5 research outputs found
Simulation of the Betatron Magnetic Field at the Electron Beam Displacement in Comsol Multiphysics
This article describes the betatron magnetic field simulation in Comsol Multiphysics software package. The model makes it possible to evaluate the betatron focusing properties at the moment of electron displacement onto the target. The simulation results coincide with the experiment described earlier. The study shows the vertical size of the target affects the focal spot size. However, a target size decrease leads to low output dose, since not all electrons reach it. Therefore, the vertical size of the target should be greater than or equal to the vertical dimension of the accelerated beam
Investigation of non-oxidative methane conversion over granulated Mo/ZSM-5 catalysts
The relevance of the investigation is caused by the need for rational use of natural hydrocarbon gases, containing methane as the main component. Currently, plenty of these gases are burned in flares at oil production sites, that does great damage to the environment in the oil-producing regions of our country. The most promising process that allows obtaining valuable chemical products is the non-oxidative methane conversion into aromatic hydrocarbons over zeolite catalysts modified with transition metal ions. The Mo/ZSM-5 catalysts have high activity in this process. These catalysts are obtained both by impregnation and solid-phase synthesis. Development of the method of preparation of Mo/ZSM-5 catalysts using binder is of great importance for the industrial technology of processing gaseous hydrocarbons. The aim of the work is to study the effect of concentration and method of introducing a binder on physicochemical and catalytic properties of the Mo/ZSM-5 catalyst in non-oxidative methane conversion. Methods of investigation: IR spectroscopy, low-temperature adsorption of nitrogen, temperature-programmed desorption of ammonia (TPD-NH3), gas chromatography. Results. The Mo-containing catalyst based on ZSM-5 zeolite and nanosized molybdenum powder was prepared via solid-phase synthesis. The authors have studied the effect of a binder on physicochemical properties and activity of the Mo/ZSM-5 catalyst in non-oxidative conversion of methane into aromatic hydrocarbons. It was ascertained that the addition of a binder to the Mo/ZSM-5 catalyst results in a change in its texture and acid characteristics. It is shown that the activity of the Mo-containing zeolite during the non-oxidative conversion of methane into aromatic hydrocarbons is determined by the concentration of the binder in the catalyst and does not depend on the method of its introduction
Investigation of non-oxidative methane conversion over granulated Mo/ZSM-5 catalysts
ΠΠΊΡΡΠ°Π»ΡΠ½ΠΎΡΡΡ ΡΠ°Π±ΠΎΡΡ ΠΎΠ±ΡΡΠ»ΠΎΠ²Π»Π΅Π½Π° Π½Π΅ΠΎΠ±Ρ
ΠΎΠ΄ΠΈΠΌΠΎΡΡΡΡ ΡΠ°ΡΠΈΠΎΠ½Π°Π»ΡΠ½ΠΎΠ³ΠΎ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΡ ΠΏΡΠΈΡΠΎΠ΄Π½ΡΡ
ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Π½ΡΡ
Π³Π°Π·ΠΎΠ², ΠΎΡΠ½ΠΎΠ²Π½ΡΠΌ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠΎΠΌ ΠΊΠΎΡΠΎΡΡΡ
ΡΠ²Π»ΡΠ΅ΡΡΡ ΠΌΠ΅ΡΠ°Π½ ΠΈ ΠΊΠΎΡΠΎΡΡΠ΅ Π² Π½Π°ΡΡΠΎΡΡΠ΅Π΅ Π²ΡΠ΅ΠΌΡ Π² Π±ΠΎΠ»ΡΡΠΎΠΌ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅ ΡΠΆΠΈΠ³Π°ΡΡΡΡ Π² ΡΠ°ΠΊΠ΅Π»ΡΠ½ΡΡ
ΡΡΡΠ°Π½ΠΎΠ²ΠΊΠ°Ρ
Π½Π΅ΡΡΠ΅ΠΏΡΠΎΠΌΡΡΠ»ΠΎΠ². ΠΠ°ΠΈΠ±ΠΎΠ»Π΅Π΅ ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ²Π½ΡΠΌ ΠΏΡΠΎΡΠ΅ΡΡΠΎΠΌ, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡΡΠΈΠΌ ΠΏΠΎΠ»ΡΡΠ°ΡΡ ΠΈΠ· Π½ΠΈΡ
