Effects of organic, inorganic and organo-mineral fertilizer on the growth, yield and nutrient composition of <em>Corchorus Olitorious (L)</em>

Corchorus olitorius (L.) is an important leafy vegetable known for its rich source of several nutrients and dietary fibre in Africa, Asia and some parts of America. One major limitation of cultivating Corchorus olitorius in the tropics is inadequate soil fertility. Fertilizer application is an integral part of the vegetable cultivation due to low soil productivity. The study therefore aims at evaluating the effects of organic, inorganic and organo-min­eral fertilizer at different concertation on the growth, yield and nutrient composition of Corchorus olitorious. The experimental setup followed a complete randomized block design with three replicates. Treatments include control, 1,000 kgha-1 sole poultry manure (PM), 2,000 kgha-1 sole PM, 200 kgha-1 sole NPK, 400 kgha-1 sole NPK, 600 kgha-1 sole NPK, 1,000 kgha-1 PM+200 kgha-1 NPK, 1,000 kgha-1 PM+400 kgha-1 NPK, 1,000 kgha-1 PM+600 kgha-1 NPK, 2,000 kgha-1 PM+200 kg/ha NPK, 2,000 kgha-1 PM+400 kgha-1 NPK and 2,000 kgha-1 PM+600 kgha-1 NPK fertilizer combinations. The growth, yield and nutrient compo­sition of C. olitorious plants were significantly enhanced in all fertilizer treated plots in comparison to the control. Significantly (p&lt;0.05) higher growth parameters, yield and nutrient composi­tion were recorded in the plots treated with combined application of both fertilizers at 2,000 kgha-1 PM+400 kgha-1 NPK and 2,000 kgha-1 PM+600 kgha-1 NPK when compared to other application combinations. This study affirms that the combined application of organic and inorganic fertilizer as a soil amendment could en­hance growth, yield, and nutrient composition of C. olitorious in comparison with sole application of either fertilizers

Structure-activity relationships for group 4 biaryl amidate complexes in catalytic hydroamination/cyclization of aminoalkenes

Synthesis of bis(carboxamide) proligands derived from (R,S)-2,2'-diamino-6,6'dimethylbiphenyl was readily achieved by treatment of the amine with acid chlorides. Direct reaction with homoleptic alkyls of the group 4 metals cleanly yielded amidate complexes. These complexes were shown by single-crystal X-ray diffraction to be monomeric in the case of titanium and dimeric in the case of zirconium. The complexes formed do not yield well-defined cations upon reaction with standard borate/borane activators, and although some hydroamination catalysis was observed, it was not at a rate that is useful. In-situ treatment of Zr(NMe2)(4) with the proligands H2L1-4 yielded complexes of varying nuclearity depending on the steric bulk of the amide substituents, but in contrast to the metal alkyl series, mononuclear species are accessible; the mesityl derivative [(S)-(LZr)-Zr-4(NMe2)(2)] was found to be a highly enantioselective catalyst for the hydroamination/cyclization of 1-amino-2,2-dimethylpent-4-ene, with an enantiomeric excess of 91%