineralized to CO 2 and H 2O, while the nitrogen was predominantly present as NH4+. Reaction intermediates were studied in detail and a number of them were identified using LC-MS/MS (ESI+), which allowed the proposal of a tentative pathway for the photocatalytic transformation of MET as a function of the TiO 2 specimen

Elastic properties, thermal stability, and thermodynamic parameters of MoAlB

MoAlB is the first and, so far, the only transition-metal boride that forms alumina when heated in air and is thus potentially useful for high-temperature applications. Herein, the thermal stability in argon and vacuum atmospheres and the thermodynamic parameters of bulk polycrystalline MoAlB were investigated experimentally. At temperatures above 1708 K, in vacuum and inert atmospheres, this compound incongruently melts into the binary MoB and liquid aluminum metal as confirmed by differential thermal analysis, quenching experiments, x-ray diffraction, and scanning electron microscopy. Making use of that information together with heat-capacity measurements in the 4–1000-K temperature range—successfully modeled as the sum of lattice, electronic, and dilation contributions—the standard enthalpy, entropy, and free energy of formation are computed and reported for the full temperature range. The standard enthalpy of formation of MoAlB at 298 K was found to be −132±3.2 kJ/mol. Lastly, the thermal conductivity values are computed and modeled using a variation of the Slack model in the 300–1600-K temperature range

Bulk electronic structure of superconducting LaRu2P2 single crystals measured by soft x-ray angle-resolved photoemission spectroscopy

We present a soft X-ray angle-resolved photoemission spectroscopy (SX-ARPES) study of the stoichiometric pnictide superconductor LaRu2P2. The observed electronic structure is in good agreement with density functional theory (DFT) calculations. However, it is significantly different from its counterpart in high-temperature superconducting Fe-pnictides. In particular the bandwidth renormalization present in the Fe-pnictides (~2 - 3) is negligible in LaRu2P2 even though the mass enhancement is similar in both systems. Our results suggest that the superconductivity in LaRu2P2 has a different origin with respect to the iron pnictides. Finally we demonstrate that the increased probing depth of SX-ARPES, compared to the widely used ultraviolet ARPES, is essential in determining the bulk electronic structure in the experiment.Comment: 4 pages, 4 figures, 1 supplemental material. Accepted for publication in Physical Review Letter

Cryptoferromagnetic state in superconductor-ferromagnet multilayers

We study a possibility of a non-homogeneous magnetic order (cryptoferromagnetic state) in heterostructures consisting of a bulk superconductor and a ferromagnetic thin layer that can be due to the influence of the superconductor. The exchange field in the ferromagnet may be strong and exceed the inverse mean free time. A new approach based on solving the Eilenberger equations in the ferromagnet and the Usadel equations in the superconductor is developed. We derive a phase diagram between the cryptoferromagnetic and ferromagnetic states and discuss the possibility of an experimental observation of the CF state in different materials.Comment: 4 pages, 1 figur

Litters Health Status and Growth Parameters in the Sows Feeding Diets Supplemented with Probiotic Actisaf Sc 47® within Pregnancy Or Lactation

The aim of this study was to investigate the effect of supplementing standard diets for pregnant and lactating sows with live yeast culture (Saccharomyces cerevisiae) on their health status, as well as the health status and growth parameters of their litters during lactation. A total of 120 sows were divided into three groups: the first group was fed diets supplemented with probiotics during pregnancy (G+P, n=40), the second group was fed these diets during lactation (L+P, n=40), and the third group was the control group which was not fed diets supplemented with probiotics (C, n = 40). During the lactation period, a significantly (p<0.01) smaller proportion of probiotic treated sows (G+P=7.5%, L+P=12.5%) manifested clinical signs of the uterus and/or the udder disease in comparison with the control sows (22.5%). The incidence of infectious diarrhea in the nursing piglets was significantly (p<0.05) lower in the treated sows (12.5%) compared to the control sows (27.5 %). The average number of weaned piglets per litter (p/l) and average litter weight at weaning (lw) (G+P=11.6 p/l and 103.6 kg lw, L+P=11.1 p/l and 102.8 kg lw, C=10 p/l and 79 kg lw) were significantly higher (p<0.01 or p<0.05) in sows treated with probiotic compared to the control sows. These results clearly show that the use of probiotic significantly improves the health status of sows and nursing piglets, as well as the piglets growth parameters

The Effect of Partial Root Drying on Antioxidant Activity in Different Agricultural Crops

