Considerations and future perspectives for the vibrational spectroscopic analysis of forensic cosmetic evidence

Cosmetics such as makeup or other personal products are widely used and easily transferred upon physical contact. As such, they may be used as trace evidence to link people to each other or to places in criminal investigations. To maximize their probative value, it is important to understand the variability among representative market products and the way in which they transfer to, or persist on various surfaces. Additionally, it is required that analysis techniques be non-destructive, readily available and relatively inexpensive. Raman spectroscopy and attenuated total reflectance--Fourier transform infrared (ATR-FTIR) are powerful tools for probing the chemistry of trace cosmetics. As well as fitting the criteria above, they offer the capability of studying a wide range of sample types with minimal prior preparation. The complementary information derived from these techniques can help analysts to understand and visualize spectral variability, potentially enabling discrimination between samples. However, the move from academic research toward forensic casework is not without challenges. In this article, we provide a focused exploration of the current state-of-the-art in forensic cosmetic research; providing context for how we may begin to address these challenges to more effectively exploit cosmetic traces for criminal investigation. This article is categorized under: Forensic Chemistry and Trace Evidence > Emerging Technologies and Methods Forensic Chemistry and Trace Evidence > Trace Evidenc

Phase Transitions in the One-Dimensional Pair-Hopping Model: a Renormalization Group Study

The phase diagram of a one-dimensional tight-binding model with a pair-hopping term (amplitude V) has been the subject of some controvery. Using two-loop renormalization group equations and the density matrix renormalization group with lengths L<=60, we argue that no spin-gap transition occurs at half-filling for positive V, contrary to recent claims. However, we point out that away from half-filling, a *phase-separation* transition occurs at finite V. This transition and the spin-gap transition occuring at half-filling and *negative* V are analyzed numerically.Comment: 7 pages RevTeX, 6 uuencoded figures which can be (and by default are) directly included. Received by Phys. Rev. B 20 April 199

Protecting the Baryon Asymmetry with Thermal Masses

We consider the evolution of baryon number $B$ in the early universe under the influence of rapid sphaleron interactions and show that $B$ will remain nonzero at all times even in the case of $B-L = 0$. This result arises due to thermal Yukawa interactions that cause nonidentical dispersion relations (thermal masses) for different lepton families. We point out the relevance of our result to the Affleck-Dine type baryogenesis.Comment: 11pp., plain tex, UMN-TH-1248/94, CfPA-TH-94-1

Subglacial Water Flow Over an Antarctic Palaeo‐Ice Stream Bed

The subglacial hydrological system exerts a critical control on the dynamic behavior of the overlying ice because its configuration affects the degree of basal lubrication between the ice and the bed. Yet, this component of the glaciological system is notoriously hard to access and observe, particularly over timescales longer than the satellite era. In Antarctica, abundant evidence for past subglacial water flow over former ice-sheet beds exists around the peripheries of the ice sheet including networks of huge channels carved into bedrock (now submarine) on the Pacific margin of West Antarctica. Here, we combine detailed bathymetric investigations of a channel system in Marguerite Trough, a major palaeo-ice stream bed, with numerical hydrological modeling to explore subglacial water accumulation, routing and potential for erosion over decadal-centennial timescales. Detailed channel morphologies from remotely operated vehicle surveys indicate multiple stages of localized incision, and the occurrence of potholes, some gigantic in scale, suggests incision by turbulent water carrying a significant bedload. Further, the modeling indicates that subglacial water is available during deglaciation and was likely released in episodic drainage events, from subglacial lakes, varying in magnitude over time. Our observations support previous assertions that these huge bedrock channel systems were incised over multiple glacial cycles through episodic subglacial lake drainage events; however, here we present a viable pattern for subglacial drainage at times when the ice sheet existed over the continental shelf and was capable of continuing to erode the bedrock substrate

Target Space Duality between Simple Compact Lie Groups and Lie Algebras under the Hamiltonian Formalism: I. Remnants of Duality at the Classical Level