ΡΠ΅Π½Π½ΡΠ΅ Ρ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΏΡΠΎΠ΄ΡΠΊΡΡ, ΡΠ²Π»ΡΠ΅ΡΡΡ Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½Π°Ρ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΡ ΠΌΠ΅ΡΠ°Π½Π° Π² Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Ρ Π½Π° ΡΠ΅ΠΎΠ»ΠΈΡΠ½ΡΡ
ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ
, ΠΌΠΎΠ΄ΠΈΡΠΈΡΠΈΡΠΎΠ²Π°Π½Π½ΡΡ
ΠΈΠΎΠ½Π°ΠΌΠΈ ΠΏΠ΅ΡΠ΅Ρ
ΠΎΠ΄Π½ΡΡ
ΠΌΠ΅ΡΠ°Π»Π»ΠΎΠ². ΠΠ°ΠΈΠ±ΠΎΠ»ΡΡΡΡ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ Π² ΡΡΠΎΠΌ ΠΏΡΠΎΡΠ΅ΡΡΠ΅ ΠΏΡΠΎΡΠ²Π»ΡΡΡ Mo/ZSM-5 ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ, ΠΊΠΎΡΠΎΡΡΠ΅ ΠΏΠΎΠ»ΡΡΠ°ΡΡ ΠΊΠ°ΠΊ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ ΠΏΡΠΎΠΏΠΈΡΠΊΠΈ, ΡΠ°ΠΊ ΠΈ ΡΠ²Π΅ΡΠ΄ΠΎΡΠ°Π·Π½ΡΠΌ ΡΠΈΠ½ΡΠ΅Π·ΠΎΠΌ. Π Π°Π·ΡΠ°Π±ΠΎΡΠΊΠ° Π½Π°ΡΡΠ½ΡΡ
ΠΎΡΠ½ΠΎΠ² ΠΏΡΠΈΠ³ΠΎΡΠΎΠ²Π»Π΅Π½ΠΈΡ ΠΠΎ/ZSM-5 ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² Ρ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΡΠ²ΡΠ·ΡΡΡΠ΅Π³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° ΡΠ°Π·Π»ΠΈΡΠ½ΠΎΠΉ ΠΏΡΠΈΡΠΎΠ΄Ρ ΠΈΠΌΠ΅Π΅Ρ Π±ΠΎΠ»ΡΡΠΎΠ΅ Π·Π½Π°ΡΠ΅Π½ΠΈΠ΅ Π΄Π»Ρ ΠΏΡΠΎΠΌΡΡΠ»Π΅Π½Π½ΠΎΠ³ΠΎ Π²Π½Π΅Π΄ΡΠ΅Π½ΠΈΡ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈ ΠΏΠ΅ΡΠ΅ΡΠ°Π±ΠΎΡΠΊΠΈ Π³Π°Π·ΠΎΠΎΠ±ΡΠ°Π·Π½ΡΡ
ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄ΠΎΠ². Π¦Π΅Π»Ρ ΡΠ°Π±ΠΎΡΡ: ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ Π²Π»ΠΈΡΠ½ΠΈΡ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠΈ ΠΈ ΡΠΏΠΎΡΠΎΠ±Π° Π²Π²Π΅Π΄Π΅Π½ΠΈΡ ΡΠ²ΡΠ·ΡΡΡΠ΅Π³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° Π½Π° ΡΠΈΠ·ΠΈΠΊΠΎ-Ρ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° Mo/ZSM-5 ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎΠΉ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΠΈ ΠΌΠ΅ΡΠ°Π½Π°. ΠΠ΅ΡΠΎΠ΄Ρ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ: ΠΠ-ΡΠΏΠ΅ΠΊΡΡΠΎΡΠΊΠΎΠΏΠΈΡ, Π½ΠΈΠ·ΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½Π°Ρ Π°Π΄ΡΠΎΡΠ±ΡΠΈΡ Π°Π·ΠΎΡΠ°, ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΠΎ-ΠΏΡΠΎΠ³ΡΠ°ΠΌΠΌΠΈΡΠΎΠ²Π°Π½Π½Π°Ρ Π΄Π΅ΡΠΎΡΠ±ΡΠΈΡ Π°ΠΌΠΌΠΈΠ°ΠΊΠ° (Π’ΠΠ-NH3), Π³Π°Π·ΠΎΠ²Π°Ρ Ρ
ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΡ. Π Π΅Π·ΡΠ»ΡΡΠ°ΡΡ. ΠΠ΅ΡΠΎΠ΄ΠΎΠΌ ΡΠ²Π΅ΡΠ΄ΠΎΡΠ°Π·Π½ΠΎΠ³ΠΎ ΡΠΈΠ½ΡΠ΅Π·Π° ΠΏΠΎΠ»ΡΡΠ΅Π½ Mo-ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ ΡΠ΅ΠΎΠ»ΠΈΡΠ° ΡΡΡΡΠΊΡΡΡΠ½ΠΎΠ³ΠΎ ΡΠΈΠΏΠ° ZSM-5 ΠΈ Π½Π°Π½ΠΎΡΠ°Π·ΠΌΠ΅ΡΠ½ΠΎΠ³ΠΎ ΠΏΠΎΡΠΎΡΠΊΠ° ΠΌΠΎΠ»ΠΈΠ±Π΄Π΅Π½Π°. ΠΡΠΎΠ²Π΅Π΄Π΅Π½ΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ Π²Π»ΠΈΡΠ½ΠΈΡ ΡΠ²ΡΠ·ΡΡΡΠ΅Π³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° Π½Π° ΡΠΈΠ·ΠΈΠΊΠΎ-Ρ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΠΈ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ Mo/ZSM-5 ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎΠΉ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΠΈ ΠΌΠ΅ΡΠ°Π½Π° Π² Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Ρ. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ Π΄ΠΎΠ±Π°Π²ΠΊΠ° ΡΠ²ΡΠ·ΡΡΡΠ΅Π³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° ΠΊ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ Mo/ZSM-5 ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ ΠΊ ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΡ Π΅Π³ΠΎ ΡΠ΅ΠΊΡΡΡΡΠ½ΡΡ
ΠΈ ΠΊΠΈΡΠ»ΠΎΡΠ½ΡΡ
Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊ. ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΡ Mo-ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠ΅Π³ΠΎ ΡΠ΅ΠΎΠ»ΠΈΡΠ° Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ Π½Π΅ΠΎΠΊΠΈΡΠ»ΠΈΡΠ΅Π»ΡΠ½ΠΎΠΉ ΠΊΠΎΠ½Π²Π΅ΡΡΠΈΠΈ ΠΌΠ΅ΡΠ°Π½Π° Π² Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Ρ ΠΎΠΏΡΠ΅Π΄Π΅Π»ΡΠ΅ΡΡΡ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠ΅ΠΉ ΡΠ²ΡΠ·ΡΡΡΠ΅Π³ΠΎ Π²Π΅ΡΠ΅ΡΡΠ²Π° Π² ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ΅ ΠΈ Π½Π΅ Π·Π°Π²ΠΈΡΠΈΡ ΠΎΡ ΡΠΏΠΎΡΠΎΠ±Π° Π΅Π³ΠΎ Π²Π²Π΅Π΄Π΅Π½ΠΈΡ.The relevance of the investigation is caused by the need for rational use of natural hydrocarbon gases, containing methane as the main component. Currently, plenty of these gases are burned in flares at oil production sites, that does great damage to the environment in the oil-producing regions of our country. The most promising process that allows obtaining valuable chemical products is the non-oxidative methane conversion into aromatic hydrocarbons over zeolite catalysts modified with transition metal ions. The Mo/ZSM-5 catalysts have high activity in this process. These catalysts are obtained both by impregnation and solid-phase synthesis. Development of the method of preparation of Mo/ZSM-5 catalysts using binder is of great importance for the industrial technology of processing gaseous hydrocarbons. The aim of the work is to study the effect of concentration and method of introducing a binder on physicochemical and catalytic properties of the Mo/ZSM-5 catalyst in non-oxidative methane conversion. Methods of investigation: IR spectroscopy, low-temperature adsorption of nitrogen, temperature-programmed desorption of ammonia (TPD-NH3), gas chromatography. Results. The Mo-containing catalyst based on ZSM-5 zeolite and nanosized molybdenum powder was prepared via solid-phase synthesis. The authors have studied the effect of a binder on physicochemical properties and activity of the Mo/ZSM-5 catalyst in non-oxidative conversion of methane into aromatic hydrocarbons. It was ascertained that the addition of a binder to the Mo/ZSM-5 catalyst results in a change in its texture and acid characteristics. It is shown that the activity of the Mo-containing zeolite during the non-oxidative conversion of methane into aromatic hydrocarbons is determined by the concentration of the binder in the catalyst and does not depend on the method of its introduction
An accelerator facility for WDM, HEDP, and HIF investigations in Nazarbayev University
Nazarbayev University (NU) in Astana, Kazakhstan, is planning to build a new multi-MV, ~10 to several hundred GW/cm2 ion accelerator facility which will be used in studies of material properties at extreme conditions relevant to ion-beam-driven inertial fusion energy, and other applications. Two design options have been considered. The first option is a 1.2 MV induction linac similar to the NDCX-II at LBNL, but with modifications, capable of heating a 1 mm spot size thin targets to a few eV temperature. The second option is a 2 - 3 MV, ~200 kA, single-gap-diode proton accelerator powered by an inductive voltage adder. The high current proton beam can be focused to ~1 cm spot size to obtain power densities of several hundred GW/cm2, capable of heating thick targets to temperatures of tens of eV. In both cases, a common requirement to achieving high beam intensity on target and pulse length compression is to utilize beam neutralization at the final stage of beam focusing. Initial experiments on pulsed ion beam neutralization have been carried out on a 0.3 MV, 1.5 GW single-gap ion accelerator at Tomsk Polytechnic University with the goal of creating a plasma region in front of a target at densities exceeding ~1012 cm-3