High-temperature Hydrogen Chloride Releases from Mixtures of Sodium Chloride with Sulfates: Implications for the Chlorine-Mineralogy as Determined by the Sample Analysis at Mars Instrument on the Curiosity Rover in Gale Crater, Mars

Hydrogen chloride releases above 500 C occurred in several samples analyzed by the Sample Analysis at Mars (SAM) evolved gas analyzer on the Curiosity rover in Gale crater. These have been attributed to reactions between chlorides (original or from oxychlorine decomposition) and water. Some of these HCl releases that peaked below the melting temperature of common chlorides did not co-evolve with oxygen or water, and were not explained by laboratory analog work (Figure 1). Therefore, these HCl releases were not caused by MgCl2 or soley due to reactions between water and melting chlorides. The goal of this work was to explain the HCl releases that did not co-evolve with oxygen or water and occurred below the melting point of common chlorides, which have not been explained by previous laboratory analog work. This work specifically evaluates the role of evolved SO2 in the production of HCl

Research to improve the design of driven pile foundations in chalk: the ALPACA project

Large numbers of offshore wind turbines, near-shore bridges and port facilities are supported by driven piles. The design and installation of such piles is often problematic in Chalk, a low-density, porous, weak carbonate rock, which is present under large areas of NW Europe. There is little guidance available to designers on driveability, axial capacity, the lateral pile resistance which dominates offshore wind turbine monopile behaviour, or on how piles can sustain axial or lateral cyclic loading. This paper describes the ALPACA project which involves comprehensive field testing at a low-to-medium density chalk research test site. The project is developing new design guidance through comprehensive field testing and analysis combined with in-situ testing campaigns and advanced static-and-cyclic laboratory testing on high quality block and rotary core samples

HLA-A, -B, -C, -DRB1, DRB3, DRB4, DRB5 and DQB1 polymorphism detected by PCR-SSP in a semi-urban HIV-positive Ugandan population.

PCR-SSP was used to HLA-type a cohort of Ugandan HIV-positive individuals. The results represent a more comprehensive description of HLA in an African population than previously described and are in concordance with data from a general Black population. Substantial differences exist between this population and Caucasoid populations in which immunological responses to HIV have been investigated; this emphasises that the main HLA-restrictive elements for HIV-specific cytotoxic T lymphocytes will most likely be different for each population

Optimisation of impact pile driving using optical fibre Bragg grating measurements

This paper reports the use of optical Fibre Bragg Grating (FBG) sensors to monitor the stress waves generated below ground during pile driving, combined with measurements using conventional pile driving analyzer (PDA) sensors mounted at the pile head. Fourteen tubular steel piles with a diameter of 508 mm and embedded length to diameter ratios of 6 to 20 were impact driven at an established chalk test site in Kent, UK. The pile shafts were instrumented with multiple FBG strain gauges and pile head PDA sensors, which monitored the piles’ responses under each hammer blow. A high frequency (5kHz) fibre optic interrogator allowed a previously unseen resolution of the stress wave propagation along the pile. Estimates of the base soil resistances to driving and distributions of shaft shear resistances were found through signal matching that compared time series of pile head PDA measurements and FBG strains measured below ground surface. Numerical solutions of the onedimensional wave equation were optimised by taking account of the data from multiple FBG gauges, leading to significant advantages that have potential for widespread application in cases where high resolution strain measurements are made

Compositional Explanation of Types and Algorithmic Debugging of Type Errors

The type systems of most typed functional programming languages are based on the Hindley-Milner type system. A practical problem with these type systems is that it is often hard to understand why a program is not type correct or a function does not have the intended type. We suggest that at the core of this problem is the difficulty of explaining why a given expression has a certain type. The type system is not defined compositionally. We propose to explain types using a variant of the Hindley-Milner type system that defines a compositional type explanation graph of principal typings. We describe how the programmer understands types by interactive navigation through the explanation graph. Furthermore, the explanation graph can be the foundation for algorithmic debugging of type errors, that is, semi-automatic localisation of the source of a type error without even having to understand the type inference steps. We implemented a prototype of a tool to explore the usefulness of the proposed methods

Social effects of territorial neighbours on the timing of spring breeding in North American red squirrels

This is the author accepted manuscript. The final version is available from Wiley via the DOI in this recordOrganisms can affect one another’s phenotypes when they socially interact. Indirect genetic effects occur when an individual’s phenotype is affected by genes expressed in another individual. These heritable effects can enhance or reduce adaptive potential, thereby accelerating or reversing evolutionary change. Quantifying these social effects is therefore crucial for our understanding of evolution, yet estimates of indirect genetic effects in wild animals are limited to dyadic interactions. We estimated indirect phenotypic and genetic effects, and their covariance with direct effects, for the date of spring breeding in North American red squirrels (Tamiasciurus hudsonicus) living in an array of territories of varying spatial proximity. Additionally, we estimated indirect effects and the strength of selection at low and high population densities. Social effects of neighbours on the date of spring breeding were different from zero at high population densities but not at low population densities. Indirect phenotypic effects accounted for a larger amount of variation in the date of breeding than differences attributable to the among-individual variance, suggesting social interactions are important for determining breeding dates. The genetic component to these indirect effects was however not statistically significant. We therefore showcase a powerful and flexible method that will allow researchers working in organisms with a range of social systems to estimate indirect phenotypic and genetic effects, and demonstrate the degree to which social interactions can influence phenotypes, even in a solitary species

Axial cyclic loading of piles in low to medium density chalk

Comprehensive field investigations into the axial cyclic loading behaviour of open-steel pipe piles driven and aged in low-to-medium density chalk identify the conditions under which behaviour is stable, unstable or metastable. Post-cycling monotonic tests confirmed that stable cycling enhanced pile capacity marginally, while unstable cases suffered potentially large losses of shaft capacity. Metastable conditions led to intermediate outcomes. The patterns by which axial deflections grew under cyclic loading varied systematically with the normalised loading parameters and could be captured by simple fitting expressions. Cyclic stiffnesses also varied with loading conditions, with the highest operational shear stiffnesses falling far below the in-situ seismic test values. The monotonic and cyclic axial responses of the test piles were controlled by the behaviour of, and conditions within, the reconsolidated, de-structured, chalk putty annuli formed around pile shafts during driving. Fibre-optic strain gauges identified progressive failure from the pile tip upwards. Large factors of safety were required for piles to survive repetitive loading under high-level, two-way, conditions involving low mean loads, while low amplitude one-way cycling had little impact. A simple ‘global’ prediction procedure employing interface shear and cyclic triaxial tests is shown to provide broadly representative predictions for field behaviour