Dual In-Situ Water Diffusion Monitoring of GFRPs based on Optical Fibres and CNTs

Glass Fibre Reinforced Polymer (GRFP) composites are increasingly being used as new materials for civil and petrochemical engineering infrastructures, owing to the combination of relatively high specific strength and stiffness and cost-competitiveness over traditional materials. However, practical concerns remain on the environmental stability of these materials in harsh environments. For instance, diffusion of salty water through the composites can trigger degradation and ageing. For this reason, a continuous monitoring of the integrity of GFRP composites is required. GRFPs health monitoring solutions, being non-destructive, in-situ, real-time, highly reliable and remotely controllable, are as desirable as challenging. Herein we develop and compare two methods for real-time monitoring of GRFP: one based on the electrical sensing signals of percolated carbon nanotubes (CNTs) networks and the other on optical fibre sensors (OFSs). As a proof-of-concept of dual sensory system, both sensors were used in combination to detect the diffusion of water through the composite. Measurements demonstrated that both CNTs and OFSs were able to detect water diffusion through the epoxy matrix successfully, with an on-off sensing behaviour. OFSs exhibit some advantages since they do not require electrical supply as required in hazardous environments and are more suitable for remote operation, which make them attractive for new developments in harsh-environment sensing. On the other hand, CNTs can be easily embedded in the composite without compromising its performance (e.g., mechanical properties) and are easily interrogated by measurement of electrical conductance, therefore could be used as spot sensors in the most failure-prone sections of GFRP components. This study opens up the possibility for an early detection of composites degradation, which could prevent failures in GFRP structures such as pipelines and storage tanks used in the oil and gas industry

Micro-end-milling of carbon nanotube reinforced epoxy nanocomposites manufactured using three roll mill technique

Carbon nanotubes (CNTs) have been applied as nano-fillers to improve mechanical, thermal and electrical properties of polymers. Despite near net shape techniques could be used to manufacture nanocomposites, micromachining processes are still necessary to attain high surface quality and dimensional accuracy. Besides, micromachining of nanocomposites could be a potential approach to produce micro-features/components, following the miniaturisation trend of modern manufacturing. Therefore, micro-machining of these relatively new materials needs to be investigated. A comprehensive investigation on machinability of nanocomposites will be presented in terms of chip formation, cutting force, tool wear, surface morphology and surface roughness. Three controlled quantitative factors are investigated at different levels, including filler loading, cutting speed and feed per tooth (FPT). Micro-slotting is performed on an ultra-precision desktop micro-machine tool using uncoated carbide micro-end mill. The additions of multi-walled carbon nanotube (MWCNT) have shown significant effects on the machinability of these epoxy-based nanocomposites including a dramatic reduction in cutting force and machined surface roughness with accelerating tool wear compared with a neat polymer. The irregular cutting force variations when micro-milling epoxy/MWCNT nanocomposites at feed rates below minimum uncut chip thickness (MUCT) (lower than 2 μm) indicating by their fluctuations that different from those in higher feed rates. It possibly shows the impact of size effects that are illustrated by the observations of chip formation, surface morphology, cutting force profiles as well as specific cutting energy calculation

Light-Driven Actuation in Synthetic Polymers: A Review from Fundamental Concepts to Applications

Light-driven actuation of synthetic polymers is an emerging field of interest because it offers simple remote addressing without complicated hydraulic, electric, or magnetic systems. Reviews on this area predominantly emphasize on the development of mechanical motions like bending, twisting, folding, etc. However, the scientific and fundamental aspects of these materials are critical in order to expand applications and industrial relevance. Polymer actuators driven by light, not only comprise soft actuators (large deformations at low stress) but also include stiff actuators (high actuation stress at low strain). Synthetic polymeric materials with photo-responsive additives together with underlying mechanisms, processing parameters, and final properties are required to broaden the scope of the field. In particular, parameters like actuation stress, actuation strain, and work capacity have been given limited attention in the past and are discussed extensively. This work gives a comprehensive critical review on all light-driven synthetic polymer actuators, their actuating mechanisms, and materials. A holistic perspective together with an insight into future prospects can lead academia and industry toward future innovations and applications of these exciting functional materials

Toward self-powered sensing and thermal energy harvesting in high-performance composites via self-folded carbon nanotube honeycomb structures

The development of high-performance self-powered sensors in advanced composites addresses the increasing demands of various fields such as aerospace, wearable electronics, healthcare devices, and the Internet-of-Things. Among different energy sources, the thermoelectric (TE) effect which converts ambient temperature gradients to electric energy is of particular interest. However, challenges remain on how to increase the power output as well as how to harvest thermal energy at the out-of-plane direction in high-performance fiber-reinforced composite laminates, greatly limiting the pace of advance in this evolving field. Herein, we utilize a temperature-induced self-folding process together with continuous carbon nanotube veils to overcome these two challenges simultaneously, achieving a high TE output (21 mV and 812 nW at a temperature difference of 17 °C only) in structural composites with the capability to harvest the thermal energy from out-of-plane direction. Real-time self-powered deformation and damage sensing is achieved in fabricated composite laminates based on a thermal gradient of 17 °C only, without the need of any external power supply, opening up new areas of autonomous self-powered sensing in high-performance applications based on TE materials.</p