Finite-size effects in amorphous Fe90Zr10/Al75Zr25 multilayers

The thickness dependence of the magnetic properties of amorphous Fe90Zr10 layers has been explored using Fe90Zr10/Al75Zr25 multilayers. The Al75Zr25 layer thickness is kept at 40 \AA, while the thickness of the Fe90Zr10 layers is varied between 5 and 20 \AA. The thickness of the Al75Zr25 layers is sufficiently large to suppress any significant interlayer coupling. Both the Curie temperature and the spontaneous magnetization decrease non-linearly with decreasing thickness of the Fe90Zr10 layers. No ferromagnetic order is observed in the multilayer with 5 {\AA} Fe90Zr10 layers. The variation of the Curie temperature $T_c$ with the Fe90Zr10 layer thickness $t$ is fitted with a finite-size scaling formula [1-\Tc(t)/\Tc(\infty)]=[(t-t')/t_0]^{-\lambda}, yielding $\lambda=1.2$, and a critical thickness $t'=6.5$ \AA, below which the Curie temperature is zero.Comment: 8 pages, 8 figure

Thermal Conversion of Guanylurea Dicyanamide into Graphitic Carbon Nitride via Prototype CNx Precursors

Guanylurea dicyanamide, [(H2N)C(-O)NHC(NH2)2][N(CN)2], has been synthesized by ion exchange reaction in aqueous solution and structurally characterized by single-crystal X-ray diffraction (C2/c, a = 2249.0(5) pm, b = 483.9(1) pm, c = 1382.4(3) pm, β = 99.49(3)°, V = 1483.8(5) × 106 pm3, T = 130 K). The thermal behavior of the molecular salt has been studied by thermal analysis, temperature-programmed X-ray powder diffraction, FTIR spectroscopy, and mass spectrometry between room temperature and 823 K. The results were interpreted on a molecular level in terms of a sequence of thermally induced addition, cyclization, and elimination reactions. As a consequence, melamine (2,4,6-triamino-1,3,5-triazine) is formed with concomitant loss of HNCO. Further condensation of melamine yields the prototypic CNx precursor melem (2,6,10-triamino-s-heptazine, C6N7(NH2)3), which alongside varying amounts of directly formed CNxHy material transforms into layered CNxHy phases without significant integration of oxygen into the core framework owing to the evaporation of HNCO. Thus, further evidence can be added to melamine and its condensation product melem acting as “key intermediates” in the synthetic pathway toward graphitic CNxHy materials, whose exact constitution is still a point at issue. Due to the characteristic formation process and hydrogen content a close relationship with the polymer melon is evident. In particular, the thermal transformation of guanylurea dicyanamide clearly demonstrates that the formation of volatile compounds such as HNCO during thermal decomposition may render a large variety of previously not considered molecular compounds suitable CNx precursors despite the presence of oxygen in the starting material

Progress in the understanding and modelling of components that could drive the overall fragility of a nuclear power plant

International audienc

Simulator for Microlens Planet Surveys

We summarize the status of a computer simulator for microlens planet surveys. The simulator generates synthetic light curves of microlensing events observed with specified networks of telescopes over specified periods of time. Particular attention is paid to models for sky brightness and seeing, calibrated by fitting to data from the OGLE survey and RoboNet observations in 2011. Time intervals during which events are observable are identified by accounting for positions of the Sun and the Moon, and other restrictions on telescope pointing. Simulated observations are then generated for an algorithm that adjusts target priorities in real time with the aim of maximizing planet detection zone area summed over all the available events. The exoplanet detection capability of observations was compared for several telescopes.Comment: Proc. IAU Symp. No. 293 "Formation, detection, and characterization of extrasolar habitable planets", ed. by N. Haghighipour. 4 pages, in pres

