Mode-Coupling as a Landau Theory of the Glass Transition

We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on the universality of MCT predictions. While our expansion generates higher order non-local corrections that modify the standard MCT equations, we find that the square root singularity of the order parameter, the scaling function in the \beta regime and the functional relation between the exponents defining the \alpha and \beta timescales are universal and left intact by these corrections.Comment: 6 pages, 1 figure, submitted to EPL; corrected typos in the abstract; corrected minor typo in reference

Critical fluctuations and breakdown of Stokes-Einstein relation in the Mode-Coupling Theory of glasses

We argue that the critical dynamical fluctuations predicted by the mode-coupling theory (MCT) of glasses provide a natural mechanism to explain the breakdown of the Stokes-Einstein relation. This breakdown, observed numerically and experimentally in a region where MCT should hold, is one of the major difficulty of the theory, for which we propose a natural resolution based on the recent interpretation of the MCT transition as a bona fide critical point with a diverging length scale. We also show that the upper critical dimension of MCT is d_c=8.Comment: Proceedings of the workshop on non-equilibrium phenomena in supercooled fluids, glasses and amorphous materials (17-22 September, 2006, Pisa

Crossover from stationary to aging regime in glassy dynamics

We study the non-equilibrium dynamics of the spherical p-spin models in the scaling regime near the plateau and derive the corresponding scaling functions for the correlators. Our main result is that the matching between different time regimes fixes the aging function in the aging regime to $h(t)=\exp(t^{1-\mu})$. The exponent $\mu$ is related to the one giving the length of the plateau. Interestingly $1-\mu$ is quickly very small when one goes away from the dynamic transition temperature in the glassy phase. This gives new light on the interpretation of experiments and simulations where simple aging was found to be a reasonable but not perfect approximation, which could be attributed to the existence of a small but non-zero stretching exponent.Comment: 7 pages+2 figure

Predictive power of MCT: Numerics and Finite size scaling for a mean field spin glass

The aim of this paper is to test numerically the predictions of the Mode Coupling Theory (MCT) of the glass transition and study its finite size scaling properties in a model with an exact MCT transition, which we choose to be the fully connected Random Orthogonal Model. Surprisingly, some predictions are verified while others seem clearly violated, with inconsistent values of some MCT exponents. We show that this is due to strong pre-asymptotic effects that disappear only in a surprisingly narrow region around the critical point. Our study of Finite Size Scaling (FSS) show that standard theory valid for pure systems fails because of strong sample to sample fluctuations. We propose a modified form of FSS that accounts well for our results. {\it En passant,} we also give new theoretical insights about FSS in disordered systems above their upper critical dimension. Our conclusion is that the quantitative predictions of MCT are exceedingly difficult to test even for models for which MCT is exact. Our results highlight that some predictions are more robust than others. This could provide useful guidance when dealing with experimental data.Comment: 37 pages, 19 figure

Dynamical field theory for glass-forming liquids, self-consistent resummations and time-reversal symmetry

We analyse the symmetries and the self-consistent perturbative approaches of dynamical field theories for glassforming liquids. In particular, we focus on the time-reversal symmetry (TRS), which is crucial to obtain fluctuation-dissipation relations (FDRs). Previous field theoretical treatment violated this symmetry, whereas others pointed out that constructing symmetry preserving perturbation theories is a crucial and open issue. In this work we solve this problem and then apply our results to the mode-coupling theory of the glass transition (MCT). We show that in the context of dynamical field theories for glass-forming liquids TRS is expressed as a nonlinear field transformation that leaves the action invariant. Because of this nonlinearity, standard perturbation theories generically do not preserve TRS and in particular FDRs. We show how one can cure this problem and set up symmetry-preserving perturbation theories by introducing some auxiliary fields. As an outcome we obtain Schwinger-Dyson dynamical equations that automatically preserve FDRs and that serve as a basis for carrying out symmetry-preserving approximations. We apply our results to MCT, revisiting previous field theory derivations of MCT equations and showing that they generically violate FDR. We obtain symmetry-preserving mode-coupling equations and discuss their advantages and drawbacks. Furthermore, we show, contrary to previous works, that the structure of the dynamic equations is such that the ideal glass transition is not cut off at any finite order of perturbation theory, even in the presence of coupling between current and density. The opposite results found in previous field theoretical works, such as the ones based on nonlinear fluctuating hydrodynamics, were only due to an incorrect treatment of TRS.Comment: 54 pages, 21 figure