Cyclic Triindoles and Tetraindoles: Substituent and Symmetry Effects on their Structural and Electronic Characteristics

During the last decade heptacyclic 10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (triindole) has been extensively studied as a new π-conjugated platform in the construction of self-assembling materials for optoelectronics. Specially remarkably is the record hole mobility values determined on triindole liquid crystals.1 In order to facilitate the design of new materials on a molecular basis and establish clear guidelines to fine tuning electronic parameters, we have recently synthesized new triindole and tetraindole-based systems.2-3 Our joint experimental and theoretical investigation shows that N-substitution, symmetry lowering of the platform, and insertion of π-spacers in extended dimers strongly impact on the fundamental electronic properties of triindoles.2 In addition, saddle-shaped tetraindoles are found to be an interesting 3D rigid scaffold to obtain electroactive molecules with increased dimensionality.3 We hope that this study can not only advance useful structure-property relationships of conjugated indole-based systems but also guide the design of new materials with potential applications in organic electronics.References 1. E.M. García-Frutos, U.K. Pandey, R. Termine, A. Omenat, J. Barberá, J.L. Serrano, A. Golemme, B. Gómez-Lor, Angew. Chem. Int. Ed. 2011, 50, 7399 2. a) C. Ruiz, J.T. López Navarrete, M.C.Ruiz Delgado, B. Gómez-Lor, Org. Lett. 2015, 17, 2258−2261. b) C. Ruiz, E.M. García-Frutos, D.A. da Silva Filho, J.T. López Navarrete, M.C. Ruiz Delgado, and B. Gómez-Lor, J. Phys. Chem. C 2014, 118, 5470−5477 3. C. Ruiz, A. Monge, E. Gutiérrez-Puebla, I. Alkorta, J. Elguero, J. T. López Navarrete, M.C. Ruiz Delgado and B. Gómez-Lor, submittedUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Cold Dark Matter and b --> s gamma in the Horava-Witten Theory

The minimal supersymmetric standard model with complete, partial or no Yukawa unification and radiative electroweak breaking with boundary conditions from the Horava-Witten theory is considered. The parameters are restricted by constraining the lightest sparticle relic abundance by cold dark matter considerations and requiring the b-quark mass after supersymmetric corrections and the branching ratio of b --> s gamma to be compatible with data. Complete Yukawa unification can be excluded. Also, t-b Yukawa unification is strongly disfavored since it requires almost degenerate lightest and next-to-lightest sparticle masses. However, the b-tau or no Yukawa unification cases avoid this degeneracy. The latter with mu<0 is the most natural case. The lightest sparticle mass, in this case, can be as low as about 77 GeV.Comment: 16 pages including 4 figures, Revtex, version to appear in Phys. Lett.

Yukawa Unification, b --> s gamma and Bino-Stau Coannihilation

The minimal supersymmetric standard model with universal boundary conditions and "asymptotic" Yukawa unification is considered. The full one-loop effective potential for radiative electroweak symmetry breaking as well as the one-loop corrections to the charged Higgs boson, b-quark and tau lepton masses are included. The CP-even Higgs boson masses are corrected to two-loops. The relic abundance of the lightest supersymmetric particle (bino) is calculated by including its coannihilations with the next-to-lightest supersymmetric particle (lightest stau) consistently with Yukawa unification. The branching ratio of b --> s gamma is evaluated by incorporating all the applicable next-to-leading order QCD corrections. The bino-stau coannihilations reduce the bino relic abundance below the upper bound from cold dark matter considerations in a sizable fraction of the parameter space allowed by b --> s gamma for mu>0. Thus, the mu>0 case, which also predicts an acceptable b-quark mass, is perfectly compatible with data.Comment: 16 pages including 3 figures, Revtex, major revisions are mad

Radio Circular Polarization Produced in Helical Magnetic Fields in Eight Active Galactic Nuclei

