42 research outputs found
A triclinic polymorph of 3-nitroanilinium chloride
The asymmetric unit of the title compound, C6H7N2O2
+·Cl−, contains two independent ion pairs. A monoclinic form of the title compound with only one ion pair in the asymmetric unit has been reported previously [Ploug-Sørensen & Andersen (1986). Acta Cryst. C42, 1813–1815]. In the crystal of the title compound, the components are linked into layers parallel to (001) by intermolecular N—H⋯Cl hydrogen bonds, with alternating hydrophilic and hydrophobic regions
Creatininium hydrogen maleate
In the title compound, C4H8N3O+·C4H3O4
−, the cations and anions are linked through N—H⋯O hydrogen bonds making a ionic pair with an R
2
2(8) ring motif. These ionic pairs are further connected through another N—H⋯O hydrogen bond, leading to an R
6
6(16) ring motif around the inversion centres of the unit cell. These approximately planar aggregates are further connected through weak van der Waals interactions in the unit cell. The anions have a characteristic intramolecular O—H⋯O hydrogen bond with a self-associated ring S(7) motif
1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-aminium 2-hydroxybenzoate
In the title salt, C11H14N3O+·C7H5O3
−, the phenyl ring of the cation is oriented at an angle of 67.0 (1)° with respect to the five-membered pyrazolone ring. The carboxylate plane of the anion is twisted out from the plane of the aromatic ring at an angle of 13.7 (3)°. In the crystal, the cations form hydrogen-bonded dimers with an R
2
2(10) ring motif. The salicylate anion has an intramolecular O—H⋯O hydrogen bond
Creatininium cinnamate
The crystal structure of the title compound (systematic name: 2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 3-phenylprop-2-enoate), C4H8N3O+·C9H7O2
−, is stabilized by N—H⋯O hydrogen bonding. Cations are linked to anions to form ion pairs with an R
2
2(8) ring motif. These ion pairs are connected through a C
2
2(6) chain motif extending along the c axis of the unit cell. This crystal packing is characterized by hydrophobic layers at x ∼ 1/2 packed between hydrophilic layers at x ∼ 0
Creatinium hydrogen oxalate
The crystal structure of the title compound, C4H10N3O2
+·C2HO4
−, is stabilized by N—H⋯O and O—H⋯O hydrogen bonds. The anions are connected by an O—H⋯O hydrogen bond, leading to C(5) chain extending along c axis. The cations are dimerized around the corners of the unit cell, leading to an R
2
2(14) ring motif. This leads to a cationic molecular aggregation at x = 0 or 1 and an anionic molecular aggregation at x = 1/2
Creatininium 2-chloroacetate
In the title compound (systematic name: 2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 2-chloroacetate), C4H8N3O+·C2H2ClO2
−, the molecular aggregations are stabilized through classical (N—H⋯O) and non-classical (C—H⋯O and C—H⋯N) hydrogen-bonding interactions. The cations are linked to the anions, forming ion pairs through two N—H⋯O bonds that produce characteristic R
2
2(8) ring motifs. These cation–anion pairs are connected through another N—H⋯O hydrogen bond, leading to an R
4
2(8) ring motif. Further weak C—H⋯N interactions link the molecules along the a axis, while other C—H⋯O interactions generate zigzag chains extending along b
(E)-3-Phenyl-3-(3-phenyl-1H-1-pyrazolyl)-2-propenal
In the title compound C18H14N2O, the pendant rings make dihedral angles of 66.1 (1)° and 13.9 (1) with the central ring. In the crystal, two molecules form a cyclic centrosymmetric R
2
2(22) dimer through pairs of C—H⋯O bonds. These dimers are further connected into zigzag chains extending along the b axis through C—H⋯π and C—H⋯O interactions
2-Amino-6-(2,4-dichlorophenyl)-4-oxo-3,5-diphenylcyclohex-2-enecarbonitrile
In the title compound, C25H18Cl2N2O, the cyclohexene ring has a sofa conformation. All the substituents in the cyclohexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N—H⋯O hydrogen bonds, forming a chain extending along the b axis and through C—H⋯N and C—H⋯Cl interactions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding
2,6-Bis(2-chlorophenyl)-4-oxo-3,5-diphenylheptane-1,1,7,7-tetracarbonitrile
In the title compound, C35H24Cl2N4O, the phenyl rings are oriented almost parallel to each other, making a dihedral angle of 0.6 (2)°, whereas the chlorophenyl rings are oriented at a dihedral angle of 28.3 (1)°. The crystal structure is stabilized through an extensive series of C—H⋯N, C—H⋯O and C—H⋯Cl interactions. One of the C—H⋯N interactions generates an R
2
2(12) ring motif around a crystallographic inversion centre. C(5), C(10) and C(12) chain motifs are observed in the unit cell through C—H⋯N and C—H⋯Cl interactions. During the structure analysis, it was observed that the unit cell contains large accessible voids, which host disordered solvent molecules. This affects the diffraction pattern, mostly at low scattering angles and was corrected with the SQUEEZE program [Spek, A. L. (2009 ▶). Acta Cryst. D65, 148–155]
4-Chloroanilinium 3-carboxyprop-2-enoate
In the title compound, C6H7ClN+·C4H3O4
−, the cations and anions lie on mirror planes and hence only half of the molecules are present in the asymmeric unit. The 4-chloroanilinium cation and hydrogen maleate anion in the asymmetric unit are each planar and are oriented at an angle of 15.6 (1)° to one another and perpendicular to the b axis. A characterestic intramolecular O—H⋯O hydrogen bond, forming an S(7) motif, is observed in the maleate anion. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds, forming layers in the ab plane. The aromatic rings of the cations are sandwiched between hydrogen-bonded chains and rings formed through the amine group of the cation and maleate anions, leading to alternate hydrophobic (z = 0 or 1) and hydrophilic layers (z = 1/2) along the c axis