Transmittance of tapered photonic crystal fibers with absorbing coatings

The interaction of the adiabatically tapered photonic crystal fiber fundamental mode with a thin-film absorbing coating, deposited on a surface of a taper waist, on transmission of a tapered fiber is studied. Examples of using this interaction in refractive index sensors and for detection of an adsorption layer with ammonia molecules upon contact of the absorbing coating with a liquid medium are presented. It is obtained that a pronounced sensory effect occurs in the case of a resonant coupling between the fundamental fiber mode and cladding modes localized between photonic crystal fiber air channels and the absorbing coating

Transmittance of tapered photonic crystal fibers with absorbing coatings

The interaction of the adiabatically tapered photonic crystal fiber fundamental mode with a thin-film absorbing coating, deposited on a surface of a taper waist, on transmission of a tapered fiber is studied. Examples of using this interaction in refractive index sensors and for detection of an adsorption layer with ammonia molecules upon contact of the absorbing coating with a liquid medium are presented. It is obtained that a pronounced sensory effect occurs in the case of a resonant coupling between the fundamental fiber mode and cladding modes localized between photonic crystal fiber air channels and the absorbing coating

Strength of Compressed Reinforced Concrete Elements Reinforced with CFRP at Different Load Application Eccentricity

Currently, many studies are devoted to the use of polymer composite materials to increase the strength and stability of concrete elements. In compressed reinforced concrete elements, the bearing capacity depends on the eccentricity of the external application of the external force and the corresponding stress-strain state, as well as the location and number of composite materials glued to the surface of the structure. The choice of a scheme for placing composite materials depending on the stress state of the structure is an urgent scientific problem. At the same time, the issue of central compression and the compression of columns with large eccentricities has been well studied. However, studies conducted in the range of average eccentricities often have conflicting results, which is the problem area of this study. The primary aim of this study was to increase the strength and stiffness of compressed reinforced concrete elements reinforced with composite materials, as well as a comparative analysis of the bearing capacity of ten different combinations of external longitudinal, transverse, and combined reinforcement. The results of testing 16 compressed columns under the action of various eccentricities of external load application (e0/h = 0; 0.16; 0.32) are presented. It is shown that the use of composite materials in strengthening structures increases the bearing capacity up to 41%, and the stiffness of the sections increases up to 30%. Based on the results of the study, recommendations are proposed for improving the calculation method for inflexible columns reinforced in the transverse direction, which take the work of concrete under the conditions of a three-dimensional stress state into consideration

Lossy mode resonances in photonic crystal fibers

The interaction effect of the fundamental mode in a special photonic crystal fiber (PCF) with a thin-film absorbing coating deposited on a surface of a fiber cladding on the optical transmission of the PCF is theoretically studied. It is shown that the transmission has a multi-peak spectrum that is determined by the resonance capture of the fundamental PCF mode energy by the coating. In some cases, this capture is explained by a resonance coupling between the fundamental core mode and leaky modes of the coating, or between the fundamental PCF mode and cladding modes located between PCF air channels and the coating. Examples are presented of using this effect to develop fiber-optic sensors of refractive index or pressure, and to sense a nanoscale adsorption layer of ammonia molecules deposited on a coating surface contacting air

Synthesis and Properties of Ethylene/propylene and Ethylene/propylene/5-ethylidene-2-norbornene Copolymers Obtained on Rac-Et(2-MeInd)2ZrMe2/Isobutylaluminium Aryloxide Catalytic Systems

Ethylene/propylene (E/P) and ethylene/propylene/5-ethylidene-2-norbornene (E/P/ENB) copolymers were obtained on rac-Et(2-MeInd)2ZrMe2 activated by a number of isobutylaluminium aryloxides: (2,6-tBu2PhO-)AliBu2 (1-DTBP) (2,6-tBu2,4-Me-PhO-)AliBu2 (1-BHT), (2,4,6-tBu2PhO-)AliBu2 (1-TTBP), (2,6-tBu2,4-Me-PhO-)2AliBu (2-BHT), (2,6-tBu2PhO-)2AliBu (2-DTBP), [(2-Me,6-tBu-C6H3O)AliBu2]2 (1-MTBP), [(2,6-Ph2-PhO)AliBu2]2 (1-DPP). This study shows how the structure of an activator influences catalytic activity and polymer properties, such as the copolymer composition, molecular weight characteristics, and thermophysical and mechanical properties. It has been shown that both the introduction of a bulky substituent in the para-position of the aryloxy group and the additional aryloxy group in the structure of an activator lead to a significant decrease in activity of the catalytic system in all studied copolymerization processes. Moreover, activation by bulkier aryloxides leads to lower levels of comonomer insertion and gives rise to higher molecular weight polymers. Broad or multiple endothermic peaks with different values of melting points are observed on the DSC curves of the copolymers obtained with different catalytic systems. The DSC of the thermally fractionated samples makes it possible to reveal the heterogeneity of the copolymer microstructure, which manifests itself in the presence of a set of lamellar crystallites of different thickness. The results also present the mechanical properties of the copolymers, such as the tensile strength (σ), elongation at break (ε), and engineering strain (EL). The synthesized E/P and E/P/ENB copolymers contain about 1–4 wt.% of the sterically hindered phenols obtained in situ as a residue of the hydrolyzed activators in the course of reaction quenching. This determines the increased thermooxidative stability of the copolymers