2,037 research outputs found
A Thermodynamically-Consistent Non-Ideal Stochastic Hard-Sphere Fluid
A grid-free variant of the Direct Simulation Monte Carlo (DSMC) method is
proposed, named the Isotropic DSMC (I-DSMC) method, that is suitable for
simulating dense fluid flows at molecular scales. The I-DSMC algorithm
eliminates all grid artifacts from the traditional DSMC algorithm; it is
Galilean invariant and microscopically isotropic. The stochastic collision
rules in I-DSMC are modified to yield a non-ideal structure factor that gives
consistent compressibility, as first proposed in [Phys. Rev. Lett. 101:075902
(2008)]. The resulting Stochastic Hard Sphere Dynamics (SHSD) fluid is
empirically shown to be thermodynamically identical to a deterministic
Hamiltonian system of penetrable spheres interacting with a linear core pair
potential, well-described by the hypernetted chain (HNC) approximation. We
apply a stochastic Enskog kinetic theory for the SHSD fluid to obtain estimates
for the transport coefficients that are in excellent agreement with particle
simulations over a wide range of densities and collision rates. The fluctuating
hydrodynamic behavior of the SHSD fluid is verified by comparing its dynamic
structure factor against theory based on the Landau-Lifshitz Navier-Stokes
equations. We also study the Brownian motion of a nano-particle suspended in an
SHSD fluid and find a long-time power-law tail in its velocity autocorrelation
function consistent with hydrodynamic theory and molecular dynamics
calculations.Comment: 30 pages, revision adding some clarifications and a new figure. See
also arXiv:0803.035
Phase transition in inelastic disks
This letter investigates the molecular dynamics of inelastic disks without
external forcing. By introducing a new observation frame with a rescaled time,
we observe the virtual steady states converted from asymptotic energy
dissipation processes. System behavior in the thermodynamic limit is carefully
investigated. It is found that a phase transition with symmetry breaking occurs
when the magnitude of dissipation is greater than a critical value.Comment: 9 pages, 6 figure
Stacking Entropy of Hard Sphere Crystals
Classical hard spheres crystallize at equilibrium at high enough density.
Crystals made up of stackings of 2-dimensional hexagonal close-packed layers
(e.g. fcc, hcp, etc.) differ in entropy by only about per sphere
(all configurations are degenerate in energy). To readily resolve and study
these small entropy differences, we have implemented two different
multicanonical Monte Carlo algorithms that allow direct equilibration between
crystals with different stacking sequences. Recent work had demonstrated that
the fcc stacking has higher entropy than the hcp stacking. We have studied
other stackings to demonstrate that the fcc stacking does indeed have the
highest entropy of ALL possible stackings. The entropic interactions we could
detect involve three, four and (although with less statistical certainty) five
consecutive layers of spheres. These interlayer entropic interactions fall off
in strength with increasing distance, as expected; this fall-off appears to be
much slower near the melting density than at the maximum (close-packing)
density. At maximum density the entropy difference between fcc and hcp
stackings is per sphere, which is roughly 30% higher
than the same quantity measured near the melting transition.Comment: 15 page
Long-Time Behavior of Velocity Autocorrelation Function for Interacting Particles in a Two-Dimensional Disordered System
The long-time behavior of the velocity autocorrelation function (VACF) is
investigated by the molecular dynamics simulation of a two-dimensional system
which has both a many-body interaction and a random potential. With
strengthening the random potential by increasing the density of impurities, a
crossover behavior of the VACF is observed from a positive tail, which is
proportional to t^{-1}, to a negative tail, proportional to -t^{-2}. The latter
tail exists even when the density of particles is the same order as the density
of impurities. The behavior of the VACF in a nonequilibrium steady state is
also studied. In the linear response regime the behavior is similar to that in
the equilibrium state, whereas it changes drastically in the nonlinear response
regime.Comment: 12 pages, 5 figure
Free energies of crystalline solids: a lattice-switch Monte Carlo method
We present a method for the direct evaluation of the difference between the
free energies of two crystalline structures, of different symmetry. The method
rests on a Monte Carlo procedure which allows one to sample along a path,
through atomic-displacement-space, leading from one structure to the other by
way of an intervening transformation that switches one set of lattice vectors
for another. The configurations of both structures can thus be sampled within a
single Monte Carlo process, and the difference between their free energies
evaluated directly from the ratio of the measured probabilities of each. The
method is used to determine the difference between the free energies of the fcc
and hcp crystalline phases of a system of hard spheres.Comment: 5 pages Revtex, 3 figure
Liquid-Solid Phase Transition of the System with Two particles in a Rectangular Box
We study the statistical properties of two hard spheres in a two dimensional
rectangular box. In this system, the relation like Van der Waals equation loop
is obtained between the width of the box and the pressure working on side
walls. The auto-correlation function of each particle's position is calculated
numerically. By this calculation near the critical width, the time at which the
correlation become zero gets longer according to the increase of the height of
the box. Moreover, fast and slow relaxation processes like and
relaxations observed in supper cooled liquid are observed when the height of
the box is sufficiently large. These relaxation processes are discussed with
the probability distribution of relative position of two particles.Comment: 6 figure
Coulomb Excitation of Multi-Phonon Levels of the Giant Dipole Resonance
A closed expression is obtained for the cross-section for Coulomb excitation
of levels of the giant dipole resonance of given angular momentum and phonon
number. Applications are made to the Goldhaber-Teller and Steinwedel-Jensen
descriptions of the resonance, at non-relativistic and relativistic bombarding
energies.Comment: 16 pages, 5 figure
Theory of Second and Higher Order Stochastic Processes
This paper presents a general approach to linear stochastic processes driven
by various random noises. Mathematically, such processes are described by
linear stochastic differential equations of arbitrary order (the simplest
non-trivial example is , where is not a Gaussian white
noise). The stochastic process is discretized into time-steps, all possible
realizations are summed up and the continuum limit is taken. This procedure
often yields closed form formulas for the joint probability distributions.
Completely worked out examples include all Gaussian random forces and a large
class of Markovian (non-Gaussian) forces. This approach is also useful for
deriving Fokker-Planck equations for the probability distribution functions.
This is worked out for Gaussian noises and for the Markovian dichotomous noise.Comment: 35 pages, PlainTex, accepted for publication in Phys Rev. E
Effect of boundary conditions on diffusion in two-dimensional granular gases
We analyze the influence of boundary conditions on numerical simulations of
the diffusive properties of a two dimensional granular gas. We show in
particular that periodic boundary conditions introduce unphysical correlations
in time which cause the coefficient of diffusion to be strongly dependent on
the system size. On the other hand, in large enough systems with hard walls at
the boundaries, diffusion is found to be independent of the system size. We
compare the results obtained in this case with Langevin theory for an elastic
gas. Good agreement is found. We then calculate the relaxation time and the
influence of the mass for a particle of radius in a sea of particles of
radius . As granular gases are dissipative, we also study the influence of
an external random force on the diffusion process in a forced dissipative
system. In particular, we analyze differences in the mean square velocity and
displacement between the elastic and inelastic cases.Comment: 15 figures eps figures, include
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