Nanofluid as Advanced Cooling Technology. Success Stories

Nanofluids are defined as heat transfer fluids with enhanced heat transfer properties by the addition of nanoparticles. Nanofluid’s stability, nanoparticles’ type and their chemical compatibility with the base fluid are essential not only to increase the nanofluid’s thermophysical properties but also to ensure a long-lasting and thermal efficient use of the equipment in which it is used. Some of these aspects are discussed in this chapter. Likewise, the improvement in terms of the heat transfer capacity (thermal resistance) that the use of nanofluids has on the heat pipes-thermosyphons is shown. On the other hand, the improvement in energy efficiency that nanofluid causes in a vapor compression system is also presented

Li2CO3 as Protection for a High-Temperature Thermoelectric Generator: Thermal Stability and Corrosion Analysis

In most steelmaking processes, huge amounts of waste heat at high temperature (700–800 °C) are thrown into the environment without any use. An alternative use for this waste heat is electricity generation through thermoelectric generators. However, these high temperatures, as well as their fluctuations over time, affect not only the conversion rate of the thermoelectric generator but also its useful lifetime. The incorporation of a latent thermal energy storage (TES) system could be a solution; nevertheless, the thermal stability and corrosive effect of the (PCM) phase change material are key aspects for the thermal storage system definition, in terms of durability. In this work, developed in the framework of the European project “PowGETEG” (RFSR-CT-2015-00028, funded by the Research Fund for Coal and Steel), a high-temperature analysis (700–800 °C) of the Li2CO3 thermal properties, thermal stability and corrosive effect on the AISI 304 and AISI 310 stainless steels is carried out. The results show that the eutectic salt Li2CO3 exhibits high thermal stability with neither change in its thermal properties nor material degradation. This work shows that lithium carbonate Li2CO3 and AISI 310 make a very good combination for the definition of a thermal storage system able to protect a high-temperature thermoelectric converter from temperature variations, making it more reliable

Carbon Inks-Based Screen-Printed Electrodes for Qualitative Analysis of Amino Acids

Due to the great significance of amino acids, a substantial number of research studies has been directed toward the development of effective and reliable platforms for their evaluation, detection, and identification. In order to support these studies, a new electrochemical platform based on PANI/ZnO nanowires’ modified carbon inks screen-printed electrodes was developed for qualitative analysis of electroactive amino acids, with emphasis on tyrosine (Tyr) and tryptophan (Trp). A comparative investigation of the carbon ink before and after modification with the PANI/ZnO was performed by scanning electron microscopy and by Raman spectroscopy, confirming the presence of PANI and ZnO nanowires. Electrochemical investigations by cyclic voltammetry and electrochemical impedance spectroscopy have shown a higher charge-transfer rate constant, which is reflected into lower charge-transfer resistance and higher capacitance values for the PANI/ZnO modified ink when compared to the simple carbon screen-printed electrode. In order to demonstrate the electrochemical performances of the PANI/ZnO nanowires’ modified carbon inks screen-printed electrodes for amino acids analysis, differential pulse voltammograms were obtained in individual and mixed solutions of electroactive amino acids. It has been shown that the PANI/ZnO nanowires’ modified carbon inks screen-printed electrodes allowed for tyrosine and tryptophan a peak separation of more than 100 mV, enabling their screening and identification in mixed solutions, which is essential for the electrochemical analysis of proteins within the proteomics research field