Homan & Lister (2006) have recently published circular-polarization (CP) detections for 34 objects in the MOJAVE sample - a set of bright, compact AGN being monitored by the Very Long Baseline Array at 15 GHz. We report the detection of 15-GHz parsec-scale CP in two more AGN (3C345 and 2231+114), and confirm the MOJAVE detection of CP in 1633+382. It is generally believed that the most likely mechanism for the generation of this CP is Faraday conversion of linear polarization to CP. A helical jet magnetic-field (B-field) geometry can facilitate this process - linearly polarized emission from the far side of the jet is converted to CP as it passes through the magnetised plasma at the front side of the jet on its way toward the observer. In this case, the sign of the generated CP is essentially determined by the pitch angle and helicity of the helical B field. We have determined the pitch-angle regimes and helicities of the helical jet B fields in 8 AGN for which parsec-scale CP has been detected, and used them to predict the expected CP signs for these AGN if the CP is generated via conversion in these helical fields. We have obtained the intriguing result that our predictions agree with the observed signs in all eight cases, provided that the longitudinal B-field components in the jets correspond to South magnetic poles. This clearly non-random pattern demonstrates that the observed CP in AGN is directly associated with the presence of helical jet B fields. These results suggest that helical B fields are ubiquitous in AGN jets.Comment: 24 pages, 6 figures, accepted for publication in Monthly Notices of the Royal Astronomical Society (MNRAS

The physical properties of star forming galaxies in the low redshift universe

(modified) We present a comprehensive study of the physical properties of \~10^5 galaxies with measurable star formation in the SDSS. By comparing physical information extracted from the emission lines with continuum properties, we build up a picture of the nature of star-forming galaxies at z<0.2. We take out essentially all aperture bias using resolved imaging, allowing an accurate estimate of the total SFRs in galaxies. We determine the SFR density to be 1.915^{+0.02}_{-0.01}(rand.)^{+0.14}_{-0.42} (sys.) h70 10^{-2} Msun/yr/Mpc^3 at z=0.1 (for a Kroupa IMF) and we study the distribution of star formation as a function of various physical parameters. The majority of the star formation in the low redshift universe takes place in moderately massive galaxies (10^10-10^11 Msun), typically in HSB disk galaxies. Roughly 15% of all star formation takes place in galaxies that show some sign of an active nucleus. About 20% occurs in starburst galaxies. We show that the present to past-average star formation rate, the Scalo b-parameter; is almost constant over almost three orders of magnitude in mass, declining only at M*>10^10 Msun. The volume averaged b parameter is 0.408^{+0.005}_{-0.002} (rand).^{+0.029}_{-0.090} (sys.) h70^{-1}. We use this value constrain the star formation history of the universe. In agreement with other work we find a correlation between $b$ and morphological type, as well as a tight correlation between the 4000AA break (D4000) and b. We discuss how D4000 can be used to estimate b parameters for high redshift galaxies.Comment: Accepted for MNRAS. Replaced with accepted version. A section on comparison with other methods of SFR estimation added and various updates have been made. The main results are almost unchange

New signposts of massive star formation in the S235A-B region

We report on new aspects of the star-forming region S235AB revealed through high-resolution observations at radio and mid-infrared wavelengths. Using the Very Large Array, we carried out sensitive observations of S235AB in the cm continuum (6, 3.6, 1.3, and 0.7) and in the 22 GHz water maser line. These were complemented with Spitzer Space Telescope Infrared Array Camera archive data to clarify the correspondence between radio and IR sources. We made also use of newly presented data from the Medicina water maser patrol, started in 1987, to study the variability of the water masers found in the region. S235A is a classical HII region whose structure is now well resolved. To the south, no radio continuum emission is detected either from the compact molecular core or from the jet-like structure observed at 3.3 mm, suggesting emission from dust in both cases. We find two new compact radio continuum sources (VLA-1 and VLA-2) and three separate maser spots. VLA-1 coincides with one of the maser spots and with a previously identified IR source (M1). VLA-2 lies towards S235B and represents the first radio detection from this peculiar nebula that may represent an ionized wind from a more evolved star. The two other maser spots coincide with an elongated structure previously observed within the molecular core in the C34S line. This structure is perpendicular to a bipolar molecular outflow observed in HCO+(1-0) and may trace the associated equatorial disk. The Spitzer images reveal a red object towards the molecular core. This is the most viable candidate for the embedded source originating the outflow and maser phenomenology. The picture emerging from these and previous data shows the extreme complexity of a small (< 0.5 pc) star-forming region where widely different stages of stellar evolution are present.Comment: 15 pages, 16 figures, to be published in Astronomy & Astrophysic

