47,959 research outputs found
Mössbauer Spectrometry Study of Thermally-Activated Electronic Processes in Li_xFePO_4
The solid solution phase of Li_xFePO_4 with different Li concentrations, x, was investigated by Mössbauer spectrometry at temperatures between 25 and 210 °C. The Mössbauer spectra show a temperature dependence of their isomer shifts (E_(IS)) and electric quadrupole splittings (E_Q), typical of thermally activated, electronic relaxation processes involving ^(57)Fe ions. The activation energies for the fluctuations of E_Q and E_(IS) for Fe^(3+) are nearly the same, 570 ± 9 meV, suggesting that both originate from charge hopping. For the Fe^(2+) components of the spectra, the fluctuations of E_Q occurred at lower temperatures than the fluctuations of E_(IS), with an activation energy of 512 ± 12 meV for E_Q and one of 551 ± 7 meV for E_(IS). The more facile fluctuations of E_Q for Fe^(2+) are evidence for local motions of neighboring Li^+ ions. It appears that the electron hopping frequency is lower than that of Li^+ ions. The activation energies of relaxation did not have a measurable dependence on the concentration of lithium, x
An integrated wind risk warning model for urban rail transport in Shanghai, China
The integrated wind risk warning model for rail transport presented has four elements:
Background wind data, a wind field model, a vulnerability model, and a risk model. Background
wind data uses observations in this study. Using the wind field model with effective surface
roughness lengths, the background wind data are interpolated to a 30-m resolution grid. In the
vulnerability model, the aerodynamic characteristics of railway vehicles are analyzed with CFD
(Computational Fluid Dynamics) modelling. In the risk model, the maximum value of three
aerodynamic forces is used as the criteria to evaluate rail safety and to quantify the risk level under
extremely windy weather. The full model is tested for the Shanghai Metro Line 16 using wind
conditions during Typhoon Chan-hom. The proposed approach enables quick quantification of real-
time safety risk levels during typhoon landfall, providing sophisticated warning information for
rail vehicle operation safety
Quantum Transport in Molecular Rings and Chains
We study charge transport driven by deformations in molecular rings and
chains. Level crossings and the associated Longuet-Higgins phase play a central
role in this theory. In molecular rings a vanishing cycle of shears pinching a
gap closure leads, generically, to diverging charge transport around the ring.
We call such behavior homeopathic. In an infinite chain such a cycle leads to
integral charge transport which is independent of the strength of deformation.
In the Jahn-Teller model of a planar molecular ring there is a distinguished
cycle in the space of uniform shears which keeps the molecule in its manifold
of ground states and pinches level crossing. The charge transport in this cycle
gives information on the derivative of the hopping amplitudes.Comment: Final version. 26 pages, 8 fig
Soliton self-modulation of the turbulence amplitude and plasma rotation
The space-uniform amplitude envelope of the Ion Temperature Gradient driven
turbulence is unstable to small perturbations and evolves to nonuniform,
soliton-like modulated profiles. The induced poloidal asymmetry of the
transport fluxes can generate spontaneous poloidal spin-up of the tokamak
plasma.Comment: Latex file, 66 pages, 24 postscript figures included. New section on
rotation five new figures, comparison with magnetic pumping dampin
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