It has been suggested that a possible classical remnant of the phenomenon of target-space duality (T-duality) would be the equivalence of the classical string Hamiltonian systems. Given a simple compact Lie group $G$ with a bi-invariant metric and a generating function $\Gamma$ suggested in the physics literature, we follow the above line of thought and work out the canonical transformation $\Phi$ generated by $\Gamma$ together with an \Ad-invariant metric and a B-field on the associated Lie algebra $\frak g$ of $G$ so that $G$ and $\frak g$ form a string target-space dual pair at the classical level under the Hamiltonian formalism. In this article, some general features of this Hamiltonian setting are discussed. We study properties of the canonical transformation $\Phi$ including a careful analysis of its domain and image. The geometry of the T-dual structure on $\frak g$ is lightly touched.Comment: Two references and related comments added, also some typos corrected. LaTeX and epsf.tex, 36 pages, 4 EPS figures included in a uuencoded fil

Denominators of Eisenstein cohomology classes for GL_2 over imaginary quadratic fields

We study the arithmetic of Eisenstein cohomology classes (in the sense of G. Harder) for symmetric spaces associated to GL_2 over imaginary quadratic fields. We prove in many cases a lower bound on their denominator in terms of a special L-value of a Hecke character providing evidence for a conjecture of Harder that the denominator is given by this L-value. We also prove under some additional assumptions that the restriction of the classes to the boundary of the Borel-Serre compactification of the spaces is integral. Such classes are interesting for their use in congruences with cuspidal classes to prove connections between the special L-value and the size of the Selmer group of the Hecke character.Comment: 37 pages; strengthened integrality result (Proposition 16), corrected statement of Theorem 3, and revised introductio

A strongly first order electroweak phase transition from strong symmetry-breaking interactions

We argue that a strongly first order electroweak phase transition is natural in the presence of strong symmetry-breaking interactions, such as technicolor. We demonstrate this using an effective linear scalar theory of the symmetry-breaking sector.Comment: LaTex, 15 pages, 3 figures in EPS format. Phys. Rev. D approved Typographically Correct version, minor grammatical change

Markov Chain Methods For Analyzing Complex Transport Networks

We have developed a steady state theory of complex transport networks used to model the flow of commodity, information, viruses, opinions, or traffic. Our approach is based on the use of the Markov chains defined on the graph representations of transport networks allowing for the effective network design, network performance evaluation, embedding, partitioning, and network fault tolerance analysis. Random walks embed graphs into Euclidean space in which distances and angles acquire a clear statistical interpretation. Being defined on the dual graph representations of transport networks random walks describe the equilibrium configurations of not random commodity flows on primary graphs. This theory unifies many network concepts into one framework and can also be elegantly extended to describe networks represented by directed graphs and multiple interacting networks.Comment: 26 pages, 4 figure

The triple-pomeron regime and the structure function of the pomeron in the diffractive deep inelastic scattering at very small x

Misprints and numerical coefficients corrected, a bit of phenomenology and one figure added. The case for the linear evolution of the unitarized structure functions made stronger.Comment: KFA-IKP(Th)-1993-17, Landau-16/93, 46 pages, 14 figures upon request from N.Nikolaev, [email protected]

Hamiltonian dynamics and Noether symmetries in Extended Gravity Cosmology

We discuss the Hamiltonian dynamics for cosmologies coming from Extended Theories of Gravity. In particular, minisuperspace models are taken into account searching for Noether symmetries. The existence of conserved quantities gives selection rule to recover classical behaviors in cosmic evolution according to the so called Hartle criterion, that allows to select correlated regions in the configuration space of dynamical variables. We show that such a statement works for general classes of Extended Theories of Gravity and is conformally preserved. Furthermore, the presence of Noether symmetries allows a straightforward classification of singularities that represent the points where the symmetry is broken. Examples of nonminimally coupled and higher-order models are discussed.Comment: 20 pages, Review paper to appear in EPJ