Iron porphyrin molecules on Cu(001): Influence of adlayers and ligands on the magnetic properties

The structural and magnetic properties of Fe octaethylporphyrin (OEP) molecules on Cu(001) have been investigated by means of density functional theory (DFT) methods and X-ray absorption spectroscopy. The molecules have been adsorbed on the bare metal surface and on an oxygen-covered surface, which shows a $\sqrt{2}\times2\sqrt{2}R45^{\circ}$ reconstruction. In order to allow for a direct comparison between magnetic moments obtained from sum-rule analysis and DFT we calculate the dipolar term $7$, which is also important in view of the magnetic anisotropy of the molecule. The measured X-ray magnetic circular dichroism shows a strong dependence on the photon incidence angle, which we could relate to a huge value of $7$, e.g. on Cu(001) $7$ amounts to -2.07\,\mbo{} for normal incidence leading to a reduction of the effective spin moment $m_s + 7$. Calculations have also been performed to study the influence of possible ligands such as Cl and O atoms on the magnetic properties of the molecule and the interaction between molecule and surface, because the experimental spectra display a clear dependence on the ligand, which is used to stabilize the molecule in the gas phase. Both types of ligands weaken the hybridization between surface and porphyrin molecule and change the magnetic spin state of the molecule, but the changes in the X-ray absorption are clearly related to residual Cl ligands.Comment: 17 figures, full articl

Adatoms and clusters of 3d transition metals on graphene: Electronic and magnetic configurations

We investigate the electronic and magnetic properties of single Fe, Co, and Ni atoms and clusters on monolayer graphene (MLG) on SiC(0001) by means of scanning tunneling microscopy (STM), x-ray absorption spectroscopy, x-ray magnetic circular dichroism (XMCD), and ab initio calculations. STM reveals different adsorption sites for Ni and Co adatoms. XMCD proves Fe and Co adatoms to be paramagnetic and to exhibit an out-of-plane easy axis in agreement with theory. In contrast, we experimentally find a nonmagnetic ground state for Ni monomers while an increasing cluster size leads to sizeable magnetic moments. These observations are well reproduced by our calculations and reveal the importance of hybridization effects and intra-atomic charge transfer for the properties of adatoms and clusters on MLG.Comment: 8 pages (supplementary included), 4 figures, (supplementary included

Exploring the limits of soft x-ray magnetic holography: Imaging magnetization reversal of buried interfaces (invited)

The following article appeared in Journal of Applied Physics 109.7 (2011): 07D357 and may be found at http://scitation.aip.org/content/aip/journal/jap/109/7/10.1063/1.3567035Only a very few experimental techniques can address the microscopic magnetization reversal behavior of the different magnetic layers in a multilayered system with element selectivity. We present an element-selective study of ferromagnetic (FM) [Co/Pt]n multilayers with perpendicular anisotropy exchange-coupled to antiferromagnetic (AFM) FeMn and IrMn films performed with a new experimental set-up developed for both soft x-ray spectroscopy and holography imaging purposes. The spectroscopy analysis allows the quantification of the unpinned (pinned) uncompensated AFM moments, providing direct evidence of its parallel (antiparallel) alignment with respect to the FM moments. The holography experiments give a direct view of both FM and uncompensated AFM magnetic structures, showing that they replicate to each other during magnetization reversal. Remarkably, we show magnetic images for effective thicknesses as small as one monolayer. Our results provide new microscopic insights into the exchange coupling phenomena and explore the sensitivity limits of these techniques. Future trends are also discussed.We acknowledge technical support by the ESRF staff R. Barrett, R. Homs-Regojo, T. Trenit, and G. Retout. A. B. acknowledges support through a Ramo´n y Cajal contract from the Spanish MICINN. This work was supported in part by the Spanish MICINN through Projects CSD2007-00010, and MAT2010-21822 and by Comunidad de Madrid through Project S2009/MAT-1726.Comunidad de Madrid. S2009/MAT-1726/NANOBIOMAGNE

Extracting depth information of 3 dimensional structures from a single view X ray Fourier transform hologram

We demonstrate how information about the three dimensional structure of an object can be extracted from a single Fourier transform X ray hologram. In contrast to lens based 3D imaging approaches that provide depth information of a specimen utilizing several images from different angles or via adjusting the focus to different depths, our method capitalizes on the use of the holographically encoded phase and amplitude information of the object amp; x2019;s wavefield. It enables single shot measurements of 3D objects at coherent X ray sources. As the ratio of longitudinal resolution over transverse resolution scales proportional to the diameter of the reference beam aperture over the X ray wavelength, we expect the approach to be particularly useful in the extreme ultraviolet and soft X ray regim

Imaging and quantifying perpendicular exchange biased systems by soft x-ray holography and spectroscopy

International audienc

Skyrmions in perpendicular magnetic anisotropy dots Imaging and simulations

We present the results of soft X ray holography imaging of sub micrometer disc shaped dots with perpendicular magnetic anisotropy. For particular geometries such dots can sustain magnetic bubbles that have been predicted to exhibit rich spin dynamical behaviour. By applying suitable in situ magnetic fields to the system we can manipulate the magnetic configuration of the system and create the desired bubble like state. This is a pre requisite for imaging of the bubble s dynamical response as well as for pump and probe imaging of their dynamic