Comments on A,B,C Chains of Heterotic and Type II Vacua

We construct, as hypersurfaces in toric varieties, Calabi-Yau manifolds corresponding to F-theory vacua dual to E8*E8 heterotic strings compactified to six dimensions on K3 surfaces with non-semisimple gauge backgrounds. These vacua were studied in the recent work of Aldazabal, Font, Ibanez and Uranga. We extend their results by constructing many more examples, corresponding to enhanced gauge symmetries, by noting that they can be obtained from previously known Calabi-Yau manifolds corresponding to K3 compactification of heterotic strings with simple gauge backgrounds by means of extremal transitions of the conifold type.Comment: 27p Plain TeX, 6 figures (4 in color) included via epsf.te

Yukawa Quasi-Unification

We construct concrete supersymmetric grand unified theories based on the Pati-Salam gauge group SU(4)_c x SU(2)_L x SU(2)_R which naturally lead to a moderate violation of "asymptotic" Yukawa unification and thus can allow an acceptable b-quark mass even with universal boundary conditions. We consider the constrained minimal supersymmetric standard model which emerges from one of these theories with a deviation from Yukawa unification which is adequate for mu>0. We show that this model possesses a wide and natural range of parameters which is consistent with the data on b --> s gamma, the muon anomalous magnetic moment, the cold dark matter abundance in the universe, and the Higgs boson masses. The lightest supersymmetric particle can be as light as about 107 GeV.Comment: 27 pages including 10 figures, Revtex, minor corrections, version to appear in Nucl. Phys.

The Globular Cluster System of NGC4374

We study the globular cluster system (GCS) of the giant elliptical NGC4374 (M84) in the Virgo cluster using B and R photometry. The colour distribution is bimodal with peaks at B-R=1.11 and B-R=1.36, fitting well to those found in other early-type galaxies. The radial profile of the cluster number density is flatter than the galaxy light. Using the luminosity function we derive a distance modulus of $\mu=31.61\pm0.2$, which within the uncertainty agrees with the distance from surface brightness fluctuations. Blue and red clusters show similar radial concentrations and azimuthal distributions. The total number of clusters is $N=1775\pm150$, which together with our distance modulus leads to a specific frequency of $S_{N}=1.6\pm0.3$. This value is surprisingly low for a giant elliptical, but resembles the case of merger remnants like NGC1316, where the low specific frequency is probably caused by the luminosity contribution of an intermediate-age population. A further common property is the high rate of type Ia supernovae which also may indicate the existence of a younger population. However, unlike in the case of NGC1316, one cannot find any further evidence that NGC4374 indeed hosts younger populations. The low specific frequency would also fit to a S0 galaxy seen face-on.Comment: Accepted for publication in Astronomy & Astrophysics. 11 page

B Mixing and Lifetimes at the Tevatron

The Tevatron collider at Fermilab provides a very rich environment for the study of b-hadrons. Both the D0 and CDF experiments have collected a sample of about 1 fb^{-1}. We report results on three topics: b-hadron lifetimes, polarization amplitudes and the decay width difference in Bs to Jpsi Phi, and Bs mixing.Comment: Flavor Physics & CP Violation Conference, Vancouver, 200