Processing and Synthesis of Multi-Metallic Nano Oxide Ceramics via Liquid-Feed Flame Spray Pyrolysis.

LF-FSP provides access to novel single phase nanopowders, known phases at compositions outside their published phase diagrams, intimate mixing at nanometer length scales in multi metallic oxide nanopowders, and control of stoichiometry to ppm levels. The materials produced may exhibit unusual properties including structural, catalytic, and photonic ones and lower sintering temperatures. Prior studies used LF-FSP to produce MgAl2O4 spinel for applications in transparent armor and IR radomes. In these studies, a stable spinel structure with a (MgO)0.1(Al2O3)0.9 composition well outside the known phase field was observed. The work reported here extends this observation to two other spinel systems: Al2O3-NiO, Al2O3-CoOx; followed by three series of transition metal binary oxides, NiO-CoO, NiO-MoO3, NiO-CuO. The impetus to study spinels derives both from the fact that a number of them are known transparent ceramics, but also others offer high SSAs coupled with unusual phases that suggest potentially novel catalytic materials. Because LF-FSP provides access to any composition, comprehensive studies of the entire tie-lines were conducted rather than just compositions of value for catalytic applications. Initial efforts established baseline properties for the nano aluminate spinels, then three binary transition metal oxide sets (Ni-Co, Ni-Mo and Ni-Cu) known for their catalytic properties. These materials then serve as baseline studies for ternary systems, such as Al:(Ni-Co)O, or Al(Ni-Cu)O likely to offer superior catalytic properties because of the relatively high SSA Al2O3. The final chapter returns to photonic materials, in the MgO-Y2O3 system targeting transparent ceramics through select compositions along the tie-line. The work presented here builds on the MgAl2O4 spinel material and continues to develop the processing techniques required to achieve transparent nano-grained ceramic materials. Thus the overall goal of this dissertation was to systematically produce novel nano-oxide materials and characterized their material properties.Ph.D.Materials Science and EngineeringUniversity of Michigan, Horace H. Rackham School of Graduate Studieshttp://deepblue.lib.umich.edu/bitstream/2027.42/62429/1/jazurdia_1.pd

Finding Spinel in All the Wrong Places We thank the Air Force Office of Scientific Research for support of this work through Contract No. F49620-03-1-0389. Supporting Information is available online from Wiley InterScience or from the author.

No Abstract.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/58573/1/1373_ftp.pd