1 research outputs found
catena-Poly[[[μ-aqua-pentaÂaquaÂdizinc(II)]-μ4-benzene-1,2,4,5-tetraÂcarboxylÂato] dihydrate]
The asymmetric unit of the title compound, {[Zn2(C10H2O8)(H2O)6]·2H2O}n, contains two distinct Zn atoms joined by a bridging water molecule and two bridging carboxylÂate groups belonging to distinct halves of benzene-1,2,4,5-tetraÂcarboxylÂate (tbec) tetraÂanionic ligands, both lying on crystallographic inversion centres. The structure of this new isopolymorphic one-dimensional coordination polymer features asymmetric bimetallic octaÂhedral knots. O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms help to consolidate the crystal packing