5 research outputs found

    Simulation of the Betatron Magnetic Field at the Electron Beam Displacement in Comsol Multiphysics

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    This article describes the betatron magnetic field simulation in Comsol Multiphysics software package. The model makes it possible to evaluate the betatron focusing properties at the moment of electron displacement onto the target. The simulation results coincide with the experiment described earlier. The study shows the vertical size of the target affects the focal spot size. However, a target size decrease leads to low output dose, since not all electrons reach it. Therefore, the vertical size of the target should be greater than or equal to the vertical dimension of the accelerated beam

    Investigation of non-oxidative methane conversion over granulated Mo/ZSM-5 catalysts

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    The relevance of the investigation is caused by the need for rational use of natural hydrocarbon gases, containing methane as the main component. Currently, plenty of these gases are burned in flares at oil production sites, that does great damage to the environment in the oil-producing regions of our country. The most promising process that allows obtaining valuable chemical products is the non-oxidative methane conversion into aromatic hydrocarbons over zeolite catalysts modified with transition metal ions. The Mo/ZSM-5 catalysts have high activity in this process. These catalysts are obtained both by impregnation and solid-phase synthesis. Development of the method of preparation of Mo/ZSM-5 catalysts using binder is of great importance for the industrial technology of processing gaseous hydrocarbons. The aim of the work is to study the effect of concentration and method of introducing a binder on physicochemical and catalytic properties of the Mo/ZSM-5 catalyst in non-oxidative methane conversion. Methods of investigation: IR spectroscopy, low-temperature adsorption of nitrogen, temperature-programmed desorption of ammonia (TPD-NH3), gas chromatography. Results. The Mo-containing catalyst based on ZSM-5 zeolite and nanosized molybdenum powder was prepared via solid-phase synthesis. The authors have studied the effect of a binder on physicochemical properties and activity of the Mo/ZSM-5 catalyst in non-oxidative conversion of methane into aromatic hydrocarbons. It was ascertained that the addition of a binder to the Mo/ZSM-5 catalyst results in a change in its texture and acid characteristics. It is shown that the activity of the Mo-containing zeolite during the non-oxidative conversion of methane into aromatic hydrocarbons is determined by the concentration of the binder in the catalyst and does not depend on the method of its introduction

    Investigation of non-oxidative methane conversion over granulated Mo/ZSM-5 catalysts

