432 research outputs found
Coarse-grained microscopic model of glass formers
We introduce a coarse-grained model for atomic glass formers. Its elements
are physically motivated local microscopic dynamical rules parameterized by
observables. Results of the model are established and used to interpret the
measured behaviors of supercooled fluids approaching glass transitions. The
model predicts the presence of a crossover from hierarchical super-Arrhenius
dynamics at short length scales to diffusive Arrhenius dynamics at large length
scales. This prediction distinguishes our model from other theories of glass
formers and can be tested by experiment.Comment: 5 pages, 5 figure
Eddy Covariance flux errors due to random and systematic timing errors during data acquisition
Modern eddy covariance (EC) systems collect
high-frequency data (10–20 Hz) via digital outputs of instru ments. This is an important evolution with respect to the tra ditional and widely used mixed analog/digital systems, as
fully digital systems help overcome the traditional limita tions of transmission reliability, data quality, and complete ness of the datasets
Absorption and photoluminescence spectroscopy on a single self-assembled charge-tunable quantum dot
We have performed detailed photoluminescence (PL) and absorption spectroscopy
on the same single self-assembled quantum dot in a charge-tunable device. The
transition from neutral to charged exciton in the PL occurs at a more negative
voltage than the corresponding transition in absorption. We have developed a
model of the Coulomb blockade to account for this observation. At large
negative bias, the absorption broadens as a result of electron and hole
tunneling. We observe resonant features in this regime whenever the quantum dot
hole level is resonant with two-dimensional hole states located at the capping
layer-blocking barrier interface in our structure.Comment: 6 pages, 6 figure
Excitation lines and the breakdown of Stokes-Einstein relations in supercooled liquids
By applying the concept of dynamical facilitation and analyzing the
excitation lines that result from this facilitation, we investigate the origin
of decoupling of transport coefficients in supercooled liquids. We illustrate
our approach with two classes of models. One depicts diffusion in a strong
glass former, and the other in a fragile glass former. At low temperatures,
both models exhibit violation of the Stokes-Einstein relation,
, where is the self diffusion constant and is the
structural relaxation time. In the strong case, the violation is sensitive to
dimensionality , going as for , and as for . In the fragile case, however, we argue that
dimensionality dependence is weak, and show that for , . This scaling for the fragile case compares favorably with the
results of a recent experimental study for a three-dimensional fragile glass
former.Comment: 7 pages, 7 figures, submitted to Phys. Rev.
Dynamic heterogeneities in the out-of-equilibrium dynamics of simple spherical spin models
The response of spherical two-spin interaction models, the spherical
ferromagnet (s-FM) and the spherical Sherrington-Kirkpatrick (s-SK) model, is
calculated for the protocol of the so-called nonresonant hole burning
experiment (NHB) for temperatures below the respective critical temperatures.
It is shown that it is possible to select dynamic features in the
out-of-equilibrium dynamics of both models, one of the hallmarks of dynamic
heterogeneities. The behavior of the s-SK model and the s-FM in three
dimensions is very similar, showing dynamic heterogeneities in the long time
behavior, i.e. in the aging regime. The appearence of dynamic heterogeneities
in the s-SK model explicitly demonstrates that these are not necessarily
related to {\it spatial} heterogeneities. For the s-FM it is shown that the
nature of the dynamic heterogeneities changes as a function of dimensionality.
With incresing dimension the frequency selectivity of the NHB diminishes and
the dynamics in the mean-field limit of the s-FM model becomes homogeneous.Comment: 16 pages, 8 figure
Kinetic Heterogeneities in a Highly Supercooled Liquid
We study a highly supercooled two-dimensional fluid mixture via molecular
dynamics simulation. We follow bond breakage events among particle pairs, which
occur on the scale of the relaxation time . Large scale
heterogeneities analogous to the critical fluctuations in Ising systems are
found in the spatial distribution of bonds which are broken in a time interval
with a width of order . The structure factor of the broken
bond density is well approximated by the Ornstein-Zernike form. The correlation
length is of order at the lowest temperature studied,
being the particle size. The weakly bonded regions thus identified evolve in
time with strong spatial correlations.Comment: 3 pages, 6 figure
Is there something of the MCT in orientationally disordered crystals ?
Molecular Dynamics simulations have been performed on the orientationally
disordered crystal chloroadamantane: a model system where dynamics are almost
completely controlled by rotations. A critical temperature T_c = 225 K as
predicted by the Mode Coupling Theory can be clearly determined both in the
alpha and beta dynamical regimes. This investigation also shows the existence
of a second remarkable dynamical crossover at the temperature T_x > T_c
consistent with a previous NMR and MD study [1]. This allows us to confirm
clearly the existence of a 'landscape-influenced' regime occurring in the
temperature range [T_c-T_x] as recently proposed [2,3].Comment: 4 pages, 5 figures, REVTEX
The nature of slow dynamics in a minimal model of frustration-limited domains
We present simulation results for the dynamics of a schematic model based on
the frustration-limited domain picture of glass-forming liquids. These results
are compared with approximate theoretical predictions analogous to those
commonly used for supercooled liquid dynamics. Although model relaxation times
increase by several orders of magnitude in a non-Arrhenius manner as a
microphase separation transition is approached, the slow relaxation is in many
ways dissimilar to that of a liquid. In particular, structural relaxation is
nearly exponential in time at each wave vector, indicating that the mode
coupling effects dominating liquid relaxation are comparatively weak within
this model. Relaxation properties of the model are instead well reproduced by
the simplest dynamical extension of a static Hartree approximation. This
approach is qualitatively accurate even for temperatures at which the mode
coupling approximation predicts loss of ergodicity. These results suggest that
the thermodynamically disordered phase of such a minimal model poorly
caricatures the slow dynamics of a liquid near its glass transition
Aging and multiscaling in out of equilibrium dynamical processes in granular media
In the framework of recently introduced frustrated lattice gas models, we
study the out of equilibrium dynamical processes during the compaction process
in granular media. We find irreversible-reversible cycles in agreement with
recent experimental observations. Moreover in analogy with the phenomenology of
the glass transition we find aging effects during the compaction process In
particular we find that the two time density correlation function
asymptotically scales as a function of the single variable .
This result is interpreted in terms of multiscaling properties of the system.Comment: 4 page
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