Partial root drying (PRD) is a new irrigation strategy which applies alternating regimes of irrigation to half the root system while the other half dries out. Many published results showed that PRD may save water without significant effect on yield. The aim of this work was to compare the effects of PRD with full irrigation (FI) on yield and antioxidant activity in grape berry, potato tuber and tomato fruit. in both experimental conditions (field and polytunnel), the soil water content in FI treatment was kept close to field capacity, although in PRD treatment, 70o/o of the irrigation water in FI was uppti"a to one half of the root system, and irrigation was shifted according to soil water content decrease in the dry side of the root zone. At the end of the vegetation season, analyses of total yield of fruit and tubers and their quality were carried out. Antioxidant activity of tomato fruit ethanolic extract was evaluated against 2,2'-azinobis (3-eyhylbenzothiazoline-6-sulfonic acid) radical cation (ABTS'*) and expressed as Trolox (6-hydroxy-2,5,7,8-tetramethylchtoman-2- carboxylic acid) equivalent antioxidant capacity (TEAC)' In general, treatment differences in yield were not significant for either crop although WUE and anti,oxidant activity in the PRD treatments were higher than in the FI treatment for investigated crops. These results for all PRD-treated crops showed that PRD could be a useful strategy to save irrigation water without significantly sacrificing either the quantity or quality of yield

Trivial topological phase of CaAgP and the topological nodal-line transition in CaAg(P1-xAsx)

By performing angle-resolved photoemission spectroscopy and first-principles calculations, we address the topological phase of CaAgP and investigate the topological phase transition in CaAg(P1-xAsx). We reveal that in CaAgP, the bulk band gap and surface states with a large bandwidth are topologically trivial, in agreement with hybrid density functional theory calculations. The calculations also indicate that application of "negative" hydrostatic pressure can transform trivial semiconducting CaAgP into an ideal topological nodal-line semimetal phase. The topological transition can be realized by partial isovalent P/As substitution at x = 0.38.Comment: 20 pages, 4 figure

Local density of states in superconductor-strong ferromagnet structures

We study the dependence of the local density of states (LDOS) on coordinates for a superconductor-ferromagnet (S/F) bilayer and a S/F/S structure assuming that the exchange energy h in the ferromagnet is sufficiently large: $>>1,$ where $\tau$ is the elastic relaxation time. This limit cannot be described by the Usadel equation and we solve the more general Eilenberger equation. We demonstrate that, in the main approximation in the parameter $(h\tau)^{-1}$, the proximity effect does not lead to a modification of the LDOS in the S/F system and a non-trivial dependence on coordinates shows up in next orders in $(h\tau) ^{-1}.$ In the S/F/S sandwich the correction to the LDOS is nonzero in the main approximation and depends on the phase difference between the superconductors. We also calculate the superconducting critical temperature $T_{c}$ for the bilayered system and show that it does not depend on the exchange energy of the ferromagnet in the limit of large h and a thick F layer.Comment: 9 pages, 5 figure

Josephson current in superconductor-ferromagnet structures with a nonhomogeneous magnetization

We calculate the dc Josephson current $I_J$ for two types of superconductor-ferromagnet (S/F) Josephson junctions. The junction of the first type is a S/F/S junction. On the basis of the Eilenberger equation, the Josephson current is calculated for an arbitrary impurity concentration. If $h\tau\ll1$ the expression for the Josephson critical current $I_c$ is reduced to that which can be obtained from the Usadel equation ($h$ is the exchange energy, $\tau$ is the momentum relaxation time). In the opposite limit $h\tau\gg1$ the superconducting condensate oscillates with period $$ and penetrates into the F region over distances of the order of the mean free path $l$. For this kind of junctions we also calculate $I_J$ in the case when the F layer presents a nonhomogeneous (spiral) magnetic structure with the period $2\pi /Q$. It is shown that for not too low temperatures, the $\pi$-state which occurs in the case of a homogeneous magnetization (Q=0) may disappear even at small values of $Q$. In this nonhomogeneous case, the superconducting condensate has a nonzero triplet component and can penetrate into the F layer over a long distance of the order of $\xi_{T}=$. The junction of the second type consists of two S/F bilayers separated by a thin insulating film. It is shown that the critical Josephson current $I_{c}$ depends on the relative orientation of the effective exchange field $h$ of the bilayers. In the case of an antiparallel orientation, $I_{c}$ increases with increasing $h$. We establish also that in the F film deposited on a superconductor, the Meissner current created by the internal magnetic field may be both diamagnetic or paramagnetic.Comment: 13 pages, 11 figures. To be published in Phys. Rev.