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    ΠΠΊΡ‚ΡƒΠ°Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ Ρ€Π°Π±ΠΎΡ‚Ρ‹ обусловлСна Π½Π΅ΠΎΠ±Ρ…ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒΡŽ Ρ€Π°Ρ†ΠΈΠΎΠ½Π°Π»ΡŒΠ½ΠΎΠ³ΠΎ использования ΠΏΡ€ΠΈΡ€ΠΎΠ΄Π½Ρ‹Ρ… ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄Π½Ρ‹Ρ… Π³Π°Π·ΠΎΠ², основным ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ‚ΠΎΠΌ ΠΊΠΎΡ‚ΠΎΡ€Ρ‹Ρ… являСтся ΠΌΠ΅Ρ‚Π°Π½ ΠΈ ΠΊΠΎΡ‚ΠΎΡ€Ρ‹Π΅ Π² настоящСС врСмя Π² большом количСствС ΡΠΆΠΈΠ³Π°ΡŽΡ‚ΡΡ Π² Ρ„Π°ΠΊΠ΅Π»ΡŒΠ½Ρ‹Ρ… установках нСфтСпромыслов. НаиболСС пСрспСктивным процСссом, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡŽΡ‰ΠΈΠΌ ΠΏΠΎΠ»ΡƒΡ‡Π°Ρ‚ΡŒ ΠΈΠ· Π½ΠΈΡ… Ρ†Π΅Π½Π½Ρ‹Π΅ химичСскиС ΠΏΡ€ΠΎΠ΄ΡƒΠΊΡ‚Ρ‹, являСтся Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½Π°Ρ конвСрсия ΠΌΠ΅Ρ‚Π°Π½Π° Π² ароматичСскиС ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄Ρ‹ Π½Π° Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π½Ρ‹Ρ… ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π°Ρ…, ΠΌΠΎΠ΄ΠΈΡ„ΠΈΡ†ΠΈΡ€ΠΎΠ²Π°Π½Π½Ρ‹Ρ… ΠΈΠΎΠ½Π°ΠΌΠΈ ΠΏΠ΅Ρ€Π΅Ρ…ΠΎΠ΄Π½Ρ‹Ρ… ΠΌΠ΅Ρ‚Π°Π»Π»ΠΎΠ². ΠΠ°ΠΈΠ±ΠΎΠ»ΡŒΡˆΡƒΡŽ Π°ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ Π² этом процСссС ΠΏΡ€ΠΎΡΠ²Π»ΡΡŽΡ‚ Mo/ZSM-5 ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Ρ‹, ΠΊΠΎΡ‚ΠΎΡ€Ρ‹Π΅ ΠΏΠΎΠ»ΡƒΡ‡Π°ΡŽΡ‚ ΠΊΠ°ΠΊ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ ΠΏΡ€ΠΎΠΏΠΈΡ‚ΠΊΠΈ, Ρ‚Π°ΠΊ ΠΈ Ρ‚Π²Π΅Ρ€Π΄ΠΎΡ„Π°Π·Π½Ρ‹ΠΌ синтСзом. Π Π°Π·Ρ€Π°Π±ΠΎΡ‚ΠΊΠ° Π½Π°ΡƒΡ‡Π½Ρ‹Ρ… основ приготовлСния Мо/ZSM-5 ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€ΠΎΠ² с использованиСм ΡΠ²ΡΠ·ΡƒΡŽΡ‰Π΅Π³ΠΎ вСщСства Ρ€Π°Π·Π»ΠΈΡ‡Π½ΠΎΠΉ ΠΏΡ€ΠΈΡ€ΠΎΠ΄Ρ‹ ΠΈΠΌΠ΅Π΅Ρ‚ большоС Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ для ΠΏΡ€ΠΎΠΌΡ‹ΡˆΠ»Π΅Π½Π½ΠΎΠ³ΠΎ внСдрСния Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈ ΠΏΠ΅Ρ€Π΅Ρ€Π°Π±ΠΎΡ‚ΠΊΠΈ Π³Π°Π·ΠΎΠΎΠ±Ρ€Π°Π·Π½Ρ‹Ρ… ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄ΠΎΠ². ЦСль Ρ€Π°Π±ΠΎΡ‚Ρ‹: исслСдованиС влияния ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΈ ΠΈ способа ввСдСния ΡΠ²ΡΠ·ΡƒΡŽΡ‰Π΅Π³ΠΎ вСщСства Π½Π° Ρ„ΠΈΠ·ΠΈΠΊΠΎ-химичСскиС ΠΈ каталитичСскиС свойства Mo/ZSM-5 ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π° Π² процСссС Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ конвСрсии ΠΌΠ΅Ρ‚Π°Π½Π°. ΠœΠ΅Ρ‚ΠΎΠ΄Ρ‹ исслСдования: ИК-спСктроскопия, низкотСмпСратурная адсорбция Π°Π·ΠΎΡ‚Π°, Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Π½ΠΎ-программированная дСсорбция Π°ΠΌΠΌΠΈΠ°ΠΊΠ° (Π’ΠŸΠ”-NH3), газовая хроматография. Π Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹. ΠœΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ Ρ‚Π²Π΅Ρ€Π΄ΠΎΡ„Π°Π·Π½ΠΎΠ³ΠΎ синтСза ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½ Mo-содСрТащий ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€ Π½Π° основС Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° структурного Ρ‚ΠΈΠΏΠ° ZSM-5 ΠΈ Π½Π°Π½ΠΎΡ€Π°Π·ΠΌΠ΅Ρ€Π½ΠΎΠ³ΠΎ ΠΏΠΎΡ€ΠΎΡˆΠΊΠ° ΠΌΠΎΠ»ΠΈΠ±Π΄Π΅Π½Π°. ΠŸΡ€ΠΎΠ²Π΅Π΄Π΅Π½ΠΎ исслСдованиС влияния ΡΠ²ΡΠ·ΡƒΡŽΡ‰Π΅Π³ΠΎ вСщСства Π½Π° Ρ„ΠΈΠ·ΠΈΠΊΠΎ-химичСскиС свойства ΠΈ Π°ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ Mo/ZSM-5 ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π° Π² процСссС Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ конвСрсии ΠΌΠ΅Ρ‚Π°Π½Π° Π² ароматичСскиС ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄Ρ‹. УстановлСно, Ρ‡Ρ‚ΠΎ Π΄ΠΎΠ±Π°Π²ΠΊΠ° ΡΠ²ΡΠ·ΡƒΡŽΡ‰Π΅Π³ΠΎ вСщСства ΠΊ ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Ρƒ Mo/ZSM-5 ΠΏΡ€ΠΈΠ²ΠΎΠ΄ΠΈΡ‚ ΠΊ измСнСнию Π΅Π³ΠΎ тСкстурных ΠΈ кислотных характСристик. Показано, Ρ‡Ρ‚ΠΎ Π°ΠΊΡ‚ΠΈΠ²Π½ΠΎΡΡ‚ΡŒ Mo-содСрТащСго Ρ†Π΅ΠΎΠ»ΠΈΡ‚Π° Π² процСссС Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΠΉ конвСрсии ΠΌΠ΅Ρ‚Π°Π½Π° Π² ароматичСскиС ΡƒΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡ€ΠΎΠ΄Ρ‹ опрСдСляСтся ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠ΅ΠΉ ΡΠ²ΡΠ·ΡƒΡŽΡ‰Π΅Π³ΠΎ вСщСства Π² ΠΊΠ°Ρ‚Π°Π»ΠΈΠ·Π°Ρ‚ΠΎΡ€Π΅ ΠΈ Π½Π΅ зависит ΠΎΡ‚ способа Π΅Π³ΠΎ ввСдСния.The relevance of the investigation is caused by the need for rational use of natural hydrocarbon gases, containing methane as the main component. Currently, plenty of these gases are burned in flares at oil production sites, that does great damage to the environment in the oil-producing regions of our country. The most promising process that allows obtaining valuable chemical products is the non-oxidative methane conversion into aromatic hydrocarbons over zeolite catalysts modified with transition metal ions. The Mo/ZSM-5 catalysts have high activity in this process. These catalysts are obtained both by impregnation and solid-phase synthesis. Development of the method of preparation of Mo/ZSM-5 catalysts using binder is of great importance for the industrial technology of processing gaseous hydrocarbons. The aim of the work is to study the effect of concentration and method of introducing a binder on physicochemical and catalytic properties of the Mo/ZSM-5 catalyst in non-oxidative methane conversion. Methods of investigation: IR spectroscopy, low-temperature adsorption of nitrogen, temperature-programmed desorption of ammonia (TPD-NH3), gas chromatography. Results. The Mo-containing catalyst based on ZSM-5 zeolite and nanosized molybdenum powder was prepared via solid-phase synthesis. The authors have studied the effect of a binder on physicochemical properties and activity of the Mo/ZSM-5 catalyst in non-oxidative conversion of methane into aromatic hydrocarbons. It was ascertained that the addition of a binder to the Mo/ZSM-5 catalyst results in a change in its texture and acid characteristics. It is shown that the activity of the Mo-containing zeolite during the non-oxidative conversion of methane into aromatic hydrocarbons is determined by the concentration of the binder in the catalyst and does not depend on the method of its introduction

    An accelerator facility for WDM, HEDP, and HIF investigations in Nazarbayev University

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    Nazarbayev University (NU) in Astana, Kazakhstan, is planning to build a new multi-MV, ~10 to several hundred GW/cm2 ion accelerator facility which will be used in studies of material properties at extreme conditions relevant to ion-beam-driven inertial fusion energy, and other applications. Two design options have been considered. The first option is a 1.2 MV induction linac similar to the NDCX-II at LBNL, but with modifications, capable of heating a 1 mm spot size thin targets to a few eV temperature. The second option is a 2 - 3 MV, ~200 kA, single-gap-diode proton accelerator powered by an inductive voltage adder. The high current proton beam can be focused to ~1 cm spot size to obtain power densities of several hundred GW/cm2, capable of heating thick targets to temperatures of tens of eV. In both cases, a common requirement to achieving high beam intensity on target and pulse length compression is to utilize beam neutralization at the final stage of beam focusing. Initial experiments on pulsed ion beam neutralization have been carried out on a 0.3 MV, 1.5 GW single-gap ion accelerator at Tomsk Polytechnic University with the goal of creating a plasma region in front of a target at densities exceeding ~1012 cm-3
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