Field-Scale Soil Property Changes under Switchgrass Managed for Bioenergy

The capacity of perennial grasses to affect change in soil properties is well documented but information on switchgrass (Panicum virgatum L.) managed for bioenergy is limited. An on-farm study (10 fields) in North Dakota, South Dakota, and Nebraska was sampled before switchgrass establishment and after 5 years to determine changes in soil bulk density (SBD), pH, soil phosphorus (P), and equivalent mass soil organic carbon (SOC). Changes in SBD were largely constrained to near-surface depths (0–0.05 m). SBD increased (0–0.05 m) at the Nebraska locations (mean=0.16 Mgm-3), while most South Dakota and North Dakota locations showed declines in SBD (mean=-0.18 Mgm-3; range=-0.42–0.07 Mgm-3). Soil pH change was significant at five of the 10 locations at near surface depths (0–0.05 m), but absolute changes were modest (range=-0.67–0.44 pH units). Available P declined at all sites where it was measured (North Dakota and South Dakota locations). When summed across the surface 0.3 m depth, annual decreases in available P averaged 1.5 kg P ha-1 yr-1 (range=0.5–2.8 kg P ha-1 yr-1). Averaged across locations, equivalent mass SOC increased by 0.5 and 2.4 Mg Cha-1 yr-1 for the 2500 and 10 000 Mg ha-1 soil masses, respectively. Results from this study underscore the contribution of switchgrass to affect soil property changes, though considerable variation in soil properties exists within and across locations

Soil Carbon Storage by Switchgrass Grown for Bioenergy

Life-cycle assessments (LCAs) of switchgrass (Panicum virgatum L.) grown for bioenergy production require data on soil organic carbon (SOC) change and harvested C yields to accurately estimate net greenhouse gas (GHG) emissions. To date, nearly all information on SOC change under switchgrass has been based on modeled assumptions or small plot research, both of which do not take into account spatial variability within or across sites for an agro-ecoregion. To address this need, we measured change in SOC and harvested C yield for switchgrass fields on ten farms in the central and northern Great Plains, USA (930 km latitudinal range). Change in SOC was determined by collecting multiple soil samples in transects across the fields prior to planting switchgrass and again 5 years later after switchgrass had been grown and managed as a bioenergy crop. Harvested aboveground C averaged 2.5± 0.7 Mg C ha−1 over the 5 year study. Across sites, SOC increased significantly at 0–30 cm (P=0.03) and 0–120 cm (P=0.07), with accrual rates of 1.1 and 2.9 Mg C ha−1 year−1 (4.0 and 10.6 Mg CO2 ha−1 year−1), respectively. Change in SOC across sites varied considerably, however, ranging from −0.6 to 4.3 Mg C ha−1 year−1 for the 0–30 cm depth. Such variation in SOC change must be taken into consideration in LCAs. Net GHG emissions from bioenergy crops vary in space and time. Such variation, coupled with an increased reliance on agriculture for energy production, underscores the need for long-term environmental monitoring sites in major agro-ecoregions

Management strategies/practices for increasing storage of organic C and N in soil in cropping systems in the Northern Great Plains of North America

Non-Peer Reviewe

Ultralight magnetic aerogels from Janus emulsions

Magnetite containing aerogels were synthesized by freeze drying olive oil silicone oil based Janus emulsion gels containing gelatin and sodium carboxymethylcellulose NaCMC . The magnetite nanoparticles dispersed in olive oil are processed into the gel and remain in the macroporous aerogel after removing the oil components. The coexistence of macropores from the Janus droplets and mesopores from freeze drying of the hydrogels in combination with the magnetic properties offer a special hierarchical pore structure, which is of relevance for smart supercapacitors, biosensors, and spilled oil sorption and separation. The morphology of the final structure was investigated in dependence on initial compositions. More hydrophobic aerogels with magnetic responsiveness were synthesized by bisacrylamide crosslinking of the hydrogel. The crosslinked aerogels can be successfully used in magnetically responsive clean up experiments of the cationic dye methylene blue